The shape of a flexible polymer in a cylindrical pore
Soft Condensed Matter
2016-08-31 v1
Abstract
We calculate the mean end-to-end distance () of a self-avoiding polymer encapsulated in an infinitely long cylinder with radius . A self-consistent perturbation theory is used to calculate as a function of for impenetrable hard walls and soft walls. In both cases, obeys the predicted scaling behavior in the limit of large and small . The crossover from the three dimensional behavior () to the fully stretched one dimensional case () is non-monotonic. The minimum value of is found at , where is the Flory radius of at . The results for soft walls map onto the hard wall case with a larger cylinder radius.
Keywords
Cite
@article{arxiv.cond-mat/0504031,
title = {The shape of a flexible polymer in a cylindrical pore},
author = {G. Morrison and D. Thirumalai},
journal= {arXiv preprint arXiv:cond-mat/0504031},
year = {2016}
}
Comments
8 pages, 2 figures, to be published in the Journal of Chemical Physics