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We present an analytic model of thermal state-to-state rotationally inelastic collisions of polar molecules in electric fields. The model is based on the Fraunhofer scattering of matter waves and requires Legendre moments characterizing the…

化学物理 · 物理学 2008-07-09 Mikhail Lemeshko , Bretislav Friedrich

We examine the effects of a linearly polarized nonresonant radiative field on the dynamics of rotationally inelastic $\text{Na}^{+} + \text{N}_2$ collisions at eV collision energies. Our treatment is based on the Fraunhofer model of matter…

化学物理 · 物理学 2009-01-20 Mikhail Lemeshko , Bretislav Friedrich

We present an accurate quantum mechanical study of molecule-molecule collisions in the presence of a magnetic field. The work focusses on the analysis of elastic scattering and spin relaxation in collisions of O2(3Sigma_g) molecules at cold…

原子物理 · 物理学 2012-02-06 T. V. Tscherbul , Yu. V. Suleimanov , V. Aquilanti , R. V. Krems

We present a theoretical study of the impact of an electric field combined with a magnetic field on the rotational dynamics of open shell diatomic molecules. Within the rigid rotor approximation, we solve the time-independent Schr\"odinger…

化学物理 · 物理学 2015-06-12 Martin Gärttner , Juan J. Omiste , Peter Schmelcher , Rosario González-Férez

We investigate the collisional stability of magnetically trapped ultracold molecules, taking into account the influence of magnetic fields. We compute elastic and spin-state-changing inelastic rate constants for collisions of the prototype…

量子物理 · 物理学 2009-11-07 Alessandro Volpi , John L. Bohn

We use accurate quantum mechanical calculations to analyze the effects of parallel electric and magnetic fields on collision dynamics of OH(2Pi) molecules. It is demonstrated that spin relaxation in 3He-OH collisions at temperatures below…

原子物理 · 物理学 2012-02-06 Timur V. Tscherbul , Gerrit C. Groenenboom , Roman V. Krems , Alex Dalgarno

We present a microscopic model for nanoparticles, of the maghemite ($\gamma $% -Fe$_{2}$O$_{3}$) type, and perform classical Monte Carlo simulations of their magnetic properties. On account of M\"{o}ssbauer spectroscopy and high-field…

材料科学 · 物理学 2009-10-31 H. Kachkachi , A. Ezzir , M. Nogues , E. Tronc

We develop an analytic model of thermal state-to-state rotationally inelastic collisions of asymmetric-top molecules with closed-shell atoms in electric fields, and apply it to the Ar--H$_2$O collision system. The predicted cross sections…

化学物理 · 物理学 2010-01-05 Mikhail Lemeshko , Bretislav Friedrich

We consider collisions of electric and magnetic polar molecules, taking the OH radical as an example, subject to combined electric and magnetic static fields. We show that the relative orientation of the fields has an important effect on…

原子物理 · 物理学 2013-07-16 Goulven Quéméner , John L. Bohn

We have generalized the BOUND and MOLSCAT packages to allow calculations in basis sets where the monomer Hamiltonians are off-diagonal and used the new capability to carry out bound-state and scattering calculations on 3He-NH and 4He-NH as…

原子物理 · 物理学 2009-03-25 Maykel Leonardo Gonzalez-Martinez , Jeremy M. Hutson

When two collisionless plasma shells collide, they interpenetrate and the overlapping region may turn Weibel unstable for some values of the collision parameters. This instability grows magnetic filaments which, at saturation, have to block…

等离子体物理 · 物理学 2020-06-03 A Bret , M E Dieckmann

We have carried out bound-state and low-energy quantum scattering calculations on He + NH (triplet Sigma) in magnetic fields, with the NH molecule in its n=1 rotationally excited states. We have explored the pattern of levels as a function…

化学物理 · 物理学 2007-07-31 R. Adam Rowlands , Maykel Leonardo Gonzalez-Martinez , Jeremy M. Hutson

We present quantum-theoretical studies of collisions between an open-shell S-state atom and a ^2Pi-state molecule in the presence of a magnetic field. We analyze the collisional Hamiltonian and discuss possible mechanisms for inelastic…

Rigorous quantum scattering calculations on ultracold molecular collisions in external fields present an outstanding computational problem due to strongly anisotropic atom-molecule interactions that depend on the relative orientation of the…

原子物理 · 物理学 2020-12-03 Masato Morita , Jacek Kłos , Timur V. Tscherbul

We use numerically exact quantum dynamics calculations to demonstrate universal stereoselectivity of cold collisions of $^2\Pi$ molecules with $^1$S-state atoms in an external electric field. We show that cold collisions of OH molecules in…

原子物理 · 物理学 2021-06-29 Timur V. Tscherbul , Jacek Kłos

We theoretically study slow collisions of NH$_3$ molecules with He atoms, where we focus in particular on the observation of scattering resonances. We calculate state-to-state integral and differential cross sections for collision energies…

Helium atoms in the metastable $2^3{S_{1}}$ state (He$^*$) have unique advantages for ultracold atomic experiments. However, there is no known accessible Feshbach resonance in He$^*$, which could be used to manipulate the scattering length…

量子气体 · 物理学 2021-09-29 T. M. F. Hirsch , D. G. Cocks , S. S. Hodgman

We study the dynamics of paramagnetic molecular superrotors in an external magnetic field. Optical centrifuge is used to create dense ensembles of oxygen molecules in ultra-high rotational states. It is shown for the first time, that the…

量子物理 · 物理学 2015-06-10 A. A. Milner , A. Korobenko , J. Floß , I. Sh. Averbukh , V. Milner

We report numerically exact quantum scattering calculations on magnetic Feshbach resonances in ultracold, strongly anisotropic atom-molecule [Rb($^2$S) + SrF($^2\Sigma^+$)] collisions based on state-of-the-art ab initio potential energy…

We calculate the interaction potential between N atoms and NH molecules and use it to investigate cold and ultracold collisions important for sympathetic cooling. The ratio of elastic to inelastic cross sections is large over a wide range…

化学物理 · 物理学 2011-02-23 Piotr S. Żuchowski , Jeremy M. Hutson
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