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The results of differential-thermal analysis of various samples as well as dielectric measurements of solid solutions $TlIn_{1-x}Fe_x^{56,57}S_2$ are presented. It has been established that phase transitions become blurred and shift to low…

凝聚态物理 · 物理学 2007-05-23 R. M. Sardarli , A. P. Abdullayev , O. A. Samedov , N. A. Eubova , B. R. Gadjiyev

A new lead-free (1-x)Li0.12Na0.88NbO3-xBaTiO3 (0 to x to 40) piezoelectric ceramics have been prepared using conventional ceramics processing route. Structural analysis revealed an existence of morphotropic phase boundary (MPB), separating…

材料科学 · 物理学 2014-12-24 Supratim Mitra , Ajit R. Kulkarni

Designing and understanding functional electronic and magnetic properties in perovskite oxides requires controlling and tuning the underlying crystal lattice. Here we report the structure, including oxygen and cation positions, of a…

We report systematic investigation of high pressure crystal structures and structural phase transition upto 46 GPa in CaFeAsF and 40 GPa in SrFeAsF at 40 K using powder synchrotron x-ray diffraction experiments and Rietveld analysis of the…

Magnetically-driven ferroelectric atomic displacements of the order of 10$^{-3} Angstrom have been observed in orthorhombic (perovskite like) YMnO$_3$ by a single-crystal synchrotron x-ray diffraction. The refined polar structure shows the…

A first-principles-derived scheme, that incorporates ferroelectric and antiferrodistortive degrees of freedom, is developed to study finite-temperature properties of PbZr1-xTixO3 solid solutions near its morphotropic phase boundary. The use…

材料科学 · 物理学 2009-11-11 Igor A. Kornev , L. Bellaiche , P. -E. Janolin , B. Dkhil , E. Suard

We present a thorough study on the magnetoanisotropic properties and magnetocaloric effect in the layered ferromagnetic Cr$_4$Te$_5$ single crystals by performing the critical behaviour analysis of magnetization isotherms. The critical…

材料科学 · 物理学 2022-09-20 Shubham Purwar , Susmita Changdar , Susanta Ghosh , S. Thirupathaiah

Magnetic flux structure on the surface of EuFe$_2$(As$\rm_{1-x}$P$\rm_x$)$_2$ single crystals with nearly optimal phosphorus doping levels $x=0.20$, and $x=0.21$ is studied by low-temperature magnetic force microscopy and decoration with…

Recently discovered fine structure of the morphotropic phase boundaries in highly piezoelectric mixture compounds PZT, PMN-PT, and PZN-PT demonstrates the importance of highly non-linear interactions in these systems. We show that an…

材料科学 · 物理学 2009-11-07 I. A. Sergienko , Yu. M. Gufan , S. Urazhdin

Erbium orthochromite, ErCrO3, is a distorted-perovskite which has antiferromagnetic ground state below 10 K while Cr3+ magnetic moments order at 133 K. The temperature dependence of magnetization is studied across different magnetic phases…

强关联电子 · 物理学 2015-01-29 Brajesh Tiwari , M Krishna Surendra , M. S. Ramachandra Rao

Single crystals of the methylammonium (MA) lead halides MAPbI3, MAPbBr3, and MAPbCl3 have been investigated using infrared spectroscopy with the aim of analyzing structural and dynamical aspects of processes that enable the ordering of the…

The structural phase transformations of 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 (PMN-30%PT) have been studied using x-ray diffraction (XRD) and neutron scattering as a function of temperature and electric field. We observe the phase transformational…

材料科学 · 物理学 2009-11-10 Feiming Bai , Naigang Wang , Jiefang Li , D. Viehland , P. M. Gehring , Guangyong Xu , G. Shirane

Temperature-dependent dielectric permittivity of lead-free (LixNa1-x)NbO3 for nominal x = 0.04-0.20, prepared by solid state reaction followed by sintering, was studied to resolve often debated issue pertaining to exactness of morphotropic…

材料科学 · 物理学 2014-01-15 S. Mitra , A. R. Kulkarni , Om. Prakash

The temperature dependence of the elastic properties of antiferroelectric PbHfO3 was investigated by Brillouin scattering. The two structural phase transitions of antiferroelectric-antiferroelectric-paraelectric phases were clearly…

材料科学 · 物理学 2015-06-18 Jae-Hyeon Ko , Krystian Roleder , Andrzej Majchrowski , Annette Bussmann-Holder

Perovskite solid solutions that have a chemical composition A(C$_x$D$_{1-x})$O$_3$ with transition metals C and D substitutionally occupying the B site of a perovskite lattice are attractive in various applications for their dielectric,…

介观与纳米尺度物理 · 物理学 2021-04-14 Ying Shi Teh , Jiangyu Li , Kaushik Bhattacharya

The properties of Pt-based materials can be intriguing due to the importance of spin-orbit coupling for Pt. Herein, we report four new phases with formulas M3Pt23Ge11 (M = Ca, Sr, Ba and Eu), which adopt the same structure type as…

材料科学 · 物理学 2021-08-25 Xin Gui , Robert J. Cava

Recently, based on the phase-field modeling, it was predicted that Hf1-xZrxO2 (HZO) exhibits the morphotropic phase boundary (MPB) in its compositional phase diagram. Here, we investigate the effect of structural changes between tetragonal…

材料科学 · 物理学 2021-05-05 Alireza Kashir , Hyunsang Hwang

In this article mixed CuInP$_2$(S$_x$Se$_{1-x}$)$_6$ crystals were investigated by broadband dielectric spectroscopy (20 Hz - 3 GHz). From these results the complete phase diagram has been obtained. In the middle part of the phase diagram…

适应与自组织系统 · 物理学 2009-11-13 J. Macutkevic , J. Banys , R. Grigalaitis , Yu. Vysochanski

Plate-like single crystals of SrFe2As2 as large as 3x3x0.5 mm3 have been grown out of Sn flux. The SrFe2As2 single crystals show a structural phase transition from a high temperature tetragonal phase to a low temperature orthorhombic phase…

The results are presented of anelastic and dielectric spectroscopy measurements on large grain ceramic PZT with compositions near the two morphotropic phase boundaries (MPBs) that the ferroelectric (FE) rhombohedral phase has with the…

材料科学 · 物理学 2013-03-27 F. Cordero , F. Trequattrini , F. Craciun , C. Galassi