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Liquid crystal elastomers are cross-linked elastomer networks with liquid crystal mesogens incorporated into the main or side chain. Polydomain liquid crystalline (nematic) elastomers exhibit unusual mechanical properties like soft…
An unresolved issue in the theory of liquid crystals is the molecular basis of the electroclinic effect in the smectic-A phase. Recent x-ray scattering experiments suggest that, in a class of siloxane-containing liquid crystals, an electric…
Photoactive liquid crystal elastomers are polymer networks of liquid crystal mesogens embedded with chromophores like azobenzene. They undergo large deformation when illuminated by light of a certain wavelength through photochemical…
Liquid crystal elastomers are cross-linked polymer networks covalently bonded with liquid crystal mesogens. In the nematic phase, due to strong coupling between mechanical strain and orientational order, these materials display…
Deformations of amorphous polymer networks prepared with significant concentrations of liquid crystalline mesogens have been recently reported to undergo mechanotropic phase transitions. Here, we report that these mechanotropic phase…
Liquid crystal networks exploit the coupling between the responsivity of liquid-crystalline mesogens, e.g., to electric fields, and the (visco)elastic properties of a polymer network. Because of this, these materials have been put forward…
In this article, we construct and analyze models of anisotropic crosslinked polymers employing tools from the theory of liquid crystal elastomers. The anisotropy of these systems stems from the presence of rigid-rod molecular units in the…
The physics of an electron solid, held on a cryogenic liquid surface by a pressing electric field, is examined in a low-density regime that has not been explored before. We consider the effect of the pressing field in distorting the surface…
In liquid crystal elastomers, the orientational order of liquid crystals is coupled with elastic distortions of crosslinked polymer networks. Previous theoretical research has described these materials through two different approaches: a…
We investigate how controlled foaming alters the mechanical dissipation of liquid crystalline elastomers (LCEs). Using thermal expandable microspheres, we generate homogeneous foams with precisely tuned bubble volume fractions up to 13% and…
Liquid crystal elastomers (LCEs) are elastomeric networks with rod-like mesogens that reorient under load. In polydomain LCEs, this reorientation drives a polydomain-to-monodomain transition that produces a soft-elastic plateau. Coupling…
When liquid-crystalline elastomers pass through the isotropic-nematic transition, the orientational order parameter and the elastic strain vary rapidly but smoothly, without the expected first-order discontinuity. This broadening of the…
Materials exhibiting a large caloric effect could lead to the development of new generation of heat-management technologies that will have better energy efficiency and be potentially more environmentally friendly. The focus of caloric…
Liquid crystal elastomers are rubbery solids that couple liquid crystalline order and deformation. This coupling leads to properties that are attractive for a number of applications in soft robotics and energy absorption. This paper is…
Modeling liquid crystal elastomers (LCEs) at the molecular level is crucial for the predictable design of energy-conversion and stimuli-responsive materials. Here, we develop a self-consistent field theory for LCEs which captures the…
We present a detailed analysis of the molecular packing of a strained liquid crystal elastomer composed of chiral mesogens in the smectic A phase. X-ray diffraction patterns of the elastomer collected over a range of orientations with…
Elasto-plastic models are among the most successful ways to study the critical properties of the plastic yielding transition of amorphous solids. Typically these models are studied under a condition of constant transition rates from one…
Recent studies of azo-dye doped liquid crystal elastomers show a strong photomechanical response. We report on models that predict experimental results that suggest photothermal heating is the dominant mechanism in a planar constrained…
We aimed to use finite element method to simulate the unique behaviors of liquid crystal elastomer, such as semi-soft elasticity, stripe domain instabilities etc. We started from an energy functional with the 2D Bladon-Warner-Terentjev…
We use molecular dynamics simulations to unravel the physics underpinning the light-induced density changes caused by the dynamic trans-cis-trans isomerization cycles of azo-mesogens embedded in a liquid crystal polymer network, an…