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Two atoms in an ultracold gas are correlated at short inter-atomic distances due to threshold effects where the potential energy of their interaction dominates the kinetic energy. The correlations manifest themselves in a distinct nodal…

原子物理 · 物理学 2011-04-15 Christiane P. Koch , Ronnie Kosloff

We analyze the formation of Rb_2 molecules with short photoassociation pulses applied to a cold Rb-85 sample. A pump laser pulse couples a continuum level of the ground electronic state X ^1\Sigma_{g}^+ with bound levels in the 0_{u}^+…

原子物理 · 物理学 2007-06-22 Jordi Mur-Petit , Eliane Luc-Koenig , Françoise Masnou-Seeuws

We study the formation of the RbCs molecule by an intense laser pulse using nonlinear dynamics. Under the Born-Oppenheimer approximation, the system is modeled by a two degree of freedom rovibrational Hamiltonian, which includes the ground…

混沌动力学 · 物理学 2017-04-05 Cristel Chandre , J Mahecha , J Salas

We propose a mechanism to realize high-yield molecular formation from ultracold atoms. Atom pairs are continuously excited by a laser, and a collective decay into the molecular ground state is induced by a coupling to a lossy cavity mode.…

We show theoretically that it is possible to form a cold molecular ion from a pair of colliding atom and ion at low energy by photoassociative two-photon Raman processes. We explore the possibility of stimulated Raman adiabatic passage…

原子物理 · 物理学 2016-09-13 Dibyendu Sardar , Somnath Naskar , Arpita Pal , Bimalendu Deb

This review describes recent experimental and theoretical advances in forming molecules in ultracold gases of trapped alkali metal atoms, both by magnetic tuning through Feshbach resonances and by photoassociation. Molecular Bose-Einstein…

化学物理 · 物理学 2007-05-23 Jeremy M. Hutson , Pavel Soldan

We discuss theoretically ion-atom collisions at low energy and predict the possibility of formation of cold molecular ion by photoassociation. We present results on radiative homo- and hetero-nuclear atom-ion cold collisions that reveal…

原子物理 · 物理学 2011-09-06 Arpita Rakshit , Bimalendu Deb

Chemical reactions typically proceed via stochastic encounters between reactants. Going beyond this paradigm, we combine exactly two atoms into a single, controlled reaction. The experimental apparatus traps two individual laser-cooled…

原子物理 · 物理学 2018-04-25 L. R. Liu , J. D. Hood , Y. Yu , J. T. Zhang , N. R. Hutzler , T. Rosenband , K. -K. Ni

We investigate the dynamical formation of crystalline states with systems of polar molecules or Rydberg atoms loaded into a deep optical lattice. External fields in these systems can be used to couple the atoms or molecules between two…

量子气体 · 物理学 2015-03-13 J. Schachenmayer , I. Lesanovsky , A. Micheli , A. J. Daley

The electrostatic interaction between an excited atom and a diatomic ground state molecule in an arbitrary rovibrational level at large mutual separations is investigated with a general second-order perturbation theory, in the perspective…

量子物理 · 物理学 2017-04-11 M. Lepers , R. Vexiau , N. Bouloufa , O. Dulieu , V. Kokoouline

The formation of ultracold metastable RbCs molecules is observed in a double species magneto-optical trap through photoassociation below the ^85Rb(5S_1/2)+^133Cs(6P_3/2) dissociation limit followed by spontaneous emission. The molecules are…

原子物理 · 物理学 2015-06-03 N. Bouloufa-Maafa , M. Aymar , O. Dulieu , C. Gabbanini

Ultracold plasmas are formed by photo-exciting clouds of cold atoms and molecules near the ionization threshold. They explore a new region of plasma physics and display effects of strong coupling, which is characterized by a ratio of…

等离子体物理 · 物理学 2012-01-05 J. Castro , P. McQuillen , H. Gao , T. C. Killian

A theoretical model is proposed for the formation of ultracold ground-state triatomic molecules in weakly bound energy levels. The process is driven by the electric component of a microwave field, which induces the association of an…

原子物理 · 物理学 2026-01-16 Baraa Shammout , Leon Karpa , Silke Ospelkaus , Eberhard Tiemann , Olivier Dulieu

We explore the feasibility of optically forming long-range tetratomic and larger polyatomic molecules in their ground electronic state from ultracold pairs of polar molecules aligned by external fields. Depending on the relative orientation…

原子物理 · 物理学 2021-06-16 Marko Gacesa , Jason N. Byrd , Jonathan Smucker , John A. Montgomery, , Robin Côté

This theoretical paper presents numerical calculations for photoassociation of ultracold cesium atoms with a chirped laser pulse and detailed analysis of the results. In contrast with earlier work, the initial state is represented by a…

原子与分子团簇 · 物理学 2009-11-10 E. Luc-Koenig , R. Kosloff , F. Masnou-Seeuws , M. Vatasescu

We propose an improved photoassociation scheme to produce ultracold molecules in their vibronic ground state for the generic case where non-adiabatic effects facilitating transfer to deeply bound levels are absent. Formation of molecules is…

原子物理 · 物理学 2008-10-28 Christiane P. Koch , Robert Moszynski

Radiative emission during cold collisions between trapped laser-cooled Rb atoms and alkaline-earth ions (Ca$^+$, Sr$^+$, Ba$^+$) and Yb$^+$, and between Li and Yb$^+$, are studied theoretically, using accurate effective-core-potential based…

原子物理 · 物理学 2015-06-23 Humberto Da Silva , Maurice Raoult , Mireille Aymar , Olivier Dulieu

We investigate the formation of ultracold NaCs molecules by photoassociation of Na and Cs atoms.

化学物理 · 物理学 2010-08-09 Xuan Li

Using a non-selective broadband detection scheme we discovered an efficient mechanism of formation of ultracold Cs$_2$ molecules in deeply bound levels ($v=1-9$) of their electronic ground state X$^1 \Sigma_g^+$. They are formed by a…

Photoassociation of ultracold rubidium atoms with femtosecond laser pulses is studied theoretically. The spectrum of the pulses is cut off in order to suppress pulse amplitude at and close to the atomic resonance frequency. This leads to…