相关论文: Cross-section and selection rules in surface enhan…
It is demonstrated in the framework of the Dipole-Quadrupole theory, that strong quadrupole light-molecule interaction, which is responsible for the most enhancement of SEHRS in the methane molecule, which belongs to the symmetry group,…
Chemical selectivity, as quantified by a branching ratio, is a phenomenon relevant for many organic chemical reactions. It may be exhibited on a potential energy surface that features a valley-ridge inflection point in the region between…
The spin-dependent cross sections for semi-inclusive lepton-nucleon scattering are derived in the framework of collinear factorization, including the effects of masses of the target and produced hadron at finite momentum transfer squared…
It is demonstrated that explanation of appearance of strong forbidden lines in the SEHR spectra of pyrazine and phenazine, caused by totally symmetric vibrations and also other details of their SER and SEHR spectra can be made on the base…
In order to numerically compute scattering cross sections in QCD, one needs to deal with various kinematic divergences that appear at intermediate stages of the calculation. One way of doing this is by setting up an IR subtraction scheme.…
Symmetries and their associated selection rules are extremely useful in all fields of science. In particular, for system that include electromagnetic (EM) fields interacting with matter, it has been shown that both of symmetries of matter…
The SEHRS spectrum of 4,4' Bipyridine is analyzed on the base of the Dipole Quadrupole theory. It is demonstrated that there appear strong lines caused by vibrations transforming after a unit irreducible representation of the D2 symmetry…
The uncertainties involved in the calculation of bottom quark cross-sections in deep-inelastic scattering at HERA are studied in different phase space regions. Besides the inclusive bottom quark cross-section, definitions closer to the…
A method is proposed to pin down an unambiguous proof for single molecule surface enhanced Raman spectroscopy (SERS). The simultaneous use of two analyte molecules enables a clear confirmation of the single (or few) molecule nature of the…
This article reviews the new developments in Tip-enhanced Raman scattering (TERS). The fundamental mechanisms underlying the Raman enhancement are discussed, including the role of the plasmonic character of the metallic tips, the nature of…
The interaction between molecules is commonly ignored in surface-enhanced Raman scattering (SERS). Under this assumption, the total SERS signal is described as the sum of the individual contributions of each molecule treated independently.…
We present a general model study of surface-enhanced resonant Raman scattering and fluorescence focusing on the interplay between electromagnetic effects and the molecular dynamics. Our model molecule is placed close to two Ag…
The cross-section for the process $\gamma + A \to \mu^+ + \mu^- + X$ is studied where the photon energy is of the order of several hundreds of GeV and where one of the leptons is scattered to large angles. This is of practical importance…
We present a method for designing smooth cross fields on surfaces that automatically align to sharp features of an underlying geometry. Our approach introduces a novel class of energies based on a representation of cross fields in the…
We present an alternative method to calculate cross sections for multi-parton scattering processes in the Standard Model at leading order. The helicity amplitudes are computed using recursion relations in the number of particles, based on…
Selection rules are often considered a hallmark of symmetry. When a symmetry is broken, e.g., by an external perturbation, the system exhibits selection rule deviations which are often analyzed by perturbation theory. Here, we employ…
We examine SERS from two perspectives: as a phenomenon described by the Laplace Equation (the electrostatic or Rayleigh limit) and by the Helmholtz Equation (electrodynamic or Mie limit). We formulate the problem in terms of the scalar…
We study the electric quadrupole (E2) contribution to resonant x-ray scattering (RXS). Under the assumption that the rotational invariance is preserved in the Hamiltonian describing the intermediate state of scattering, we derive a useful…
We present a general model study of surface-enhanced resonant Raman scattering and fluorescence, focusing on the interplay between electromagnetic (EM) effects and the molecular dynamics as treated by a density matrix calculation. The model…
A theory of electronic Raman scattering in the presence of several energy bands crossing the Fermi surface is developed. The contributions to the light scattering cross section are calculated for each band and it is shown that the cross…