English

The shape of a flexible polymer in a cylindrical pore

Soft Condensed Matter 2016-08-31 v1

Abstract

We calculate the mean end-to-end distance (RR) of a self-avoiding polymer encapsulated in an infinitely long cylinder with radius DD. A self-consistent perturbation theory is used to calculate RR as a function of DD for impenetrable hard walls and soft walls. In both cases, RR obeys the predicted scaling behavior in the limit of large and small DD. The crossover from the three dimensional behavior (DD\to\infty) to the fully stretched one dimensional case (D0D\to 0) is non-monotonic. The minimum value of RR is found at D0.46RFD\sim 0.46 R_F, where RFR_F is the Flory radius of RR at DD \to \infty. The results for soft walls map onto the hard wall case with a larger cylinder radius.

Keywords

Cite

@article{arxiv.cond-mat/0504031,
  title  = {The shape of a flexible polymer in a cylindrical pore},
  author = {G. Morrison and D. Thirumalai},
  journal= {arXiv preprint arXiv:cond-mat/0504031},
  year   = {2016}
}

Comments

8 pages, 2 figures, to be published in the Journal of Chemical Physics