相关论文: Dissociation and ionization of small molecules ste…
The modern era in spectral line broadening began with the understanding that the slow(quasistatic) ion and fast(impact) electron perturbers could be treated separately. The problem remained of unifying these two theoretical limits. A scheme…
A new microscopic approach to the optical transitions in quantum dots and quantum dot molecules, which accounts for both diagonal and non-diagonal exciton-phonon interaction, is developed. The cumulant expansion of the linear polarization…
We analyze the classical phase space of the hydrogen atom in crossed magnetic and circularly polarized microwave fields in the high frequency regime, using the Chirikov resonance overlap criterion and the renormalization map. These methods…
Photoionized and electronically excited ethylene \ce{C2H4+} can undergo \ce{H}-loss, \ce{H2}-loss, and ethylene-ethylidene isomerization, where the latter entails a hydrogen migration. Recent pioneering experiments with few-femtosecond…
We investigate the quantum many-body dynamics of dissociation of a Bose-Einstein condensate of molecular dimers into pairs of constituent bosonic atoms and analyze the resulting atom-atom correlations. The quantum fields of both the…
We perform molecular dynamics simulations driven by accurate Quantum Monte Carlo forces on dense liquid hydrogen. Recently it has been reported a complete atomization transition between a mixed-atomic liquid and a completely dissociated…
Full $NVT$ quantum statistics of the H$_3^+$ ion is simulated at low densities using the path integral Monte Carlo approach. For the first time, the molecular total energy, partition function, free energy, entropy and heat capacity are…
Bodies in relative motion, spatially separated in vacuum, experience a tiny friction force known as quantum friction. This force has eluded experimental detection so far due to its small magnitude and short range. Herein, we give…
Coherently displaced harmonic oscillator number states of a harmonically bound ion can be coupled to two internal states of the ion by a laser-induced motional sideband interaction. The internal states can subsequently be read out in a…
We investigated the pressure dependence of gas flow and field ion intensity of a coaxial ion source operating at room temperature over a wide pressure range, testing various gases and ionisation voltages. Flow conductance measurements…
The angular distribution of the emitted electrons, following the two-photon ionization of the hydrogen-like ions, is studied within the framework of second order perturbation theory and the Dirac equation. Using a density matrix approach,…
Double ionization of an atom by single-photon absorption in the presence of a neighbouring atom is studied. The latter is, first, resonantly photoexcited and, afterwards, transfers the excitation energy radiationlessly to the other atom,…
We study the electron-impact induced ionization of O$_{2}$ from threshold to 120 eV using the electron spectroscopy method. Our approach is simple in concept and embodies the ion source with a collision chamber and a mass spectrometer with…
We discuss the influence of periodic orbits on the dissociation of a model diatomic molecule driven by a strong bichromatic laser fields. Through the stability of periodic orbits we analyze the dissociation probability when parameters like…
Noise measurements are a probe beyond simple electronic transport that can reveal additional information about electronic correlations and inelastic processes. Here we report noise measurements in individual electromigrated nanojunctions,…
We present analytical and numerical results for the microwave excitation of nonhydrogenic atoms in a static electric field when up to 1000 photons are required to ionize an atom. For small microwave fields, dynamical localization in photon…
We consider charge transport through a nanoscopic object, e.g. single molecules, short nanotubes, or quantum dots, that is weakly coupled to metallic electrodes. We account for several levels of the molecule/quantum dot with level-dependent…
Revelation of the effects of isotope fractionation during fragmentation in electron ionization mass spectrometry (EI-MS) on compound-specific isotope analysis of chlorine and bromine (CSIA-Cl/Br) may be of crucial significance, yet a…
High magnetic fields in neutron stars, B ~ 10^{11} - 10^{13} G, substantially modify the properties of atoms and their interaction with radiation. In particular, the photoionization cross section becomes anisotropic and strongly…
Fundamental studies of the effect of specific ions on hydrophobic interactions are driven by the need to understand phenomena such as hydrophobically driven self-assembly or protein folding. Using beta-peptide-inspired nano-rods, we…