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We present a computational study of the two-phonon Raman spectra of silicene and graphene within a density-functional non-orthogonal tight-binding model. Due to the presence of linear bands close to the Fermi energy in the electronic…

介观与纳米尺度物理 · 物理学 2016-04-29 Valentin N. Popov , Philippe Lambin

The effect of grain boundaries and wrinkles on the electrical properties of polycrystalline graphene is pronounced. Here we investigate the stitching between grains of polycrystalline graphene, specifically, overlapping of layers at the…

材料科学 · 物理学 2014-06-09 Rahul Rao , Neal Pierce , Avetik R. Harutyunyan

We report on resonance Raman spectroscopy measurements with excitation photon energy down to 1.16 eV on graphene, to study how low-energy carriers interact with lattice vibrations. Thanks to the excitation energy close to the Dirac point at…

In this work we study the symmetry properties of electrons and phonons in graphene systems as function of the number of layers. We derive the selection rules for the electron-radiation and for the electron-phonon interactions at all points…

介观与纳米尺度物理 · 物理学 2013-06-20 L. M. Malard , D. L. Mafra , M. H. D. Guimarães , M. S. C. Mazzoni , A. Jorio

We report multiphonon Raman scattering in graphene samples. Higher order combination modes involving 3 phonons and 4 phonons are observed in single-layer (SLG), bi-layer (BLG), and few layer (FLG) graphene samples prepared by mechanical…

介观与纳米尺度物理 · 物理学 2015-05-30 Rahul Rao , Derek Tishler , Jyoti Katoch , Masa Ishigami

We report a Raman spectroscopy study of graphene field-effect transistors (GFET) with a controlled amount of defects introduced in graphene by exposure to electron-beam irradiation. Raman spectra are taken at T = 8 K over a range of back…

材料科学 · 物理学 2015-06-22 Isaac Childres , Luis A. Jauregui , Yong P. Chen

We present a detailed calculation of intensities of two-phonon and four-phonon Raman peaks in graphene. Writing the low-energy hamiltonian of the interaction of electrons with the crystal vibrations and the electromagnetic field from pure…

材料科学 · 物理学 2009-11-13 D. M. Basko

We demonstrate electrochemical top gating of graphene by using a solid polymer electrolyte. This allows to reach much higher electron and hole doping than standard back gating. In-situ Raman measurements monitor the doping. The G peak…

The most important bands for the evaluation of strain in graphene (the 2D and 2D prime modes) are investigated. It is shown that for Bernal-stacked bilayers, the two-phonon Raman features have three different components that can be assigned…

材料科学 · 物理学 2021-07-27 Sara D Costa , Johan Ek Weis , Otakar Frank , Michaela Fridrichová , Martin Kalbac

Avoiding charge density variations and impurities in graphene is vital for high-quality graphene-based devices. Here, we demonstrate an optical method using Raman 2D peak-split to monitor charge density variations in the range 1-25e10 cm-2.…

应用物理 · 物理学 2020-05-12 Zhuofa Chen , Nathan Ullberg , Mounika Vutukuru , David Barton , Anna K Swan

Though graphene has been intensively studied by Raman spectroscopy, in this letter, we report a study of second-order overtone and combinational Raman modes in an unexplored range of 1690-2150 cm-1 in nonsuspended commensurate (AB-stacked),…

材料科学 · 物理学 2010-10-19 Chunxiao Cong , Ting Yu , Riichiro Saito

The Raman peak position and linewidth provide insight into phonon anharmonicity and electron-phonon interactions (EPI) in materials. For monolayer graphene, prior first-principles calculations have yielded decreasing linewidth with…

材料科学 · 物理学 2022-01-27 Zherui Han , Xiaolong Yang , Sean E. Sullivan , Tianli Feng , Li Shi , Wu Li , Xiulin Ruan

The symmetry group analysis is applied to classify the phonon modes of $N$-stacked graphene layers (NSGL's) with AB- and AA-stacking, particularly their infra-red and Raman properties. The dispersions of various phonon modes are calculated…

材料科学 · 物理学 2008-06-30 Jin-Wu Jiang , Hui Tang , Bing-Shen Wang , Zhao-Bin Su

We present a systematic experimental and theoretical study of the two-phonon (2D) Raman scattering in graphene under uniaxial tension. The external perturbation unveils that the 2D mode excited with 785nm has a complex line-shape mainly due…

We uncover the interlayer shear mode of multi-layer graphene samples, ranging from bilayer-graphene (BLG) to bulk graphite, and show that the corresponding Raman peak measures the interlayer coupling. This peak scales from~43cm-1 in bulk…

介观与纳米尺度物理 · 物理学 2015-05-28 P. H. Tan , W. P. Han , W. J. Zhao , Z. H. Wu , K. Chang , H. Wang , Y. F. Wang , N. Bonini , N. Marzari , G. Savini , A. Lombardo , A. C. Ferrari

Bilayer graphene is normally a semimetal with parabolic dispersion, but a tunable bandgap up to few hundreds meV can be opened by breaking the symmetry between the layers through an external potential. Ab-initio calculations show that the…

介观与纳米尺度物理 · 物理学 2015-09-30 Simone De Liberato

The unique properties of graphene offer immense opportunities for applications to many scientific fields, as well as societal needs, beyond our present imagination. One of the important features of graphene is the relatively simple…

材料科学 · 物理学 2018-04-27 Otakar Frank , Mildred S. Dresselhaus , Martin Kalbac

The phonon dispersions of monolayer and few-layer graphene (AB bilayer, ABA and ABC trilayers) are investigated using the density-functional perturbation theory (DFPT). Compared with the monolayer, the optical phonon $E_{2g}$ mode at…

材料科学 · 物理学 2009-11-13 Jia-An Yan , W. Y. Ruan , M. Y. Chou

The dispersion of electrons and phonons near the K point of bilayer graphene was investigated in a resonant Raman study using different laser excitation energies in the near infrared and visible range. The electronic structure was analyzed…

介观与纳米尺度物理 · 物理学 2011-04-08 D. L. Mafra , L. M. Malard , S. K. Doorn , H. Htoon , J. Nilsson , A. H. Castro Neto , M. A. Pimenta

Magneto-Raman scattering experiments from the surface of graphite reveal novel features associated to purely electronic excitations which are observed in addition to phonon-mediated resonances. Graphene-like and graphite domains are…

介观与纳米尺度物理 · 物理学 2015-05-27 C. Faugeras , M. Amado , P. Kossacki , M. Orlita , M. Kühne , A. A. L. Nicolet , Yu. I. Latyshev , M. Potemski