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It is important to be able to calculate the moist-air entropy of the atmosphere with precision. A potential temperature has already been defined from the third law of thermodynamics for this purpose. However, a doubt remains as to whether…

大气与海洋物理 · 物理学 2019-05-28 Pascal Marquet

Heat, work and entropy production: the statistical distribution of such quantities are constrained by the fluctuation theorems (FT), which reveal crucial properties about the nature of non-equilibrium dynamics. In this paper we report…

量子物理 · 物理学 2021-10-15 K. Khan , J. Sales Araújo , W. F. Magalhães , G. H. Aguilar , B. de Lima Bernardo

Building on work of Kontsevich, we introduce a definition of the entropy of a finite probability distribution in which the "probabilities" are integers modulo a prime p. The entropy, too, is an integer mod p. Entropy mod p is shown to be…

数论 · 数学 2020-12-03 Tom Leinster

We generalize the weighted cumulative entropies (WCRE and WCE), introduced in [5], for a system or component lifetime. Representing properties of cumulative entropies, several bounds and inequalities for the WCRE is proposed

信息论 · 计算机科学 2015-07-28 Yuri Suhov , Salimeh Yasaei Sekeh

It is shown that the structure of thermodynamics is "form invariant", when it is derived using maximum entropy principle for various choices of entropy and even beyond equilibrium. By the form invariance of thermodynamics, it is meant that…

量子物理 · 物理学 2015-11-12 Avijit Misra , Uttam Singh , Manabendra Nath Bera , A. K. Rajagopal

We present a general framework for systems which are prepared in a non-stationary non-equilibrium state in the absence of any perturbation, and which are then further driven through the application of a time-dependent perturbation. We…

统计力学 · 物理学 2012-12-06 Gatien Verley , David Lacoste

We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy (H-function) is not just a Lyapunov function…

统计力学 · 物理学 2015-05-13 H. -H. Hasegawa , J. Ishikawa , K. Takara , D. J. Driebe

Starting for the Stillinger and Weber expression for the free energy of supercooled liquids, we extend the free energy to the case in which two time scales separate and the system is in quasi-equilibrium. The concept of an effective…

软凝聚态物质 · 物理学 2012-11-26 Antonio Scala , Francesco Sciortino

We consider a previously proposed non-extensive statistical mechanics in which the entropy depends only on the probability, this was obtained from a f(\beta) distribution and its corresponding Boltzmann factor. We show that the first term…

统计力学 · 物理学 2016-10-24 Octavio Obregón , J. Torres-Arenas , A. Gil-Villegas

The notion of group entropy is proposed. It enables to unify and generalize many different definitions of entropy known in the literature, as those of Boltzmann-Gibbs, Tsallis, Abe and Kaniadakis. Other new entropic functionals are…

统计力学 · 物理学 2015-05-28 Piergiulio Tempesta

Some general considerations on the notion of entropy in physics are presented. An attempt is made to clarify the question of the differentiation between physical entropy (the Clausius-Boltzmann one) and quantities called entropies…

统计力学 · 物理学 2007-05-23 Roberto Luzzi , Áurea R. Vasconcellos , J. Galvão Ramos

The aim of the present paper is to present a careful and accessible discussion of the formal aspects of Boltzmann-Gibbs and Tsallis entropies. We begin with a brief overview of Boltzmann-Gibbs entropy, highlighting its main properties and…

统计力学 · 物理学 2025-10-23 Kelvin dos Santos Alves , Rogerio Teixeira Cavalcanti

Entropy might be a not well defined concept if the system can undergo transformations involving stationary nonequilibria. It might be analogous to the heat content (once called ``caloric'') in transformations that are not isochoric (i.e.…

统计力学 · 物理学 2007-05-23 Giovanni Gallavotti

Entropy production is the crucial quantity characterizing irreversible phenomena and the second law of thermodynamics. Yet, a ubiquitous definition eludes consensus. Given that entropy production arises from incomplete access to…

量子物理 · 物理学 2024-08-26 Adalberto D. Varizi , Pedro S. Correia

In this simple article, with possible applications in theoretical and applied physics, we suggest an original way to derive the expression of Shannon's entropy from a purely variational approach,using constraints. Based on the work of Edwin…

统计力学 · 物理学 2021-07-13 Thomas Cailleteau

It has long been known that the relative entropy of a non-equilibrium ensemble to the corresponding equilibrium ensemble is the excess free energy. We show that the reverse relative entropy also has a thermodynamic interpretation: it is the…

统计力学 · 物理学 2026-02-18 Gavin E. Crooks

Topological entropy is a widely studied indicator of chaos in topological dynamics. Here we give a generalized definition of topological entropy which may be applied to set-valued functions. We demonstrate that some of the well-known…

动力系统 · 数学 2015-09-29 James Kelly , Tim Tennant

Here we deconstruct, and then in a reasoned way reconstruct, the concept of "entropy of a system," paying particular attention to where the randomness may be coming from. We start with the core concept of entropy as a COUNT associated with…

综合物理 · 物理学 2017-05-10 Tommaso Toffoli

Partial complementary energy densities are introduced through partial Legendre transforms from the strain energy density of linear elasticity. They have mixed components of the strain and stress tensors. Mixed variational principles based…

经典物理 · 物理学 2024-09-30 Jiashi Yang

We consider viscous, heat conducting mixtures of molecularly miscible chemical species forming a fluid in which the constituents can undergo chemical reactions. Assuming a common temperature for all components, we derive a closed system of…

流体动力学 · 物理学 2016-04-01 Dieter Bothe , Wolfgang Dreyer
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