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The appearance of superconductivity at ambient pressures in the undoped iron pnictide parent compound SrFe2As2 is studied experimentally using several techniques and approaches to aid in understanding the nature of this phase. Low…

超导电性 · 物理学 2010-04-13 K. C. Kirshenbaum , S. R. Saha , N. P. Butch , J. D. Magill , J. Paglione

Here we report the discovery of the first ternary molybdenum pnictide based superconductor K2Mo3As3. Polycrystalline samples were synthesized by the conventional solid state reaction method. X-ray diffraction analysis reveals a…

超导电性 · 物理学 2018-08-02 Qing-Ge Mu , Bin-Bin Ruan , Kang Zhao , Bo-Jin Pan , Tong Liu , Lei Shan , Gen-Fu Chen , Zhi-An Ren

EuFe2As2 is a member of the ternary iron arsenide family. Similar to BaFe2As2 and SrFe2As2, EuFe2As2 exhibits a clear anomaly in resistivity near 200 K. It suggests that EuFe2As2 is another promising parent compound in which…

超导电性 · 物理学 2009-11-13 Yanpeng Qi , Zhaoshun Gao , Lei Wang , Dongliang Wang , Xianping Zhang , Yanwei Ma

The synthesis, structural and physical properties of iron lanthanide oxypnictide superconductors, L4Fe2As2Te1-xO4 (L = Pr, Sm, Gd), with transition temperature at ~ 25 K are reported. Single crystals have been grown at high pressure using…

超导电性 · 物理学 2015-06-18 S. Katrych , A. Pisoni , S. Bosma , S. Weyeneth , N. D. Zhigadlo , R. Gaal , J. Karpinski , L. Forró

We report the unprecedented square-planar coordination of iridium in the iron iridium arsenide Ca10(Ir4As8)(Fe2As2)5. This material experiences superconductivity at 16 K. X-ray photoemission spectroscopy and first- principles band…

We report the realization of superconductivity by 5d element Ir doping in LaFeAsO, a prototype parent compound of high-temperature iron based superconductors. X-ray diffraction patterns indicate that the material has formed the…

超导电性 · 物理学 2009-08-06 Yanpeng Qi , Lei Wang , Zhaoshun Gao , Dongliang Wang , Xianping Zhang , Zhiyu Zhang , Yanwei Ma

The Ca10(PtnAs8)(Fe2As2)5 (n=3,4) compounds are a new type of iron pnictide superconductors whose structures consist of stacking Ca-PtnAs8-Ca-Fe2As2 layers in a unit cell. When n=3 (the 10-3-8 phase), the undoped compound is an…

Here we report the synthesis and discovery of superconductivity in a novel ternary iridium-arsenide compound BaIr2As2. The polycrystalline BaIr2As2 sample was synthesized by a high temperature and high pressure method. Crystal structural…

超导电性 · 物理学 2017-08-22 Xiao-Chuan Wang , Bin-Bin Ruan , Jia Yu , Bo-Jin Pan , Qing-Ge Mu , Tong Liu , Gen-Fu Chen , Zhi-An Ren

An overview of the crystal structures and physical properties of the recently discovered iron-platinum-arsenide superconductors, Ca10(PtnAs8)(Fe2-xPtxAs2)5 (n = 3 and 4), which have a superconducting transition temperature up to 38 K, is…

We have synthesized two iron-pnictide/chalcogenide materials, CuFeTe2 and Fe2As, which share crystallographic features with known iron-based superconductors, and carried out high-pressure electrical resistivity measurements on these…

Kamihara and coworkers' report of superconductivity at Tc = 26 K in fluorine-doped LaFeAsO inspired a worldwide effort to understand the nature of the superconductivity in this new class of compounds. These iron pnictide and chalcogenide…

超导电性 · 物理学 2011-12-14 G. R. Stewart

Superconductivity in PdTe2 heavy transition metal based compounds is rapidly developing field in condensed matter physics community. Here, we report superconductivity in a nominal ternary telluride Ta2Pd0.97Te6 compound, which is…

超导电性 · 物理学 2015-06-01 Reena Goyal , Brajesh Tiwari , Rajveer Jha , V. P. S Awana

Superconductivity has been found in the iron-arsenides with different structures by alternative stacking of the conducting Fe2As2 layers and spacer layers including alkali- or alkali-earth metal ions and PbO- or perovskite-type oxides…

超导电性 · 物理学 2015-06-17 X. F. Lu , N. Z. Wang , G. H. Zhang , X. G. Luo , Z. M. Ma , B. Lei , F. Q. Huang , X. H. Chen

Since the discovery of superconductivity\cite{1} at 26 K in oxy-pnictide $LaFeAsO_{1-x}F_x$, enormous interests have been stimulated in the fields of condensed matter physics and material sciences. Among the five different structures in…

超导电性 · 物理学 2009-09-29 Xiyu Zhu , Fei Han , Peng Cheng , Gang Mu , Bing Shen , Hai-Hu Wen

We have synthesized a quaternary fluoroarsenide SrFeAsF with the ZrCuSiAs-type structure (P4/nmm, a = 0.3999 and c = 0.8973 nm), which is composed of an alternately stacked (FeAs)- and (SrF)+ layers, analogous to the FeAs-based…

超导电性 · 物理学 2008-11-10 Satoru Matsuishi , Yasunori Inoue , Takatoshi Nomura , Masahiro Hirano , Hideo Hosono

We measured the pressure dependence of in-plane resistivity $\rho_{ab}$ in the recently-discovered iron-based superconductor Ca$_{10}$(Ir$_{4}$As$_{8}$)(Fe$_{2-x}$Ir$_{x}$As$_{2}$)$_{5}$, which shows a unique structural phase transition in…

We successfully synthesized new layered iron oxypnictide Sr2CrO2(FeAs)2 by solid-state-reaction techniques. This is the first report on the Fe-substituted Sr2Mn3As2O2-type oxypnictides to our knowledge. A pellet of stoichiometric mixtures…

Bulk superconductivity was discovered in BaRh2P2 (Tc = 1.0 K) and BaIr2P2 (Tc = 2.1 K), which are isostructural to (Ba,K)Fe2As2, indicative of the appearance of superconductivity over a wide variety of layered transition metal pnictides.…

A series of layered (Sr$_{1-x}$K$_x$)Fe$_2$As$_2$ compounds with nominal x=0 to 0.40 are synthesized by solid state reaction method. Similar to other parent compounds of iron-based pnictide superconductors, the pure SrFe$_2$As$_2$ shows a…

超导电性 · 物理学 2008-08-05 G. F. Chen , Z. Li , G. Li , W. Z. Hu , J. Dong , X. D. Zhang , P. Zheng , N. L. Wang , J. L. Luo

We report resistivity measurement under pressure in single crystals of SrFe_2As_2, which is one of the parent materials of Fe-based superconductors. The structural and antiferromagnetic (AFM) transition of T_0 = 198 K at ambient pressure is…

超导电性 · 物理学 2009-11-13 H. Kotegawa , H. Sugawara , H. Tou