English

Control of Optical Transitions with Magnetic Fields in Weakly Bound Molecules

Atomic Physics 2015-12-22 v2 Quantum Physics

Abstract

In weakly bound diatomic molecules, energy levels are closely spaced and thus more susceptible to mixing by magnetic fields than in the constituent atoms. We use this effect to control the strengths of forbidden optical transitions in 88^{88}Sr2_2 over 5 orders of magnitude with modest fields by taking advantage of the intercombination-line threshold. The physics behind this remarkable tunability is accurately explained with both a simple model and quantum chemistry calculations, and suggests new possibilities for molecular clocks. We show how mixed quantization in an optical lattice can simplify molecular spectroscopy. Furthermore, our observation of formerly inaccessible ff-parity excited states offers an avenue for improving theoretical models of divalent-atom dimers.

Keywords

Cite

@article{arxiv.1503.05946,
  title  = {Control of Optical Transitions with Magnetic Fields in Weakly Bound Molecules},
  author = {B. H. McGuyer and M. McDonald and G. Z. Iwata and W. Skomorowski and R. Moszynski and T. Zelevinsky},
  journal= {arXiv preprint arXiv:1503.05946},
  year   = {2015}
}

Comments

8 pages, 4 figures

R2 v1 2026-06-22T08:57:40.123Z