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A generalized Green's function theory is developed to simulate the inelastic electron tunneling spectroscopy (IETS) of molecular junctions. It has been applied to a realistic molecular junction with an octanedithiolate embedded between two…

介观与纳米尺度物理 · 物理学 2015-06-25 Jun Jiang , Mathias Kula , Wei Lu , Yi Luo

We study inelastic electron tunneling through a molecular junction using the non-equilibrium Green function (NEGF) formalism. The effect of the mutual influence between the phonon and the electron subsystems on the electron tunneling…

介观与纳米尺度物理 · 物理学 2009-11-10 Michael Galperin , Mark A. Ratner , Abraham Nitzan

A theoretical analysis of inelastic electron tunneling spectroscopy (IETS) experiments conducted on molecular junctions are presented, where the second derivative of the current with respect to voltage is usually plotted as a function of…

介观与纳米尺度物理 · 物理学 2009-11-13 Kamil Walczak

We report on inelastic electron tunneling spectroscopy measurements carried out on single molecules incorporated into a mechanically controllable break-junction of Au and Pt electrodes at low temperature. Here we establish a correlation…

介观与纳米尺度物理 · 物理学 2010-11-16 Youngsang Kim , Hyunwook Song , Florian Strigl , Hans-Fridtjof Pernau , Takhee Lee , Elke Scheer

The theory of inelastic electron tunneling spectroscopy (IETS) and motions of single adsorbed atoms and molecules on metal surfaces induced by vibrational excitation with a scanning tunneling microscope (STM) is reviewed. The theory of…

介观与纳米尺度物理 · 物理学 2011-01-20 H. Ueba , S. G. Tikhodeev , B. N. J. Persson

Quantum transport through single molecules is essentially affected by molecular vibrations. We investigate the behavior of the prototype single-level model with intermediate electron-vibron coupling and arbitrary coupling to the leads. We…

介观与纳米尺度物理 · 物理学 2009-11-13 Dmitry A. Ryndyk , Gianaurelio Cuniberti

We investigate the interplay of quantum interference effects and electronic-vibrational coupling in electron transport through single-molecule junctions, employing a nonequilibrium Green's function approach. Our findings show that inelastic…

介观与纳米尺度物理 · 物理学 2013-02-18 R. Härtle , M. Butzin , M. Thoss

We consider the interaction between electrons and molecular vibrations in the context of electronic transport in nanoscale devices. We present a method based on non-equilibrium Green's functions to calculate both equilibrium and…

介观与纳米尺度物理 · 物理学 2010-03-16 L. K. Dash , H. Ness , R. W. Godby

Detection of a single nuclear spin constitutes an outstanding problem in different fields of physics such as quantum computing or magnetic imaging. Here we show that the energy levels of a single nuclear spin can be measured by means of…

介观与纳米尺度物理 · 物理学 2011-12-16 F. Delgado , J. Fernández-Rossier

A self-consistent method for calculating electron transport through a molecular device is proposed. It is based on density functional theory electronic structure calculations under periodic boundary conditions and implemented in the…

介观与纳米尺度物理 · 物理学 2007-05-23 San-Huang Ke , Harold U. Baranger , Weitao Yang

The interaction between electronic and vibrational degrees of freedom in single-molecule junctions may result from the dependence of the electronic energies or the electronic states of the molecular bridge on the nuclear displacement. The…

介观与纳米尺度物理 · 物理学 2015-06-09 A. Erpenbeck , R. Härtle , M. Thoss

The role of multimode vibrational dynamics in electron transport through single molecule junctions is investigated. The study is based on a generic model, which describes charge transport through a single molecule that is attached to metal…

介观与纳米尺度物理 · 物理学 2010-10-26 R. Härtle , C. Benesch , M. Thoss

We theoretically analyzed inelastic effects in the electron transport through molecular junctions originating from electron-vibron interactions. The molecular bridge was simulated by a periodic chain of identical interacting hydrogen-like…

材料科学 · 物理学 2010-01-03 Natalya A. Zimbovskaya , Maija M. Kuklja

In contrast to the static operations of conventional semiconductor devices, the dynamic conformational freedom in molecular devices opens up the possibility of using molecules as new types of devices such as a molecular conformational…

介观与纳米尺度物理 · 物理学 2009-07-02 Daijiro Nozaki , Gianaurelio Cuniberti

We develop a series of propensity rules for interpreting Inelastic Electron Tunneling (IET) spectra of single-molecule transport junctions. IETS has no selection rules, such as those seen in optical, infrared and Raman spectra, because IETS…

材料科学 · 物理学 2015-06-25 Alessandro Troisi , Mark A. Ratner

In single-molecule transistors, we observe inelastic cotunneling features that correspond energetically to vibrational excitations of the molecule, as determined by Raman and infrared spectroscopy. This is a form of inelastic electron…

介观与纳米尺度物理 · 物理学 2007-05-23 L. H. Yu , Z. K. Keane , J. W. Ciszek , L. Cheng , M. P. Stewart , J. M. Tour , D. Natelson

Resonant electron transport through a mesoscopic region (quantum dot or single molecule) with electron-phonon interaction is considered at finite voltage. In this case the standard Landauer-B\"uttiker approach cannot be applied. Using the…

介观与纳米尺度物理 · 物理学 2009-11-10 D. A. Ryndyk , J. Keller

Single-molecule junctions - nanoscale systems where a molecule is connected to metallic electrodes - offer a unique platform for studying charge, spin and energy transport in non-equilibrium many-body quantum systems, with few parallels in…

介观与纳米尺度物理 · 物理学 2024-11-05 María Camarasa-Gómez , Daniel Hernangómez-Pérez , Jan Wilhelm , Alexej Bagrets , Ferdinand Evers

Here we present theoretical studies of the effect of vibronic coupling on nonlinear transport characteristics (current-voltage and conductance-voltage) in molecular electronic devices. Considered device is composed of molecular quantum dot…

介观与纳米尺度物理 · 物理学 2009-11-11 Kamil Walczak

We report inelastic electron tunneling spectroscopy (IETS) of multilayer molecular junctions with and without incorporated metal nano-particles. The incorporation of metal nanoparticles into our devices leads to enhanced IET intensity and a…

介观与纳米尺度物理 · 物理学 2009-11-13 Lam H. Yu , Christopher D. Zangmeister , James G. Kushmerick
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