相关论文: Growth of Oxide Compounds under Dynamic Atmosphere…
We present a density-functional theory based Wulff construction of the equilibrium shape of RuO2 particles in an oxygen environment. The obtained intricate variations of the crystal habit with the oxygen chemical potential allow for a…
Terrestrial-like exoplanets may obtain atmospheres from three primary sources: Capture of nebular gases, degassing during accretion, and degassing from subsequent tectonic activity. Here we model degassing during accretion to estimate the…
In materials that are exposed to thermodynamic potential gradients, i.e., gradients of chemical potentials, electrical potential, temperature, or pressure, transport processes of the mobile components occur. These transport processes and…
Atmospheric compositions for rocky exoplanets will depend strongly on the bulk planetary composition and the orbital position of the planet. Non-traditional gases may be present in the atmospheres of exceptionally hot planets. Atmospheres…
Differential settling and growth of dust grains impact the structure of the radiative envelopes of gaseous planets during formation. Sufficiently rapid dust growth can result in envelopes with substantially reduced opacities for radiation…
In this chapter we outline some of the basic understanding of the chemistry that accompanies planet formation. We discuss the basic physical environment which dictates the dominant chemical kinetic pathways for molecule formation. We focus…
New observing capabilities coming online over the next few years will provide opportunities for characterization of exoplanet atmospheres. However, clouds/hazes could be present in the atmospheres of many exoplanets, muting the amplitude of…
A magma ocean (MO) is thought to be a ubiquitous stage in the early evolution of rocky planets and exoplanets. During the lifetime of the MO, exchanges between the interior and exterior envelopes of the planet are very efficient. In…
The ratio of nitrogen isotopes in the Martian atmosphere is a key constraint on the planet's atmospheric evolution. However, enrichment of the heavy isotope expected due to atmospheric loss from sputtering and photochemical processes is…
Mn doped GaAs thin films were grown using molecular beam epitaxy at high and low substrate temperatures. The elemental concentration depth profiles in the thin films were determined by using Auger electron spectroscopy combined with ion…
Upcoming studies of extrasolar gas giants will give precise insights into the composition of planetary atmospheres with the ultimate goal to link it to the formation history of the planet. Here, we investigate how drifting and evaporating…
We discuss the chemical pre-conditions for planet formation, in terms of gas and ice abundances in a protoplanetary disk, as function of time and position, and the resulting chemical composition and cloud properties in the atmosphere when…
At high pressure, the typical behavior of elements dictated by the periodic table - including oxidation numbers, stoichiometries in compounds, and reactivity, to name but a few - is altered dramatically. As pressure is applied, the…
Using density-functional theory (DFT) we calculate the Gibbs free energy to determine the lowest-energy structure of a RuO_2(110) surface in thermodynamic equilibrium with an oxygen-rich environment. The traditionally assumed stoichiometric…
As the characterization of exoplanet atmospheres proceeds, providing insights into atmospheric chemistry and composition, a key question is how much deeper into the planet we might be able to see from its atmospheric properties alone. For…
We provide estimates of atmospheric pressure and surface composition on short-period rocky exoplanets with dayside magma pools and silicate vapor atmospheres. Atmospheric pressure tends toward vapor-pressure equilibrium with surface magma,…
Understanding the possible climatic conditions on rocky extrasolar planets, and thereby their potential habitability, is one of the major subjects of exoplanet research. Determining how the climate, as well as potential atmospheric…
Under high pressure, krypton, one of the most inert elements is predicted to become sufficiently reactive to form a new class of krypton compounds; krypton oxides. Using modern ab-initio evolutionary algorithms in combination with Density…
We examine the physical processes which are involved in the formation and stability of the anomalous states of water reported recently. The initial step of adding a small amount of ionic compound XY to pure water leads to the formation of…
This chapter provides an overview of the basic concepts foundational to atmospheric physics and chemistry. We discuss the retention of atmospheres against thermal evaporation and the global energy balance of planets. We present simple…