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A phenomenological theory has been proposed for the diffusionless structural phase transitions in crystalline solids here. It has been found that for BaTiO3 single crystal, both the phase transitions and the crystal structures can be…

材料科学 · 物理学 2012-10-02 Hui Zhang

The methyl groups in hexamethylbenzene C$_6$(CH$_3$)$_6$ become magnetically ordered at the molecular level below 118 K. This is also near the temperature at which the system structurally transitions from triclinic to a unique near-cubic…

强关联电子 · 物理学 2018-12-07 Fei Yen

The two-dimensional organic conductor $\alpha$-(BEDT-TTF)$_2$I$_3$ undergoes a metal-insulator transition at $T_{\rm CO}=135$ K due to electronic charge ordering. We have conducted time-resolved investigations of its electronic properties…

强关联电子 · 物理学 2016-06-15 Tobias Peterseim , Tomislav Ivek , Dieter Schweitzer , Martin Dressel

We report X-ray structural studies of the metal-insulator phase transition in bismuth ferrite, BiFeO3, both as a function of temperature and of pressure (931 oC at atmospheric pressure and ca. 45 GPa at ambient temperature). Based on the…

材料科学 · 物理学 2009-02-05 S. A. T. Redfern , J. N. Walsh , S. M. Clark , G. Catalan , J. F. Scott

Although the structural phase transitions in single-crystal hybrid methyl-ammonium (MA) lead halide perovskites (MAPbX3, X = Cl, Br, I) are common phenomena, they have never been observed in the corresponding nanocrystals. Here we…

应用物理 · 物理学 2020-04-08 Yuri D. Glinka , Rui Cai , Xian Gao , Dan Wu , Rui Chen , Xiao Wei Sun

Neutron diffraction measurements of a high quality single crystal of CaFe2As2 are reported. A sharp transition was observed between the high temperature tetragonal and low temperature orthorhombic structures at TS = 172.5K (on cooling) and…

Aliovalent rare earth substitution into the alkaline earth site of CaFe2As2 single-crystals is used to fine-tune structural, magnetic and electronic properties of this iron-based superconducting system. Neutron and single crystal x-ray…

超导电性 · 物理学 2015-03-19 S. R. Saha , N. P. Butch , T. Drye , J. Magill , S. Ziemak , K. Kirshenbaum , P. Y. Zavalij , J. W. Lynn , J. Paglione

SrRh2As2 exhibits structural phase transitions reminiscent to those of BaFe2As2, but crystallizes with three polymorphs derived from the tetragonal ThCr2Si2-type structure. The structure of \alpha-SrRh2As2 is monoclinic with a = 421.2(1)…

超导电性 · 物理学 2012-02-02 V. Zinth , V. Petricek , M. Dusek , D. Johrendt

We study pressure-induced structural evolution of vanadium diselenide (VSe2), a 1T polymorphic member of the transition metal di-chalcogenide (TMD) family using synchrotron-based powder X-ray diffraction (PXRD) and first-principles density…

Ferroelectric phase transition in the semiconductor Sn2P2S6 single crystal has been studied by means of neutron scattering in the pressure-temperature range adjacent to the anticipated tricritical Lifshitz point (p=0.18GPa, T=296K). The…

The temperature dependent electrical resistivity of single crystalline SrFe2As2 and BaFe2As2 has been measured in a liquid medium, modified Bridgman anvil cell for pressures in excess of 75 kbar. These data allow for the determination of…

超导电性 · 物理学 2015-05-13 E. Colombier , S. L. Bud'ko , N. Ni , P. C. Canfield

The structural and magnetic phase transitions of the ternary iron arsenides SrFe2As2 and EuFe2As2 were studied by temperature-dependent x-ray powder diffraction and 57-Fe Moessbauer spectroscopy. Both compounds crystallize in the tetragonal…

The temperature-dependent phase transitions in Ruddlesden-Popper oxides with perovskite bilayers have been under increased scrutiny in recent years due to the so-called hybrid improper ferroelectricity that some chemical compositions…

The organic salt $\alpha$-(BEDT-TTF)$_2$I$_3$ is considered a model system for metal-insulator transition due to electronic charge ordering at $T_{\rm CO}=135$~K. The optical properties obtained from polarized reflection measurements above…

强关联电子 · 物理学 2016-03-25 T. Peterseim , M. Dressel

We measured the pressure dependence of in-plane resistivity $\rho_{ab}$ in the recently-discovered iron-based superconductor Ca$_{10}$(Ir$_{4}$As$_{8}$)(Fe$_{2-x}$Ir$_{x}$As$_{2}$)$_{5}$, which shows a unique structural phase transition in…

We present a group theoretical analysis of the superconducting state of the Bechgaard salts, e.g., (TMTSF)_2PF_6 or (TMTSF)_2ClO_6. We show that there are eight symmetry distinct superconducting states. Of these only the (fully gapped, even…

超导电性 · 物理学 2008-08-08 B. J. Powell

A magneto-structural phase transition is investigated in single crystal CrN thin films grown by rf plasma molecular beam epitaxy on MgO(001) substrates. While still within the vacuum environment following MBE growth, $\it in-situ$…

We present high pressure electrical transport, magnetization, and single crystal X-ray diffraction data on SrCo2P2 single crystals. X-ray diffraction data show that there is a transition to a collapsed tetragonal structure for p ~> 10 GPa…

Single crystals of the new ternary compound Ce2Ga12Pt were prepared by the self-flux technique. The crystal structure with the space group P4/nbm was established from single-crystal X-ray diffraction data and presents a derivative of the…

强关联电子 · 物理学 2012-06-12 Olga Sichevych , Cornelius Krellner , Yuri Prots , Yuri Grin , Frank Steglich

High-energy x-ray diffraction experiments peformed on rhombohedral (1-x)Pb(Zn1/3Nb2/3)O3-xPbTiO3(PZN-xPT) crystals with x= 4.5 and 8% show that an electric field applied along the [001] direction induces the tetragonal phase, as proposed by…

材料科学 · 物理学 2009-11-07 B. Noheda , Z. Zhong , D. E. Cox , G. Shirane , S-E. Park , P. Rehring