相关论文: Surface-induced First Order Transition in Athermal…
The papers [1,2] consider unbinding of a disordered heteropolymer. They find the first order phase transition [1] when disorder is strong (i.e. the ratio v of the binding energies is large; in DNA v is~1.1) and the Griffiths singularity,…
The problem of first order phase transitions in nanoscopic systems is investigated in the framework of Hill's nanothermodynamics. We obtain the equilibrium conditions and a generalized version of the Clapeyron-Clausius equation for a…
We apply a modified mean-field density functional theory to determine the phase behavior of Stockmayer fluids in slitlike pores formed by two walls with identical substrate potentials. Based on the Carnahan-Starling equation of state, a…
The effect of topology on the collapse transition and instantaneous shape of an energy polydisperse polymer (a model heteropolymer) is studied by means of computer simulations. In particular, we consider three different chain topology,…
The rheology of coextruded layered films of polystyrene/poly(methyl methacrylate) (PS/PMMA) has been studied with small and large amplitude oscillations at a temperature above their glass transition. While the complex viscosity remains…
When out-of-equilibrium particles interact by means of pairwise forces, their stationary distribution in general exhibits many-body interactions. In the particular case of active particles, it has been shown numerically that the Motility…
We study different scenarios of topological phase transitions in the vicinity of the \pi^0 condensation point in neutron matter. The transitions occur between the Fermi-liquid state and a topologically different one with two sheets of the…
We consider the effect of droplet excitations in the random first order transition theory of glasses on the configurational entropy. The contribution of these excitations is estimated both at and above the ideal glass transition…
The origin of the non commutativity of the limits $t \to \infty$ and $N \to \infty$ in the dynamics of first order transitions is investigated. In the large-N model, i.e. $N \to \infty$ taken first, the low temperature phase is…
Supercooled liquids give rise, by homogeneous nucleation, to solid superclusters acting as building blocks of glass, ultrastable glass, and glacial glass phases before being crystallized. Liquid-to-liquid phase transitions begin to be…
We study a model of phantom tethered membranes, embedded in three-dimensional space, by extensive Monte Carlo simulations. The membranes have hexagonal lattice structure where each monomer is interacting with six nearest-neighbors (NN).…
Polymer-grafted nanoparticles (PGNPs) can provide property profiles than cannot be obtained individually by polymers or nanoparticles (NPs). Here, we have studied the mixing--demixing transition of symmetric copolymer melts of…
It has been well established that particulate systems show the jamming transition and critical scaling behaviors associated with it. However, our knowledge is limited to (nearly) monodisperse systems. Recently, a binary mixture of jammed…
First-order phase transitions exist in many models beyond the Standard Model and can generate detectable stochastic gravitational waves for a strong one. Using the cosmological observables in big bang nucleosynthesis and cosmic microwave…
Large scale molecular dynamics simulations are used to study the dispersion of nanoparticles (NPs) in a polymer film during solvent evaporation. As the solvent evaporates, a dense polymer-rich skin layer forms at the liquid/vapor interface,…
We study first order phase transitions that occur when the temperature of the system increases and we identify the conditions that lead to super-heating, a phase where the system can heat up arbitrarily. First order phase transitions with…
By taking advantage of the molecular weight dependence of the glass transition of polymers and their ability to form perfectly miscible blends, we propose a way to modify the fragility of a system, from fragile to strong, keeping the same…
In this work we discuss the measurement protocols for indirect determination of the isothermal entropy change associated with first order phase transitions in caloric materials. The magneto- structural phase transitions giving rise to giant…
The transport of polymers with folded configurations across membrane pores is investigated theoretically by analyzing simple discrete stochastic models. The translocation dynamics is viewed as a sequence of two events: motion of the folded…
Using exact enumeration methods and Monte Carlo simulations we study the phase diagram relative to the conformational transitions of a two dimensional diblock copolymer. The polymer is made of two homogeneous strands of monomers of…