软凝聚态物质
Nanoconfinement reduces the favorable hydration free energies of single ions, which is correlated with ion rejection and modified chemical reactivity in water-filled nanopores. Many factors contribute to the magnitude of the observed…
Colloidal gels form through the sol-gel transition of attractive particle suspensions, where local aggregation leads to a space-spanning network with solid-like properties. Their microstructure and mechanical properties are highly sensitive…
Fluid filled pipes are ubiquitous in both man-made constructions and living organisms. In the latter, biological pipes, such as arteries, have unique properties as their walls are made of soft, incompressible, highly deformable materials.…
In a ferroelectric nematic liquid crystal, the electrostatic interaction can induce a spontaneous cholesteric helix, even if the material is not chiral. If the liquid-crystal cell is infinitely thick, then the predicted pitch depends…
There has been much recent interest in the chiral motion of achiral particles that sediment in a viscous fluid in a regime where inertial effects can be neglected. This occurs in a broad range of applications such as those involving…
The present work emphasizes the relevance of low-field NMR relaxometry to investigate colloid-polymer hydrogels by probing water dynamics across a wide range of formulations between $\rm 10^{\circ}C$ and $\rm 80^{\circ}C$. By examining the…
Cellulose ethers represent a class of water-soluble polymers widely utilized across diverse sectors, spanning from healthcare to the construction industry. This experimental study specifically delves into aqueous suspensions of…
Soft Glassy Materials (SGM) consist in dense amorphous assemblies of colloidal particles of multiple shapes, elasticity, and interactions, which confer upon them solid-like properties at rest. They are ubiquitously encountered in modern…
Shear thickening denotes the reversible increase in viscosity of a suspension of rigid particles under external shear. This ubiquitous phenomenon has been documented in a broad variety of multiphase particulate systems, while its…
Liquid-liquid crystal phase separation (LLCPS) occurs in many industrial and biological settings. To date the states of the separated condensed liquid crystals have been found to be nematic, columnar, or smectic phases. Interestingly, when…
The emergence of long-range spatiotemporal order from intrinsic chaos is a central challenge in far-from-equilibrium physics. In active fluids, such as cytoskeletal networks driving cellular motion, self-generated flows typically produce…
Entropic forces play a fundamental role in nanoscale phenomena, from colloidal self-assembly to biomolecular disaggregation. Here, we develop an exact analytical theory and find general scaling laws for the entropic separation of…
We investigate the effect of flow kinematics on the extensional viscosity of dilute polymer solutions by conducting dissipative particle dynamics simulations under uniaxial, planar, and biaxial extensional flows. At high extension rates,…
Non-active disordered solids feature quasilocalized excitations that control plasticity, similar to crystal lattice defects, and these excitations can be identified via harmonic or anharmonic analyses of the potential energy landscape. Here…
Charged colloidal particles can self-assemble into gel networks upon screening of electrostatic repulsion by added salt. While gelation of spherical colloids has been extensively studied, much less is known about the gelation dynamics of…
Coarse-grain Lagrangian methods, such as Dissipative Particle Dynamics ( Hoogerbrugge et al., EPL, 1992), are suitable for describing mesoscopic fluid systems that include thermal fluctuations. However, the realistic simulation of liquids…
The statistical "monomer-based" segment length $b$ and the Kuhn length $l_k$ are central to polymer physics, yet the minimal size required for a truly statistical segment - Gaussian, uncorrelated, and valid as an entropic spring - is not…
We investigate how symmetry, exact coherent structures (ECSs), and their invariant manifolds organize spontaneous flow reversals in a 2D active nematic confined to a periodic channel. In minimal flow units commensurate with the intrinsic…
Viscosity calculation from equilibrium molecular dynamics (MD) simulations relies on the traditional Green-Kubo (GK) framework, which integrates the stress autocorrelation function (SACF) over time. While the formalism is exact in the…
Using extensive Monte Carlo (MC) and molecular dynamics (MD) simulations, we investigate how spatial confinement affects molecular organization within thin films of the nematic twist-bend ($\mathrm{N_{TB}}$) phase. Our simulations show that…