相关论文: Microcanonical phase transitions in small systems

By making use of a recently proposed framework for the inference of thermodynamic irreversibility in bosonic quantum systems, we experimentally measure and characterize the entropy production rates in the non-equilibrium steady state of two…

We develop a generalized hyperdynamics method, which is able to simulate slow dynamics in atomistic general (both energy and entropy-dominated) systems. We show that a few functionals of the pair correlation function, involving two-body…

We show how the dependence of phase space volume $\Omega(N)$ of a classical system on its size $N$ uniquely determines its extensive entropy. We give a concise criterion when this entropy is not of Boltzmann-Gibbs type but has to assume a…

A general formulation of stochastic thermodynamics is presented for open systems exchanging energy and particles with multiple reservoirs. By introducing a partition in terms of "macrostates" (e.g. sets of "microstates"), the consequence on…

The efficiency of microscopic heat engines in a thermally heterogenous environment is considered. We show that, as a consequence of the recently discovered entropic anomaly, quasi-static engines, whose efficiency is maximal in a fluid at…

Two-dimensional electrostatic turbulence in magnetized weakly-collisional plasmas exhibits a cascade of entropy in phase space [Phys. Rev. Lett. 103, 015003 (2009)]. At scales smaller than the gyroradius, this cascade is characterized by…

We reaccess the droplet condensation-evaporation transition of a three-dimensional Lennard-Jones system upon a temperature change. With the help of parallel multicanonical simulations we obtain precise estimates of the transition…

Particle motion at the micro-scale is an incessant tug-of-war between thermal fluctuations and applied forces on one side, and the strong resistance exerted by fluid viscosity on the other. Friction is so strong that completely neglecting…

It is shown that the vacuum-like energy of the Higgs potential at non-zero temperatures leads, in the course of the cosmological expansion, to a small but non-negligible rise of the entropy density in the comoving volume. This increase is…

The theory of small-system thermodynamics was originally developed to extend the laws of thermodynamics to length scales of nanometers. Here we review this "nanothermodynamics," and stress how it also applies to large systems that subdivide…

According to the recently obtained thermodynamic uncertainty relation, the microcanonical regions with a negative heat capacity can be accessed within a canonical-like description by using a thermostat with a fluctuating inverse…

Transitions between ``glassy'' local minima of a model free-energy functional for a dense hard-sphere system are studied numerically using a ``microcanonical'' Monte Carlo method that enables us to obtain the transition probability as a…

Mesoscopic density functional theory for inhomogeneous mixtures of sperical particles is developed in terms of mesoscopic volume fractions by a systematic coarse-graining procedure starting form microscopic theory. Approximate expressions…

Concepts of everyday use like energy, heat, and temperature have acquired a precise meaning after the development of thermodynamics. Thermodynamics provides the basis for understanding how heat and work are related and with the general…

We present a maximum entropy approach to analyze the internal dynamics of a small system in contact with a large bath e.g. a solute-solvent system. For the small solute, the fluctuations around the mean values of observables are not…

We present general and rigorous results showing that the microcanonical and canonical ensembles are equivalent at all three levels of description considered in statistical mechanics - namely, thermodynamics, equilibrium macrostates, and…

In the current work we revisit the pair-potential recently proposed by Wang et al. (Phys. Chem. Chem. Phys. 10624, 22, 2020) as a well defined finite-range alternative to the widely used Lennard-Jones interaction model. The advantage of…

It is shown that the von Neumann entropy, a measure of quantum entanglement, does have its classical counterpart in thermodynamic systems, which we call partial entropy. Close to the critical temperature the partial entropy shows perfect…

The quest for a microscopic foundation of Thermodynamics is addressed within the Nonunitary Newtonian Gravity model through the study of a specific closed system, namely a three-dimensional harmonic nanocrystal. A numerical calculation of…

We describe microcanonical phase transitions and instabilities of the ideal Fermi gas in general relativity at nonzero temperature confined in the interior of a spherical shell. The thermodynamic behaviour is governed by the compactness of…