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Molecular process of polymer collapse was reproduced by isothermal molecular dynamics simulation. The initial polymer chains were obtained by mean of random walks in continuum space. Two potential models were considered to represent short…

Soft Condensed Matter · Physics 2007-05-23 S. A. Sabeur , F. Hamdache , M. Bouarkat

Systems of globally coupled logistic maps (GCLM) can display complex collective behaviour characterized by the formation of synchronous clusters. In the dynamical clustering regime, such systems possess a large number of coexisting…

Disordered Systems and Neural Networks · Physics 2009-11-07 Susanna C. Manrubia , Ugo Bastolla , Alexander S. Mikhailov

The scaling behavior of a directed polymer in a two-dimensional (2D) random potential under confining force is investigated. The energy of a polymer with configuration $\{y(x)\}$ is given by $H\big(\{y(x)\}\big) = \sum_{x=1}^N \exyx +…

Statistical Mechanics · Physics 2009-11-11 Hyeong-Chai Jeong

This study deals with polymer looping, an important process in many chemical and biological systems. We investigate basic questions on the looping dynamics of a polymer under tension using the freely-jointed chain (FJC) model. Previous…

Statistical Mechanics · Physics 2024-10-03 Wout Laeremans , Anne Floor den Ouden , Jef Hooyberghs , Wouter G. Ellenbroek

We investigate the properties of a system of semi-diluted polymers in the presence of charged groups and counter-ions, by means of self-consistent field theory. We study a system of polyelectrolyte chains grafted to a similarly, as well as…

Soft Condensed Matter · Physics 2015-05-19 Gabriele Migliorini

We present a new simulation technique to study systems of polymers functionalized by reactive sites that bind/unbind forming reversible linkages. Functionalized polymers feature self-assembly and responsive properties that are unmatched by…

Soft Condensed Matter · Physics 2018-04-18 Bernardo Oyarzún , Bortolo Matteo Mognetti

We consider the unbinding of a directed polymer in a random media from a wall in $d=1+1$ dimensions and a simple one-dimensional model for DNA unzipping. Using the replica trick we show that the restricted partition functions of these…

Statistical Mechanics · Physics 2007-05-23 Yariv Kafri , Anatoli Polkovnikov

Self-assembled linear structures like giant cylindrical micelles or discotic molecules in solution stacked in flexible columns are systems reminiscent of polydisperse polymer solutions.These supramolecular polymers have an equilibrium…

Soft Condensed Matter · Physics 2015-06-25 C-C Huang , H. Xu , F. Crevel , J. Wittmer , J. -P. Ryckaert

We calculate the mean end-to-end distance ($R$) of a self-avoiding polymer encapsulated in an infinitely long cylinder with radius $D$. A self-consistent perturbation theory is used to calculate $R$ as a function of $D$ for impenetrable…

Soft Condensed Matter · Physics 2016-08-31 G. Morrison , D. Thirumalai

A conceptual difficulty in the Hooke's-law description of ideal Gaussian polymer-chain elasticity is sometimes apparent in analyses of experimental data or in physical models designed to simulate the behavior of biopolymers. The problem,…

Biological Physics · Physics 2009-09-25 Richard M. Neumann

We investigate the kinetics of a polymer collapse due to the formation of irreversible crosslinks between its monomers. Using the contact probability $P(s)$ as a scale-dependent order parameter depending on the chemical distance $s$, our…

Soft Condensed Matter · Physics 2018-08-15 Vittore F. Scolari , Guillaume Mercy , Romain Koszul , Annick Lesne , Julien Mozziconacci

We consider the complex polymer system, consisting of ring polymer connected to the $f_1$-branched star-like structure, in good solvent in presence of structural inhomogeneities. We assume, that structural defects are correlated at large…

Soft Condensed Matter · Physics 2018-03-14 K. Haydukivska , V. Blavatska

We present a kinetic model of crystal growth of polymers of finite molecular weight. Experiments help to classify polymer crystallization broadly into two kinetic regimes. One is observed in melts or in high molar mass polymer solutions and…

Soft Condensed Matter · Physics 2009-11-11 Arindam Kundagrami , M. Muthukumar

The longitudinal response of single semiflexible polymers to sudden changes in externally applied forces is known to be controlled by the propagation and relaxation of backbone tension. Under many experimental circumstances, realized, e.g.,…

Soft Condensed Matter · Physics 2011-02-25 Florian Thüroff , Benedikt Obermayer , Erwin Frey

A copolymer is a chain of repetitive units (monomers) that are almost identical, but they differ in their degree of affinity for certain solvents. This difference leads to striking phenomena when the polymer fluctuates in a nonhomogeneous…

Probability · Mathematics 2010-11-11 Francesco Caravenna , Giambattista Giacomin

The spatial correlations of entangled polymer dynamics are examined by molecular dynamics simulations and neutron spin-echo spectroscopy. Due to the soft nature of topological constraints, the initial spatial decays of intermediate…

The rupture of a polymer chain maintained at temperature $T$ under fixed tension is prototypical to a wide array of systems failing under constant external strain and random perturbations. Past research focused on analytic and numerical…

Soft Condensed Matter · Physics 2021-03-03 Harish Charan , Alex Hansen , H. G. E. Hentschel , Itamar Procaccia

We perform simulations to compute the effective potential between the centers-of-mass of two polymers with reversible bonds. We investigate the influence of the topology of the unbonded precursor (linear or ring) and the specific sequence…

Soft Condensed Matter · Physics 2022-05-04 Mariarita Paciolla , Christos N. Likos , Angel J. Moreno

We study the unfolding of a single polymer chain due to an external force. We use a simplified model which allows to perform all calculations in closed form without assuming a Boltzmann-Gibbs form for the equilibrium distribution.…

Statistical Mechanics · Physics 2009-11-13 Erik Van der Straeten , Jan Naudts

We develop a new, dynamical field theory of isotropic randomly branched polymers, and we use this model in conjunction with the renormalization group (RG) to study several prominent problems in the physics of these polymers. Our model…

Statistical Mechanics · Physics 2015-05-14 Hans-Karl Janssen , Olaf Stenull