相关论文: Zinc in a +III oxidation state
We report observations of the cyanide anion, CN, in the disk around TW~Hya covering the $N=1-0$, $N=2-1$ and $N=3-2$ transitions. Using line stacking techniques, 24 hyperfine transitions are detected out of the 30 within the observed…
Plausible ratios of deuterium to hydrogen D/H as a function of metallicity, time, and redshift are investigated. Guided by the heavy element abundance patterns observed locally in Galactic dwarf stars and at large redshift in quasi-stellar…
The damped Lyman alpha systems seen in the spectra of high redshift QSOs offer the means to determine element abundances in galaxies observed while still at an early stage of evolution. Such measurements, which have only recently come…
Using a wave packet propagation approach, we find that the resonant charge transfer process of H^- near a Cu(111) surface is strongly influenced by transient hybrid states. These states originate from an ion-induced confinement parallel to…
A novel state of matter has been hypothesized to exist during the early stage of relativistic heavy ion collisions, with normal hadrons not appearing until several fm/c after the start of the reaction. To test this hypothesis, correlations…
The modern means of controlled irradiation by femtosecond lasers or swift heavy ion beams can transiently produce such energy densities in samples that reach collective electronic excitation levels of the warm dense matter state where the…
Recent computational studies have predicted many new ternary nitrides, revealing synthetic opportunities in this underexplored phase space. However, synthesizing new ternary nitrides is difficult, in part because intermediate and product…
Knowing oxide-forming ability is vital to gain desired or avoid deleterious oxides formation through tuning oxidizing environment and materials chemistry. Here, we have conducted a comprehensive thermodynamic analysis of 137 binary oxides…
We study theoretically the electronic states in a $5d$ transition metal oxide Na$_2$IrO$_3$, in which both the spin-orbit interaction and the electron correlation play crucial roles. Tight-binding model analysis together with the…
Magnetic moments of bound-electron systems are a sensitive tool for testing fundamental interactions. $g$ factors of lithium-like ions have been rigorously studied in recent years, enabling insights into the relativistic inter-electronic…
To accelerate exploration of chemical space, it is necessary to identify the compounds that will provide the most additional information or value. A large-scale analysis of mononuclear octahedral transition metal complexes deposited in an…
Recently, C. M. P\'epin \textit{et al.} [Science \textbf{357}, 382 (2017)] reported the formation of several new iron polyhydrides FeH$_x$ at pressures in the megabar range, and spotted FeH$_5$, which forms above 130 GPa, as a potential…
Damped Lyman-alpha absorbers (DLAs), seen in absorption against a background quasar, provide the most detailed probes available of element abundances in the Universe over > 90 % of its age. DLAs can be used to observationally measure the…
Carbon and oxygen are key tracers of the Galactic chemical evolution; in particular, a reported upturn in [C/O] towards decreasing [O/H] in metal-poor halo stars could be a signature of nucleosynthesis by massive Population III stars. We…
This study presents a comprehensive Multiphysics model for zinc-ion batteries (ZIBs), incorporating electrochemical aspects. The model integrates the mass transport of Zn2+ ions, charge transfer, and solid diffusion to predict performance…
Hydrogen is rarely observed as ligand in hypervalent species, however, we find that high-pressure hydrogenation may stabilise hypervalent hydrogen-rich materials. Focussing on ternary silicon hydrides via lithium doping, we find anions…
We present initial results of an ESO-VLT large programme (AMAZE) aimed at determining the evolution of the mass-metallicity relation at z>3 by means of deep near-IR spectroscopy. Gas metallicities are measured, for an initial sample of nine…
Seven distinct families of superconductors with critical temperatures at ambient pressure that equal or surpass the historic 23 K limit for Nb3Ge have been discovered in the last 25 years. Each family is reviewed briefly and their common…
Superconductivity in transition metal nitrides (TMNs) has been investigated for a long time, such as zirconium nitride (ZrN) with a superconducting transition temperature Tc of 10 K. Recently, a phase diagram has been revealed in ZrNx with…
An ab initio study of the electronic and spin configuration for the iron ion in the active center of the human hemoglobin molecule is presented. It is well known that the iron ion, being surrounded by the porphyrin ring and the ligands,…