Dimensional cross-over of hard parallel cylinders confined on cylindrical surfaces
Abstract
We derive, from the dimensional cross-over criterion, a fundamental-measure density functional for parallel hard curved rectangles moving on a cylindrical surface. We derive it from the density functional of circular arcs of length with centers of mass located on an external circumference of radius . The latter functional in turns is obtained from the corresponding 2D functional for a fluid of hard discs of radius on a flat surface with centers of mass confined onto a circumference of radius . Thus the curved length of closest approach between two centers of mass of hard discs on this circumference is , the length of the circular arcs. From the density functional of circular arcs, and by applying a dimensional expansion procedure to the spatial dimension orthogonal to the plane of the circumference, we finally obtain the density functional of curved rectangles of edge-lengths and . The DF for curved rectangles can also be obtained by fixing the centers of mass of parallel hard cylinders of radius and length on a cylindrical surface of radius . The phase behavior of a fluid of aligned curved rectangles is obtained by calculating the free-energy branches of smectic, columnar and crystalline phases for different values of the ratio in the range ; the smectic phase turns out to be the most stable except for where the crystalline phase becomes reentrant in a small range of packing fractions. When the transition is absent, since the density functional of curved rectangles reduces to the 1D Percus functional.
Keywords
Cite
@article{arxiv.1305.4257,
title = {Dimensional cross-over of hard parallel cylinders confined on cylindrical surfaces},
author = {Yuri Martinez-Raton and Enrique Velasco},
journal= {arXiv preprint arXiv:1305.4257},
year = {2015}
}
Comments
27 pages, 6 figures