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The conductivity of the electron hole and polaron conductor La1-xSrxFe0.75Ni0.25O3-{\delta}, a potential cathode material for intermediate temperature solid oxide fuel cells, was studied for 0 <x < 1 and for temperatures 300 K <T < 1250 K.…

Iron resonant valance band photoemission spectra of Sr substituted LaFe0.75Ni0.25 O3-{\delta} have been recorded across the Fe 2p - 3d absorption threshold to obtain Fe specific spectral information on the 3d projected partial density of…

强关联电子 · 物理学 2011-06-07 Selma Erat , Hiroki Wadati , Funda Aksoy , Zhi Liu , Thomas Graule , Ludwig J. Gauckler , Artur Braun

Substitution of La by Sr in the 25% Ni doped charge transfer insulator LaFeO3 creates structural changes that inflect the electrical conductivity caused by small polaron hopping via exchange interactions and charge transfer. The…

Angle-resolved photoemission spectroscopy (ARPES) reveals effects of electron doping, which is realized by Co and Ni substitution for Fe in FeTe$_{1-y}$Se$_{y}$ (y$\sim$0.35) superconductor. The data show consistent band shifts as well as…

超导电性 · 物理学 2019-10-29 M. Rosmus , R. Kurleto , D. J. Gawryluk , J. Goraus , M. Z. Cieplak , P. Starowicz

We report the doping high concentration of tetravalent Ge4+ ions (5 mol % for x = 0.05 to 30 mol % for x = 0.30) at the Fe3+ sites of Fe2-xGexO3 system by chemical coprecipitation route. The charge state of Fe and Ge ions has been modified…

材料科学 · 物理学 2023-09-08 Divya Sherin G T , R. N Bhowmik

We have performed an angle-resolved photoemission spectroscopy study of La$_{0.6}$Sr$_{0.4}$FeO$_3$ using {\it in situ} prepared thin films and determined its band structure. The experimental band dispersions could be well explained by an…

A large number of published experimental works suggest that when the Fe ions in orthorhombic LaFeO3 are substituted, band gap reduction is expected. However, recent experimental works observe band gap enhancement with increasing Ti ions…

材料科学 · 物理学 2024-01-23 Jesaya Situmeang , Djoko Triyono , Muhammad Aziz Majidi

We have investigated the electronic and optical properties of epitaxial La1-xSrxFeO3 for x from 0 to 1 prepared by molecular beam epitaxy. Core-level and valence-band x-ray photoemission features monotonically shift to lower binding energy…

Electric conductivity and structural details of the hole-doped polaron conductor La0.9Sr0.1FeO3 (LSF10) are reported. The conductivity of a single crystal shows an exponential increase with temperature with a maxi-mum of 100 S/cm at 700 K…

We report optical spectroscopic measurements on electron- and hole-doped BaFe2As2. We show that the compounds in the normal state are not simple metals. The optical conductivity spectra contain, in addition to the free carrier response at…

超导电性 · 物理学 2015-05-28 N. L. Wang , W. Z. Hu , Z. G. Chen , R. H. Yuan , G. Li , G. F. Chen , T. Xiang

In order to examine to what extent the rigid-band-like electron doping scenario is applicable to the transition metal-substituted Fe-based superconductors, we have performed angle-resolved photoemission spectroscopy studies of…

We report a theoretical investigation of effects of Mn and Co substitution in the transition metal sites of the kagome-lattice ferromagnet, Fe3Sn2. Herein, hole- and electron-doping effects of Fe3Sn2 have been studied by density-functional…

材料科学 · 物理学 2023-04-26 Milo Adams , Chen Huang , Michael Shatruk

X-ray absorption spectroscopy and optical reflectance measurements have been carried out to elucidate the evolution of the electronic structure in (Mg$_{1-x}$Al$_{x}$)B$_{2}$ for $\emph{x}$ = 0.0,0.1, 0.2, 0.3, and 0.4. The important role…

超导电性 · 物理学 2015-06-24 H. D. Yang , H. L. Liu , J. -Y. Lin , M. X. Kuo , P. L. Ho , J. M. Chen , C. U. Jung , Min-Seok Park , Sung-Ik Lee

The electronic structure of Li-doped Ni$_{1-x}$Fe$_x$O has been investigated using photoemission spectroscopy (PES) and x-ray absorption spectroscopy (XAS). The Ni $2p$ core-level PES and XAS spectra were not changed by Li doping. In…

The electronic and optical properties of self-trapped holes in kappa-phase orthorhombic Ga2O3 in conjunction with isoelectronic and acceptor dopants were studied using hybrid density functional theory. Hole trapping was found to be…

We have investigated the electronic structure of electron-doped Sr$_{2-x}$La$_x$FeMoO$_6$ ($x$=0.0 and 0.2) by photoemission spectroscopy and band-structure calculations within the local-density approximation+$U$ (LDA+$U$) scheme. A…

强关联电子 · 物理学 2007-05-23 T. Saitoh , M. Nakatake , H. Nakajima , O. Morimoto , A. Kakizaki , Sh. Xu , Y. Moritomo , N. Hamada , Y. Aiura

When either electron or hole doped at concentrations $x\sim 0.1$, the LaOFeAs family displays remarkably high temperature superconductivity with T$_c$ up to 55 K. In the most energetically stable $\vec Q_M = (\pi,\pi)$ antiferromagnetic…

超导电性 · 物理学 2009-11-13 Z. P. Yin , S. Lebègue , M. J. Han , B. Neal , S. Y. Savrasov , W. E. Pickett

The electronic band structures of the LaOFeP superconductor have been calculated theoretically by the first principles method and measured experimentally by electron energy loss spectroscopy. The calculations indicate that the Fe atom in…

超导电性 · 物理学 2009-11-13 Renchao Che , Ruijuan Xiao , Chongyun Liang , Huaixin Yang , Chao Ma , Honglong Shi , Jianqi Li

Electron energy-loss spectroscopy (EELS) was combined with heat capacity measurements to follow the change of superconductivity with systematic Al doping of MgB$_2$. By using x-ray diffraction and Vegard's law to assess the actual Al…

超导电性 · 物理学 2009-11-11 L. D. Cooley , A. J. Zambano , A. R. Moodenbaugh , R. F. Klie , Jin-Cheng Zheng , Yimei Zhu

The results of a previous work, where it was considered the effect of hole doping on a simple model of the CuO2 planes in La2CuO4, are extended. The parameters are adjusted with the objective to fix the known values of the gap of 2 eV for…

超导电性 · 物理学 2014-10-08 Yoandri Vielza de la Cruz , Alejandro Cabo Montes de Oca
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