端基为联苯基的聚炔烃（α,ω-联苯基聚炔）的合成与表征
材料科学
2018-03-20 v2
摘要
利用 Cadiot-Chodkiewicz 反应条件，通过简单的一步法合成了以联苯端基封端的稳定聚炔链（α,ω-联苯基聚炔）。经 HPLC 分析分离 α,ω-联苯基聚炔，并借助其电子吸收光谱进行鉴定。通过 FT-IR 与拉曼光谱研究 α,ω-联苯基聚炔，并以 DFT 计算支撑光谱指认。观察到 α,ω-联苯基聚炔与臭氧反应活性异常低。
引用
@article{arxiv.1803.03504,
title = {Synthesis And Characterization Of Polyynes End-Capped By Biphenyl Groups ({\Alpha},{\Omega}-Biphenylpolyynes)},
author = {Franco Cataldo and Ornella Ursini and Alberto Milani and Carlo S. Casari},
journal= {arXiv preprint arXiv:1803.03504},
year = {2018}
}
备注
The research leading to these results has received funding from the European Research Council Consolidator Grant EspLORE (ERC-2016-CoG Grant No.724610)