相关论文: Adiabatic orientation of rotating dipole molecules…
We have experimentally and theoretically investigated the mixed-field orientation of rotational-state-selected OCS molecules and we achieve strong degrees of alignment and orientation. The applied moderately intense nanosecond laser pulses…
A beam of rotating dipolar particles (molecules or clusters) will broaden when passed through an electric or magnetic field gradient region. This broadening, which is a common experimental observable, can be expressed in terms of the…
We present a theoretical study of recent laser-alignment and mixed-field-orientation experiments of asymmetric top molecules. In these experiments, pendular states were created using linearly polarized strong ac electric fields from pulsed…
A scheme of adiabatic cross-polarization is described. It is based on demagnetization - remagnetization, when the Zeeman order of abundant nuclei in the laboratory frame is first adiabatically converted into the dipolar order, and then,…
It is experimentally demonstrated that an adiabatic demagnetization - remagnetization scheme, where the Zeeman order of abundant nuclei is first adiabatically converted into the dipolar order, and then, into the Zeeman order of rare nuclei,…
The adiabatic motion of a charged, spinning, quantum particle in a two - dimensional magnetic field is studied. A suitable set of operators generalizing the cinematical momenta and the guiding center operators of a particle moving in a…
We show that combined electrostatic and radiative fields can greatly amplify the directional properties, such as axis orientation and alignment, of symmetric top molecules. In our computational study, we consider all four symmetry…
The mixed-field orientation of an asymmetric-rotor molecule with its permanent dipole moment non-parallel to the principal axes of polarizability is investigated experimentally and theoretically. We find that for the typical case of a…
In a Stark decelerator, polar molecules are slowed down and focussed by an inhomogeneous electric field which switches between two configurations. For the decelerator to work, it is essential that the molecules follow the changing electric…
We study the growth dynamics of ordered structures of strongly interacting polar molecules in optical lattices. Using dipole blockade of microwave excitations, we map the system onto an interacting spin-1/2 model possessing ground states…
Continuum or discrete polarizable models for the study of optoelectronic processes in embedded subsystems rely mostly on the restriction of the surrounding electronic dielectric response to its low frequency limit. Such a description hinges…
The vibronic mixing by an odd-parity vibrational mode of two opposite-parity nearly-degenerate electronic states at a molecular site may drive the small polaron off-center. An associated electric dipole may occur due to broken inversion…
Small lattice bipolarons driven by external harmonic fields are considered in the adiabatic approximation. Resonant excitation of ions modulates the trapping potential and promotes hole transfer between neighboring atomic layers. It leads…
We review some of the few available nonadiabatic calculations of dipole moments. We show that those carried out in a laboratory-fixed set of coordinate axes are bound to fail and discuss the more reasonable ones in a molecule-fixed…
We consider the adiabatic demagnetization in the rotating reference frame (ADRF) of a system of dipolar coupled nuclear spins $s=1/2$ in the external magnetic field. The demagnetization starts with the offset of the external magnetic field…
We examine the potential-energy curves and polarization of the dipole moments of two static polar molecules under the influence of an external dc electric field and their anisotropic dipole-dipole interaction. We model the molecules as…
Proposals for quantum computing using rotational states of polar molecules as qubits have previously considered only diatomic molecules. For these the Stark effect is second-order, so a sizable external electric field is required to produce…
We present a theoretical study of the impact of an electrostatic field combined with non-resonant linearly polarized laser pulses on the rotational dynamics of linear molecules. Within the rigid rotor approximation, we solve the…
If the photon energy is much less than the electron binding energy, ionization of an atom by a strong optical field is often described in terms of electron tunneling through the potential barrier resulting from the superposition of the…
We present generalized adiabatic theorems for closed and open quantum systems that can be applied to slow modulations of rapidly varying fields, such as oscillatory fields that occur in optical experiments and light induced processes. The…