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We demonstrate that the capacitance of ionic-liquid filled supercapacitors is substantially increased by placing a diode-like structure on the separator membrane. We call the structured separator: gate, and demonstrate that the order of a…

应用物理 · 物理学 2019-07-09 Tazima S. Chowdhury , Haim Grebel

We develop a theory of charge storage in ultra-narrow slit-like pores of nano\-structured electrodes. Our analysis is based on the Blume-Capel model in external field, which we solve analytically on a Bethe lattice. The obtained solutions…

软凝聚态物质 · 物理学 2020-01-08 Maxym Dudka , Svyatoslav Kondrat , Olivier Bénichou , Alexei A. Kornyshev , Gleb Oshanin

Nanoporous carbon-based supercapacitors store electricity through adsorption of ions from the electrolyte at the surface of the electrodes. Room temperature ionic liquids, which show the largest ion concentrations among organic liquid…

Having smaller energy density than batteries, supercapacitors have exceptional power density and cyclability. Their energy density can be increased using ionic liquids and electrodes with sub-nanometer pores, but this tends to reduce their…

材料科学 · 物理学 2015-06-18 S. Kondrat , P. Wu , R. Qiao , A. Kornyshev

When the electron density of highly crystalline thin films is tuned by chemical doping or ionic liq- uid gating, interesting effects appear including unconventional superconductivity, sizeable spin-orbit coupling, competition with…

介观与纳米尺度物理 · 物理学 2018-12-19 G. Dezi , N. Scopigno , S. Caprara , M. Grilli

In bulk semiconductor materials, the insulator-metal transition (IMT) is governed by the concentration of conduction electrons. Meanwhile, even when fabricated from metallic building blocks, nanocrystal films are often insulating with…

Nanopores made with low dimensional semiconducting materials, such as carbon nanotubes and graphene slit pores, are used in supercapacitors. In theories and simulations of their operation, it is often assumed that such pores screen ion-ion…

材料科学 · 物理学 2017-01-24 Alpha A. Lee , Dominic Vella , Alain Goriely

Ionic gating is a powerful technique to realize field-effect transistors (FETs) enabling experiments not possible otherwise. So far, ionic gating has relied on the use of top-electrolyte gates, which pose experimental constraints and make…

This paper investigates thermal transport in a nanocomposite system "porous silicon matrix filled with ionic liquid". First, the thermal conductivity and heat capacity of two imidazolium and one ammonium ionic liquids were evaluated using…

介观与纳米尺度物理 · 物理学 2023-04-13 Pavlo Lishchuk , Alina Vashchuk , Sergiy Rogalsky , Lesia Chepela , Mykola Borovyi , David Lacroix , Mykola Isaiev

Manipulating the superconducting states of high-T_c cuprate superconductors in an efficient and reliable way is of great importance for their applications in next-generation electronics. Traditional methods are mostly based on a…

Discotic ionic liquid crystals (DILCs) consist of self-assembled superdiscs of cations and anions that spontaneously stack in linear columns with high one-dimensional ionic and electronic charge mobility, making them prominent model systems…

In recent experiments, unprecedentedly large values for the conductivity of electrolytes through carbon nanotubes (CNTs) have been measured, possibly owing to flow slip and a high pore surface charge density whose origin is still unknown.…

软凝聚态物质 · 物理学 2023-07-25 Théo Hennequin , Manoel Manghi , Adrien Noury , Francois Henn , Vincent Jourdain , John Palmeri

Ionic gating is a very popular tool to investigate and control the electric charge transport and electronic ground state in a wide variety of different materials. This is due to its capability to induce large modulations of the surface…

超导电性 · 物理学 2021-05-27 Erik Piatti

We report the operation of a field-effect transistor based on a single InAs nanowire gated by an ionic liquid. Liquid gating yields very efficient carrier modulation with a transconductance value thirty time larger than standard back gating…

For a capacitor made of a semiconducting carbon nanotube (CNT) suspended above a metallic gate, Coulomb correlations between individual electrons can lead to a capacitance that is much larger than the geometric capacitance. We argue that…

强关联电子 · 物理学 2015-04-22 Han Fu , B. I. Shklovskii , Brian Skinner

We introduce a combined density functional theory (DFT) and non-equilibrium Green's function (NEGF) framework to compute the capacitance of nanocapacitors and directly extract the dielectric response of a sub-nanometer dielectric under…

Designing and fabricating self-assembled open colloidal crystals have become one major direction in soft matter community because of many promising applications associated with open colloidal crystals. However, most of the self-assembled…

软凝聚态物质 · 物理学 2019-04-16 Krongtum Sankaewtong , Qun-li Lei , Ran Ni

The potential of semiconductors assembled from nanocrystals (NC semiconductors) has been demonstrated for a broad array of electronic and optoelectronic devices, including transistors, light emitting diodes, solar cells, photodetectors,…

Supercapacitors are energy storage devices able to deliver electricity with a high power. They consist of porous carbon electrodes in a concentrated electrolyte. Charged is stored by the adsorption of ions at the electrode surface.…

化学物理 · 物理学 2018-11-26 Benjamin Rotenberg , Mathieu Salanne , Patrice Simon

The periodic spatial modulation potential arising from the zig-zag distribution of ions at large gate voltage in an ionic liquid gated device may enable functionalities in a similar way as nanopatterning and moir\'e engineering. However,…

介观与纳米尺度物理 · 物理学 2025-04-28 Qiao Chen , Chengyu Yan , Changshuai Lan , Qiyang Song , Yi Yan , Shun Wang
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