English

Dimensional cross-over of hard parallel cylinders confined on cylindrical surfaces

Soft Condensed Matter 2015-06-16 v1 Statistical Mechanics

Abstract

We derive, from the dimensional cross-over criterion, a fundamental-measure density functional for parallel hard curved rectangles moving on a cylindrical surface. We derive it from the density functional of circular arcs of length σ\sigma with centers of mass located on an external circumference of radius R0R_0. The latter functional in turns is obtained from the corresponding 2D functional for a fluid of hard discs of radius RR on a flat surface with centers of mass confined onto a circumference of radius R0R_0. Thus the curved length of closest approach between two centers of mass of hard discs on this circumference is σ=2R0sin1(R/R0)\sigma=2R_0\sin^{-1}(R/R_0), the length of the circular arcs. From the density functional of circular arcs, and by applying a dimensional expansion procedure to the spatial dimension orthogonal to the plane of the circumference, we finally obtain the density functional of curved rectangles of edge-lengths σ\sigma and LL. The DF for curved rectangles can also be obtained by fixing the centers of mass of parallel hard cylinders of radius RR and length LL on a cylindrical surface of radius R0R_0. The phase behavior of a fluid of aligned curved rectangles is obtained by calculating the free-energy branches of smectic, columnar and crystalline phases for different values of the ratio R0/RR_0/R in the range 1<R0/R41<R_0/R\leq 4; the smectic phase turns out to be the most stable except for R0/R=4R_0/R=4 where the crystalline phase becomes reentrant in a small range of packing fractions. When R0/R<1R_0/R<1 the transition is absent, since the density functional of curved rectangles reduces to the 1D Percus functional.

Keywords

Cite

@article{arxiv.1305.4257,
  title  = {Dimensional cross-over of hard parallel cylinders confined on cylindrical surfaces},
  author = {Yuri Martinez-Raton and Enrique Velasco},
  journal= {arXiv preprint arXiv:1305.4257},
  year   = {2015}
}

Comments

27 pages, 6 figures