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Kondo insulator FeSb$_2$ with large Seebeck coefficient would have potential in thermoelectric applications in cryogenic temperature range if it had not been for large thermal conductivity $\kappa$. Here we studied the influence of…

强关联电子 · 物理学 2016-05-06 Kefeng Wang , Rongwei Hu , John Warren , C. Petrovic

Thermoelectric materials operating at cryogenic temperatures are in high demand for efficient cooling and power generation in applications ranging from superconductors to quantum computing. The narrow band-gap semiconductor FeSb2, known for…

材料科学 · 物理学 2023-11-02 Deepak Gujjar , Sunidhi Gujjar , V. K. Malik , Hem C. Kandpal

We study the thermoelectric properties of Te-doped FeSb2 nanostructured samples. Four samples of stoichiometry FeSb1.84Te0.16 were prepared by a hot press method at temperatures of 200, 400, 500, and 600 oC. Te-doping enhances the…

材料科学 · 物理学 2013-03-18 M. Pokharel , H. Z. Zhao , M. Koirala , Z. F. Ren , C. Opeil

We report a strategy based on introduction of point defects for improving the thermoelectric properties of FeSb2, a promising candidate for low temperature applications. Introduction of Sb deficiency to the tune of 20% leads to enhancement…

材料科学 · 物理学 2015-05-01 Anup V. Sanchela , Ajay D. Thakur , C. V. Tomy

The effect of Co doping on supercoductivity of FeSe$_{0.4}$Te$_{0.6}$ single crystals is investigated. The superconducting transition temperature decreases linearly for Co doping with the rate -0.75 K/(Co %). On the other hand, the residual…

超导电性 · 物理学 2015-05-28 Fuyuki Nabeshima , Yusuke Kobayashi , Yoshinori Imai , Ichiro Tsukada , Atsutaka Maeda

Substitution of Sb in FeSb$_2$ by less than 0.5% of Te induces a transition from a correlated semiconductor to an unconventional metal with large effective charge carrier mass $m^*$. Spanning the entire range of the semiconductor-metal…

材料科学 · 物理学 2016-08-14 P. Sun , M. Søndergaard , Y. Sun , S. Johnsen , B. B. Iversen , F. Steglich

We report the evolution of thermal transport properties of iron-based superconductor K$_x$Fe$_{2-y}$Se$_2$ with sulfur substitution at Se sites. Sulfur doping suppresses the superconducting $T_c$ as well as the Seebeck coefficient. The…

超导电性 · 物理学 2015-05-28 Kefeng Wang , Hechang Lei , C. Petrovic

In this work, thermoelectric properties of Al$_{1.2}$Fe$_2$B$_2$ compound were investigated over a temperature range from 300\,K to 773\,K. Al$_{1.2}$Fe$_2$B$_2$ compound was produced by vacuum arc melting of Al, Fe, and B followed by…

材料科学 · 物理学 2022-12-05 Duraisamy Sivaprahasam , Ashutosh Kumar , Babu Jayachandran , Raghavan Gopalan

Thermoelectric properties of the chemically-doped intermetallic narrow-band semiconductor FeGa3 are reported. The parent compound shows semiconductor-like behavior with a small band gap (Eg = 0.2 eV), a carrier density of ~ 10(18) cm-3 and,…

We employ density functional theory to investigate the thermoelectric properties of electron and hole doped PtSb$_2$. Our results show that for doping of 0.04 holes per unit cell (1.5$\times10^{20}$ cm$^{-3}$) PtSb$_2$ shows a high Seebeck…

材料科学 · 物理学 2014-02-19 Y. Saeed , N. Singh , Schwingenschlögl

We investigate the effect of electronic correlations onto the thermoelectricity of semi-conductors and insulators. Appealing to model considerations, we study various many-body renormalizations that enter the thermoelectric response. We…

材料科学 · 物理学 2010-08-13 Jan M. Tomczak , K. Haule , T. Miyake , A. Georges , G. Kotliar

We present the effects of lead doping on the thermoelectric properties of Tellurium Telluride, prepared by solid state reactions in an evacuated sealed silica tubes. Structurally, all these compounds were found to be phase pure as confirmed…

强关联电子 · 物理学 2016-10-05 Wiqar Hussain Shah , Aqeel Khan , Waqar Adil Syed

The potential of Fe2TiSn full-Heusler compounds for thermoelectric applications has been suggested theoretically, but not yet grounded experimentally, due to the difficulty of obtaining reproducible, homogeneous, phase pure and defect free…

The sodium cobaltate system Na$_{x}$CoO$_2$ is a prominent representant of strongly correlated materials with promising thermoelectric response. In a combined theoretical and experimental study we show that by doping the Co site of the…

材料科学 · 物理学 2018-04-25 Raphael Richter , Denitsa Shopova , Wenjie Xie , Anke Weidenkaff , Frank Lechermann

We report the thermoelectric properties (Seebeck coefficient, thermal conductivity, and electrical resistivity) of lightly doped single crystals of (001)-oriented SrTiO3 (STO). Hall effect measurements show that electron doping around 10^-5…

强关联电子 · 物理学 2012-11-08 P. L. Bach , V. Leborán , V. Pardo , A. S. Botana , D. Baldomir , F. Rivadulla

Ge$_{2}$Sb$_{2}$Te$_{5}$ (GST) has been widely used as a popular phase change material. In this study, we show that it exhibits high Seebeck coefficients 200 - 300 $\mu$V/K in its cubic crystalline phase ($\it{c}$-GST) at remarkably high…

材料科学 · 物理学 2015-03-30 Jifeng Sun , Saikat Mukhopadhyay , Alaska Subedi , Theo Siegrist , David J. Singh

Search of new thermoelectric (TE) materials with high \textit{figure-of-merit} (ZT) is always inspired the researcher in TE field. Here, we present a combined experimental and theoretical study of TE properties of Na$_{0.74}$CoO$_{2}$…

材料科学 · 物理学 2020-08-26 Shamim Sk , Jayashree Pati , R. S. Dhaka , Sudhir K. Pandey

We investigate the thermoelectric propeties of the electron-doped FeAs$_2$ both experimentally and theoretically. Electrons are doped by partially substituting Se for As, which leads to a metallic behavior in the resistivity. A Seebeck…

材料科学 · 物理学 2013-09-06 Hidetomo Usui , Kazuhiko Kuroki , Seiya Nakano , Kazutaka Kudo , Minoru Nohara

We study role of site substitutions at In and Te site in In2Te5 on the thermoelectric behavior. Single crystals with compositions In2(Te1-xSex)5 (x = 0, 0.05, 0.10) and Fe0.05In1.95(Te0.90Se0.10)5 were prepared using modified…

材料科学 · 物理学 2016-08-24 Anup V. Sanchela , Ajay D. Thakur , C. V. Tomy

The effects of various transition metal dopants on the electrical and thermal transport properties of Fe1-xMxSi alloys (M= Co, Ir, Os) are reported. The maximum thermoelectric figure of merit ZTmax is improved from 0.007 at 60 K for pure…

强关联电子 · 物理学 2015-05-28 Brian C. Sales , Olivier Delaire , Michael A. McGuire , Andrew F. May
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