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Interplay of spin, charge, orbital and lattice degrees of freedom in oxide heterostructures results in a plethora of fascinating properties, which can be exploited in new generations of electronic devices with enhanced functionalities. The…

Materials containing high densities of exceptionally displaceable ions (e.g. perovskites) have extremely large ratios of their static to high-frequency dielectric constants, > 2. Large polarons form in such materials as their electronic…

超导电性 · 物理学 2020-08-26 David Emin

Polar discontinuities and structural changes at oxide interfaces can give rise to a large variety of electronic and ionic phenomena. Related effects have been intensively studied in epitaxial systems, including ferroelectric domain walls…

Neutron scattering has been used to study the nature of the ferromagnetic transition in a single crystal of the perovskite La0.7Ca0.3MnO3. Diffuse scattering from lattice polarons develops as the Curie temperature is approached from below,…

强关联电子 · 物理学 2009-10-31 C. P. Adams , J. W. Lynn , Y. M. Mukovskii , A. A. Arsenov , D. A. Shulyatev

The formation of polarons is a pervasive phenomenon in transition metal oxide compounds, with a strong impact on the physical properties and functionalities of the hosting materials. In its original formulation the polaron problem considers…

材料科学 · 物理学 2019-02-18 Michele Reticcioli , Ulrike Diebold , Georg Kresse , Cesare Franchini

Charge trapping and formation of polarons is a pervasive phenomenon in transition metal oxide compounds, in particular at the surface, affecting fundamental physical properties and functionalities of the hosting materials. Here we…

材料科学 · 物理学 2018-07-25 Michele Reticcioli , Martin Setvin , Michael Schmid , Ulrike Diebold , Cesare Franchini

The work is devoted to the investigation of the surface plasmon polaritons in the metal - dielectric heterostructures containing materials with magnetoelectric properties. The analysis of various possible configurations shows that the…

The growth of charge ordering phenomenon in calcium doped lanthanum manganites La1-xCaxMnO3, x 0.62, 0.67 has been studied using transmission electron microscopy TEM. The diffuse intensity characteristic of short range charge ordering is…

强关联电子 · 物理学 2009-01-28 P. R. Sagdeo

The behavior of electrons in the conduction band of TiO2 and other transition-metal oxides is key to the many applications of these materials. Experiments seem to produce conflicting results: optical and spin-resonance techniques reveal…

材料科学 · 物理学 2015-06-12 A. Janotti , C. Franchini , J. B. Varley , G. Kresse , C. G. Van de Walle

Acceptor-doped perovskite oxides like BaZrO$_3$ are showing great potential as materials for renewable energy technologies where hydrogen acts an energy carrier, such as solid oxide fuel cells and hydrogen separation membranes. While ionic…

材料科学 · 物理学 2016-08-24 Anders Lindman , Paul Erhart , Göran Wahnström

Polarons, quasiparticles formed through interactions between lattice and charge carriers (electrons and holes), strongly influence the electronic and optical properties of functional materials. In nanostructured BiVO$_{4}$, polaron…

材料科学 · 物理学 2025-11-26 Seyeon Park , Yajing Zhang , Michele Reticcioli , Cesare Franchini , Bongjae Kim

In the colossal magnetoresistance manganites polarons have been proposed as the charge carrier state which localizes across the metal-insulator transition. The character of the polarons is still under debate. We present an assessment of…

强关联电子 · 物理学 2015-06-24 Ch. Hartinger , F. Mayr , A. Loidl , T. Kopp

The interplay of the electron-phonon interaction and of the double and super exchange magnetic effects is analyzed in the $La_{1-x}Ca_xMnO_3$ perovskites with $0<x<0.5$. By using an analytical variational scheme that allows to treat the…

强关联电子 · 物理学 2009-10-31 V. Cataudella , G. De Filippis , G. Iadonisi

The question whether excess electrons in SrTiO3 form free or trapped carriers is a crucial aspect for the electronic properties of this important material. This fundamental ambiguity prevents a consistent interpretation of the puzzling…

强关联电子 · 物理学 2018-03-15 Xianfeng Hao , Zhiming Wang , Michael Schmid , Ulrike Diebold , Cesare Franchini

We present a minimal model of charge transport in hybrid perovskites, which provides an intuitive explanation for the recently proposed formation of ferroelectric large polarons. We demonstrate that short-ranged charge--rotor interactions…

介观与纳米尺度物理 · 物理学 2023-03-08 Georgios M. Koutentakis , Areg Ghazaryan , Mikhail Lemeshko

Two-dimensional (2D) perovskite oxide interfaces are ideal systems where diverse emergent properties can be uncovered.The formation and modification of polaronic properties due to short-range strong charge-lattice interactions of 2D…

By means of density-functional simulations for half-doped manganites, such as pseudocubic Pr0.5Ca0.5MnO3 and bilayer PrCa2Mn2O7, we discuss the occurrence of ferroelectricity and we explore its crucial relation to the crystal structure and…

强关联电子 · 物理学 2013-10-07 Kunihiko Yamauchi , Silvia Picozzi

Polarons - fermionic charge carriers bearing a strong companion lattice deformation - exhibit a natural tendency for self-localization due to the recursive interaction between electrons and the lattice. While polarons are ubiquitous in…

CaCu$_{3}$Ti$_{4}$O$_{12}$ (CCTO) has a large dielectric permittivity that is independent of the probing frequency near the room temperature, which complicated due to the existence of several dynamic processes. Here, we consider the…

Recently a growing number of experiments have provided indications of the key role of polarons (composite particles formed by a charge strongly coupled with a local lattice deformation) in doped perovskites, hosting colossal…

超导电性 · 物理学 2009-09-25 A. Lanzara , N. L. Saini , A. Bianconi , Guo-meng Zhao , K. Conder , H. Keller , K. A. Muller
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