English

Density functional for hard hyperspheres from a tensorial-diagrammatic series

Soft Condensed Matter 2015-05-27 v1 Statistical Mechanics

Abstract

We represent the free energy functional by a diagrammatic series with tensorial coefficients indexed by powers of length scale. For hard cores, we obtain Percus' exact functional in one dimension and the Kierlik-Rosinberg form of fundamental measures theory in three dimensions. In five dimensions, the functional describes bulk fluids better than Percus-Yevick theory does. At planar walls density profiles oscillate with smaller periods than in lower dimensions. Our findings open up avenues for treating both more general high-dimensional systems, as well as three-dimensional mixtures via dimensional reduction.

Keywords

Cite

@article{arxiv.1101.3868,
  title  = {Density functional for hard hyperspheres from a tensorial-diagrammatic series},
  author = {Gavin Leithall and Matthias Schmidt},
  journal= {arXiv preprint arXiv:1101.3868},
  year   = {2015}
}

Comments

12 pages, 4 figures