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相关论文: Charge density dependent nongeminate recombination…

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We performed temperature dependent transient photovoltage and photocurrent measurements on poly(3-hexylthiophene):[6,6]-phenyl-C61 butyric acid methylester bulk heterojuction solar cells. We found a strongly charge carrier concentration and…

材料科学 · 物理学 2009-08-07 A. Foertig , A. Baumann , D. Rauh , V. Dyakonov , C. Deibel

We studied the recombination dynamics of charge carriers in organic bulk heterojunction solar cells made of the blend system poly(2,5-bis(3-dodecyl thiophen-2-yl) thieno[2,3-b]thiophene) (pBTCT-C12):[6,6]-phenyl-C61-butyric acid methyl…

Charge carrier recombination is studied in operational organic solar cells made from the polymer:fullerene system PCDTBT:PC71BM (poly[N-9"-heptadecanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] :…

Recombination of photogenerated charge carriers in polymer bulk heterojunction (BHJ) solar cells reduces the short circuit current (Jsc) and the fill factor (FF). Identifying the mechanism of recombination is, therefore, fundamentally…

材料科学 · 物理学 2015-05-20 Sarah R. Cowan , Anshuman Roy , Alan J. Heeger

We propose a model to explain the reduced bimolecular recombination rate found in state-of-the-art bulk heterojunction solar cells. When compared to the Langevin recombination, the experimentally observed rate is one to four orders of…

材料科学 · 物理学 2009-08-09 C. Deibel , A. Wagenpfahl , V. Dyakonov

We investigate nongeminate recombination in organic solar cells based on copper phthalocyanine (CuPc) and C$_{60}$. Two device architectures, the planar heterojunction (PHJ) and the bulk heterojunction (BHJ), are directly compared in view…

应用物理 · 物理学 2021-06-21 A. Foertig , A. Wagenpfahl , T. Gerbich , D. Cheyns , V. Dyakonov , C. Deibel

A combination of transient photovoltage (TPV), voltage dependent charge extraction (CE) and time delayed collection field (TDCF) measurements is applied to poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl]…

应用物理 · 物理学 2021-06-21 A. Foertig , J. Kniepert , M. Gluecker , T. Brenner , V. Dyakonov , D. Neher , C. Deibel

Understanding how the complex intermolecular- and nano-structure present in organic semiconductor donor-acceptor blends impacts charge carrier motion, interactions, and recombination behavior is a critical fundamental issue with a…

材料科学 · 物理学 2016-06-08 Michael C. Heiber , Thuc-Quyen Nguyen , Carsten Deibel

The charge carrier dynamics of organic solar cells are strongly influenced by trapping and allow to draw conclusions on the loss mechanisms limiting the photovoltaic performance. In this study we derive the recombination order \Delta\ of…

材料科学 · 物理学 2013-07-26 Carsten Deibel , Daniel Rauh , Alexander Foertig

We systematically investigate PM6:Y12 bulk-heterojunction solar cells with donor fractions ranging from 1% to 45%, linking morphology, charge transport, and recombination to device performance. Complementary structural and spectroscopic…

State of the art organic solar cells exhibit power conversion efficiencies of 18 % and above. These devices benefit from the suppression of free charge recombination with regard to the Langevin-limit of charge encounter in a homogeneous…

应用物理 · 物理学 2021-12-24 Guangzheng Zuo , Safa Shoaee , Martijn Kemerink , Dieter Neher

Transient photovoltage (TPV) and voltage dependent charge extraction (CE) measurements were applied to poly(3-hexylthiophene)(P3HT):[6,6]-phenyl-C61 butyric acid methyl ester (PCBM) bulk heterojunction solar cells to analyze the limitations…

材料科学 · 物理学 2012-08-23 Markus Gluecker , Alexander Foertig , Vladimir Dyakonov , Carsten Deibel

The power conversion efficiency of organic solar cells based on donor--acceptor blends is governed by an interplay of polaron pair dissociation and bimolecular polaron recombination. Both processes are strongly dependent on the charge…

材料科学 · 物理学 2010-05-26 C. Deibel , A. Wagenpfahl , V. Dyakonov

We report on the non-trivial field dependence of charge carrier recombination in an organic blend at low temperatures. A new microwave resonance technique for monitoring charge recombination in organic semiconductors at low temperatures is…

介观与纳米尺度物理 · 物理学 2015-09-09 S. Athanasopoulos , N. C. Greenham , R. H. Friend , A. D. Chepelianskii

In polymer:fullerene solar cells, the origin of the losses in the field-dependent photocurrent is still controversially debated. We contribute to the ongoing discussion by performing photo-induced charge extraction measurements on…

材料科学 · 物理学 2009-12-03 C. Deibel

The charge carrier mobility is a key parameter for the organic bulk heterojunction solar cell efficiency. It was recently shown that the interplay charge carrier transport and recombination, both depending on electron and hole mobilities,…

材料科学 · 物理学 2011-01-17 A. Wagenpfahl , C. Deibel , V. Dyakonov

The theoretical effects of phase separation on encounter-limited charge carrier recombination in organic semiconductor blends are investigated using kinetic Monte Carlo (KMC) simulations of pump-probe experiments. Using model bulk…

材料科学 · 物理学 2015-04-06 Michael C. Heiber , Christoph Baumbach , Vladimir Dyakonov , Carsten Deibel

In organic solar cells, photogenerated singlet excitons form charge transfer (CT) complexes, which subsequently split into free charge carriers. Here, we consider the contributions of excess energy and molecular quadrupole moments to the…

Surface recombination has a major impact on the open-circuit voltage ($V_\text{oc}$) of organic photovoltaics. Here, we study how this loss mechanism is influenced by imbalanced charge transport in the photoactive layer. As a model system,…

The present work revisits the recombination velocities ($s_{\mathrm{GB}}$) of minority-charge carriers determined at grain boundaries in polycrystalline absorber materials for solar cells. The equations describing $s_{\mathrm{GB}}$ as well…

材料科学 · 物理学 2025-03-13 Daniel Abou-Ras , Matthias Maiberg
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