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Microscopic control over polar molecules with tunable interactions would enable realization of novel quantum phenomena. Using an applied electric field gradient, we demonstrate layer-resolved state preparation and imaging of ultracold…

We propose and analyze a scheme for sympathetic cooling of the translational motion of polar molecules in an optical lattice, interacting one by one with laser-cooled ions in a radio-frequency trap. The energy gap between the excitation…

原子物理 · 物理学 2015-05-19 Zbigniew Idziaszek , Tommaso Calarco , Peter Zoller

Simultaneous two-dimensional trapping of neutral dipolar molecules in low- and high-field seeking states is analyzed. A trapping potential of the order of 20 mK can be produced for molecules like ND3 with time-dependent electric fields. The…

化学物理 · 物理学 2009-11-10 T. Junglen , T. Rieger , S. A. Rangwala , P. W. H. Pinkse , G. Rempe

Magneto-optical trapping forces for molecules are far weaker than for alkali atoms because the photon scattering rate is reduced when there are multiple ground states, and because of optical pumping into dark states. The force is further…

原子物理 · 物理学 2021-12-14 M. R. Tarbutt , T. C. Steimle

We analyze theoretically the entanglement between two non-planar and light identical molecules (e.g., pyramidal as $NH_3$) that present inversion doubling due to the internal spatial inversion of their nuclear conformations by tunneling.…

量子物理 · 物理学 2020-01-08 Isabel Gonzalo , Miguel A. Antón

Cold, neutral hydroxyl radicals are Stark decelerated and confined within a magnetic trap consisting of two permanent ring magnets. The OH molecules are trapped in the ro-vibrational ground state at a density of $\sim10^{6}$ cm$^{-3}$ and…

原子物理 · 物理学 2009-01-22 Brian C. Sawyer , Benjamin K. Stuhl , Dajun Wang , Mark Yeo , Jun Ye

A comprehensive description of molecular electron transfer reactions is essential for our understanding of fundamental phenomena in bio-energetics and molecular electronics. Experimental studies of molecular systems in condensed-phase…

We demonstrate simultaneous deceleration and trapping of a cold atomic and molecular mixture. This is the first step towards studies of cold atom-molecule collisions at low temperatures as well as application of sympathetic cooling. Both…

We predict that pairs of polar molecules can be weakly bound together in an ultracold environment, provided that a dc electric field is present. The field that links the molecules together also strongly influences the basic properties of…

原子物理 · 物理学 2009-11-07 A. V. Avdeenkov , J. L. Bohn

In proposals for quantum computers using arrays of trapped ultracold polar molecules as qubits, a strong external field with appreciable gradient is imposed in order to prevent quenching of the dipole moments by rotation and to distinguish…

量子物理 · 物理学 2015-05-27 Qi Wei , Sabre Kais , Bretislav Friedrich , Dudley Herschbach

We present first steps toward understanding the ultracold scattering properties of polar molecules in strong electric field-seeking states. We have found that the elastic cross section displays a quasi-regular set of potential resonances as…

原子物理 · 物理学 2009-11-11 Christopher Ticknor , John L. Bohn

In weakly bound diatomic molecules, energy levels are closely spaced and thus more susceptible to mixing by magnetic fields than in the constituent atoms. We use this effect to control the strengths of forbidden optical transitions in…

原子物理 · 物理学 2015-12-22 B. H. McGuyer , M. McDonald , G. Z. Iwata , W. Skomorowski , R. Moszynski , T. Zelevinsky

We show that congruent electric, magnetic and non-resonant optical fields acting concurrently on a polar paramagnetic (and polarisable) molecule offer possibilities to both amplify and control the directionality of the ensuing molecular…

化学物理 · 物理学 2016-01-12 Ketan Sharma , Bretislav Friedrich

We investigate the collisional stability of magnetically trapped ultracold molecules, taking into account the influence of magnetic fields. We compute elastic and spin-state-changing inelastic rate constants for collisions of the prototype…

量子物理 · 物理学 2009-11-07 Alessandro Volpi , John L. Bohn

The collisional stability of ultracold polar molecules in electrostatic traps is considered. Rate constants for collisions that drive molecules from weak-field-seeking to strong-field-seeking states are estimated using a simple model. The…

原子物理 · 物理学 2009-11-06 John L. Bohn

We demonstrate a 1D magneto-optical trap of the polar free radical calcium monohydroxide (CaOH). A quasi-closed cycling transition is established to scatter $\sim 10^3$ photons per molecule, predominantly limited by interaction time. This…

We find a superradiant quantum phase transition in the model of triangular molecular magnets coupled to the electric component of a microwave cavity field. The transition occurs when the coupling strength exceeds a critical value which, in…

介观与纳米尺度物理 · 物理学 2017-08-23 Dimitrije Stepanenko , Mircea Trif , Oleksandr Tsyplyatyev , Daniel Loss

We report optical trapping of a polyatomic molecule, calcium monohydroxide (CaOH). CaOH molecules from a magneto-optical trap are sub-Doppler laser cooled to $20(3)~\mu\text{K}$ in free space and loaded into an optical dipole trap. We…

This paper reviews recent advances in the study of strongly interacting systems of dipolar molecules. Heteronuclear molecules feature large and tunable electric dipole moments, which give rise to long-range and anisotropic dipole-dipole…

量子气体 · 物理学 2016-07-14 Bryce Gadway , Bo Yan

Internal states of polar molecules can be controlled by microwave-frequency electric dipole transitions. If the applied microwave electric field has a spatial gradient, these transitions also affect the motion of these dipolar particles.…

量子物理 · 物理学 2021-10-20 Eric R. Hudson , Wesley C. Campbell