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K$_x$Fe$_{2-y}$Se$_2$ exhibits an iron-vacancy ordering at $T_{\rm s} {\sim}270{\deg}$C and separates into two phases: a minor superconducting (iron-vacancy-disordered) phase and a major non-superconducting (iron-vacancy-ordered) phase. The…

The magnetic structure of superconducting Eu(Fe0.82Co0.18)2As2 is unambiguously determined by single-crystal neutron diffraction. A long-range ferromagnetic order of the Eu2+ moments along the c-direction is revealed below the magnetic…

超导电性 · 物理学 2014-05-06 W. T. Jin , S. Nandi , Y. Xiao , Y. Su , O. Zaharko , Z. Guguchia , Z. Bukowski , S. Price , W. H. Jiao , G. H. Cao , Th. Brueckel

The crystal structure of the superconductor FeSe0.44Te0.56 was redetermined by high-resolution X-ray single crystal diffraction at 173 K (anti-PbO-type, P4/nmm, a=3.7996(2), c=5.9895(6) A, R1=0.022, wR2=0.041, 173 F^2). Significantly…

超导电性 · 物理学 2010-02-24 Marcus Tegel , Catrin Loehnert , Dirk Johrendt

Single crystals of K0.58Fe1.56Se2 were successfully synthesized by a new single step process with the onset superconducting transition temperatures 31.9 K. The x-ray diffraction patterns suggest that they have high crystalline quality and…

超导电性 · 物理学 2011-03-17 Zhaoshun Gao , Yanpeng Qi , Lei Wang , Chao Yao , Dongliang Wang , Xianping Zhang , Yanwei Ma

Quantum transitions in Fe-based systems are believed to involve spin, charge and nematic fluctuations. Complex structural phase diagram in these materials often emphasizes importance of covalency in their exotic properties, which is…

The single-crystal growth, stoichiometry, and structure of Rb1-xFe2-ySe2-zSz crystals with substitution of Se by S are reported. The variation of the magnetic and thermodynamic parameters of samples was studied by differential-scanning…

We measure the resistivity and magnetic susceptibility in the temperature range from 5 K to 600 K for the single crystals $A$Fe$_{2-y}$Se$_2$ ($A$ = K$_{0.8}$, Rb$_{0.8}$, Cs$_{0.8}$, Tl$_{0.5}$K$_{0.3}$ and Tl$_{0.4}$Rb$_{0.4}$). A sharp…

Single crystals of A$_{1-x}$K$_x$Fe$_2$As$_2$ (A=Ba, Sr) with high quality have been grown successfully by FeAs self-flux method. The samples have sizes up to 4 mm with flat and shiny surfaces. The X-ray diffraction patterns suggest that…

超导电性 · 物理学 2009-11-13 Huiqian Luo , Zhaosheng Wang , Huan Yang , Peng Cheng , Xiyu Zhu , Hai-Hu Wen

The local structure and electronic properties of Rb$_{1-x}$Fe$_{2-y}$Se$_2$ are investigated by means of site selective polarized x-ray absorption spectroscopy at the iron and selenium K-edges as a function of pressure. A combination of…

In as-grown bulk crystals of Fe$_{1+y}$Te$_{1-x}$Se$_{x}$ with $x\lesssim0.3$, excess Fe ($y>0$) is inevitable and correlates with a suppression of superconductivity. At the same time, there remains the question as to whether the character…

In the layered iron-based superconductor YFe2Ge2, a high Sommerfeld ratio of ~100 mJ/molK^2 and a T^(3/2) temperature dependence of the electrical resistivity at low temperature T indicate strong electronic correlations and point towards an…

强关联电子 · 物理学 2019-01-09 Jiasheng Chen , Monika B. Gamza , Konstantin Semeniuk , F. Malte Grosche

Single crystals of Ba_{1-x}Rb_{x}Fe_2As_2 with x=0.05-0.1 have been grown from Sn flux and are bulk superconductors with T_c up to 23 K. The crystal structure was determined by X-ray diffraction analysis, and Sn is found to be incorporated…

超导电性 · 物理学 2009-04-07 Z. Bukowski , S. Weyeneth , R. Puzniak , P. Moll , S. Katrych , N. D. Zhigadlo , J. Karpinski , H. Keller , B. Batlogg

We report the superconductivity at above 30 K in a new FeSe-layer compound K0.8Fe2Se2 (nominal composition) achieved by metal K intercalating in between FeSe layers. It is isostructural to BaFe2As2 and possesses the highest Tc for…

超导电性 · 物理学 2019-06-12 Jiangang Guo , Shifeng Jin , Gang Wang , Shunchong Wang , Kaixing Zhu , Tingting Zhou , Meng He , Xiaolong Chen

The magnetic structure of the Eu2+ moments in the superconducting EuFe2(As1-xPx)2 sample with x = 0.19 has been determined using neutron scattering. We conclude that the Eu2+ moments are aligned along the c direction below T_C = 19.0(1) K…

Crystal structures and microstructural features, such as structural phase transitions, defect structures, chemical and structural inhomogeneities, are known to have profound effects on the physical properties of superconducting materials.…

超导电性 · 物理学 2013-07-22 Wang Zhen , Cai Yao , Yang Huai-Xin , Tian Huan-Fang , Wang Zhi-Wei , Ma Chao , Chen Zhen , Li Jian-Qi

We report on the synthesis of large single crystals of a new FeSe-layer superconductor Cs0.8(FeSe0.98)2. X-ray powder diffraction, neutron powder-diffraction and magnetization measurements have been used to compare the crystal structure and…

We report on the first local atomic structure study via the pair density function (PDF) analysis of neutron diffraction data and show a direct correlation of local coordinates to TC in the newly discovered superconducting FeSe1-xTex. The…

We report structurally tuned superconductivity in KxFe2-ySe2-zSz (0<=z<=2) phase diagram. Superconducting Tc is suppressed as S is incorporated into the lattice, eventually vanishing at 80% of S. The magnetic and conductivity properties can…

超导电性 · 物理学 2011-09-22 Hechang Lei , Milinda Abeykoon , Emil S. Bozin , Kefeng Wang , J. B. Warren , C. Petrovic

High-quality superconducting KxFeySe2 single crystals were synthesized using an easy one-step method. Detailed annealing studies were performed to make clear the phase formation process in KxFeySe2. Compatible observations were found in…

超导电性 · 物理学 2015-06-18 W. Zhou , X. Li , X. Zhou , F. F. Yuan , Y. Ding , J. C. Zhuang , Y. Sun , H. L. Zhou , Z. X. Shi

In this review, we present a summary of the results on single crystal growth of two types of iron-chalcogenide superconductors, Fe(1+y)Te(1-x)Se(x) (11), and A(x)Fe(2-y)Se(2) (A= K, Rb, Cs, Tl, Tl/K, Tl/Rb), using Bridgman, zone-melting,…

超导电性 · 物理学 2011-10-11 Jinsheng Wen , Guangyong Xu , Genda Gu , J. M. Tranquada , R. J. Birgeneau