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We have successfully synthesized a new layered iron oxychalcogenide BaFe2OSe2 single crystal. This compound is built up of Ba and Fe-Se(O) layers alternatively stacked along the c-axis. The Fe-Se(O) layers contain double chains of…

超导电性 · 物理学 2015-06-05 Hechang Lei , Hyejin Ryu , John Warren , A. I. Frenkel , V. Ivanovski , B. Cekic , C. Petrovic

By means of the first-principle calculations, we have investigated electronic, magnetic properties and correlation effects for the newly discovered layered oxyselenide Na2Fe2Se2O. Our results reveal that the electron correlations in the Fe…

材料科学 · 物理学 2015-06-05 D. V. Suetin , I. R. Shein , A. L. Ivanovskii

We successfully synthesized new layered iron oxypnictide Sr2CrO2(FeAs)2 by solid-state-reaction techniques. This is the first report on the Fe-substituted Sr2Mn3As2O2-type oxypnictides to our knowledge. A pellet of stoichiometric mixtures…

A new iron-oxychalcogenide (CaO)(FeSe) was obtained which crystallizes in the orthorhombic space group Pnma (No. 62) with a = 5.9180(12) {\AA}, b = 3.8802(8) {\AA}, c = 13.193(3) {\AA}. The unique structure of (CaO)(FeSe) is built up of a…

Our searches for new oxide chalcogenides of rare earths and Fe, Co, Ni, and Zn resulted in preparation of two new compounds Ce2Fe2O3S2 and Pr2Fe2O3S2 which are isostructural to La2Fe2O3Se2 and Sm2Ti2O3Sb2. Crystal structures of the new…

材料科学 · 物理学 2011-10-20 D. O. Charkin , V. A. Plotnikov , A. V. Sadakov , O. E. Omel'yanovskii , S. M. Kazakov

The new layered manganese oxychalcogenides (LaO)$_2$Mn$_2$Se$_2$O and (BaF)$_2$Mn$_2$Se$_2$O, isostructural to (LaO)$_2$Fe$_2$Se$_2$O, were synthesized by using solid state reaction. The single crystals of former compound were also…

材料科学 · 物理学 2013-05-29 R. H. Liu , J. S. Zhang , P. Cheng , X. G. Luo , X. H. Chen

We report a combination of X-ray and neutron diffraction studies, Mossbauer spectroscopy and muon spin relaxation (muSR) measurements to probe the structure and magnetic properties of the semiconducting beta-Ce2O2FeSe2 oxychalcogenide. We…

We investigated the crystal structure, magnetic behavior, and optical properties of the layered honeycomb compound Na2Cu2TeO6. X-ray and neutron diffraction confirmed a monoclinic structure, with Cu ions arranged in dimerized chains.…

强关联电子 · 物理学 2025-08-25 Shubham Patil , S. D. Kaushik

We present the results of structural and magnetic phase comparisons of the iron oxychalcogenides La$_{2}$O$_{2}$Fe$_{2}$O$M$$_{2}$ ($M$ = S, Se). Elastic neutron scattering reveals that $M$ = S and Se have similar nuclear structures at room…

The latest discovery of a new iron-chalcogenide superconductor A$_x$Fe$_{2-y}$Se$_2$(A=K, Cs, Rb, Tl and etc.) has attracted much attention due to a number of its unique characteristics, such as the possible insulating state of the parent…

超导电性 · 物理学 2012-01-04 Daixiang Mou , Lin Zhao , Xingjiang Zhou

A new oxide, sodium iron antimonate, Na2FeSbO5, was synthesized and structurally characterized, and its static and dynamic magnetic properties were comprehensively studied both experimentally by dc and ac magnetic susceptibility,…

The iron arsenide Eu3Fe2O5Fe2As2 was synthesized at 1173-1373 K in a resistance furnace and characterized by X-ray powder diffraction with Rietveld analysis: Sr3Fe2O5Cu2S2-type, I4/mmm, a = 406.40(1) pm, c = 2646.9(1) pm. Layers of…

强关联电子 · 物理学 2015-06-10 Franziska Hummel , Marcus Tegel , Birgit Gerke , Rainer Pöttgen , Dirk Johrendt

We report an experimental study of the CoFe2O4/CoFe2 nanocomposite, a nanostructured material formed by hard (CoFe2O4) and soft (CoFe2) magnetic materials. The precursor material, cobalt ferrite (CoFe2O4), was prepared using the…

介观与纳米尺度物理 · 物理学 2019-07-17 E. S. Ferreira , E. F. Chagas , A. P. Albuquerque , R. J. Prado , E. Baggio-Saitovitch

Layered Sr0.35CoO2 has been synthesized by means of an ion exchange reaction from Na0.7CoO2. Resistivity measurements show that this material can be either metallic or semiconducting depending on the annealing conditions. Magnetic…

强关联电子 · 物理学 2007-05-23 H. X. Yang , Y. G. Shi , Y. Q. Guo , X. Liu , R. J. Xiao , J. L. Luo , J. Q. Li

We report an experimental study of the bimagnetic nanocomposites CoFe2/CoFe2O4.The precursor material, CoFe2O4 was prepared using the conventional stoichiometric combustion method. The nanocomposite CoFe2/CoFe2O4 was obtained by total…

The ability to tune the iron chalcogenides BaFe2Q3 from Mott insulators, to metals and then superconductors with applied pressure has renewed interest in low-dimensional iron chalcogenides and oxychalcogenides. We report here a combined…

强关联电子 · 物理学 2019-07-31 B. D. Coles , A. D. Hillier , F. C. Coomer , N. C. Bristowe , S. Ramos , E. E. McCabe

Structure and composition of iron chalcogenides have a delicate relationship with magnetism and superconductivity. In this report we investigate the iron sulfide layered tetragonal phase (t-FeS), and compare with three-dimensional hexagonal…

Polycrystalline samples of the layered iron arsenides Sr2CrO3FeAs and Ba2ScO3FeAs were synthesized by high temperature solid state reactions and their crystal structures determined by the X-ray powder diffraction. Their structures are…

Superconductivity has been found in the iron-arsenides with different structures by alternative stacking of the conducting Fe2As2 layers and spacer layers including alkali- or alkali-earth metal ions and PbO- or perovskite-type oxides…

超导电性 · 物理学 2015-06-17 X. F. Lu , N. Z. Wang , G. H. Zhang , X. G. Luo , Z. M. Ma , B. Lei , F. Q. Huang , X. H. Chen

We report the results of a systematic investigation of the phase diagram of the iron-based superconductor system, Ba1-xNaxFe2As2, from x = 0.1 to x = 1.0 using high resolution neutron and x-ray diffraction and magnetization measurements. We…

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