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Generalizations of the microcanonical and canonical ensembles for paths of Markov processes have been proposed recently to describe the statistical properties of nonequilibrium systems driven in steady states. Here we propose a theory of…

Statistical Mechanics · Physics 2013-09-18 Raphael Chetrite , Hugo Touchette

In this paper, we draw attention to the problem of phase transitions in systems with locally affine microcanonical entropy, in which partial equivalence of (microcanonical and canonical) ensembles is observed. We focus on a very simple spin…

Statistical Mechanics · Physics 2020-02-19 Agata Fronczak , Piotr Fronczak , Grzegorz Siudem

Thermodynamics and its quantum counterpart are traditionally described with statistical ensembles. Canonical typicality has related statistical mechanics for a system to ensembles of global energy eigen- states of system and its environment…

Quantum Physics · Physics 2024-05-13 Sebastian Gemsheim , Jan M. Rost

It is generally believed that, in the thermodynamic limit, the microcanonical description as a function of energy coincides with the canonical description as a function of temperature. However, various examples of systems for which the…

Statistical Mechanics · Physics 2016-01-13 Tiziano Squartini , Joey de Mol , Frank den Hollander , Diego Garlaschelli

The microcanonical ensemble has long been a starting point for the development of thermodynamics from statistical mechanics. However, this approach presents two problems. First, it predicts that the entropy is only defined on a discrete set…

Statistical Mechanics · Physics 2017-06-07 William Griffin , Michael Matty , Robert H. Swendsen

The grand canonical ensemble lies at the core of quantum and classical statistical mechanics. A small system thermalizes to this ensemble while exchanging heat and particles with a bath. A quantum system may exchange quantities represented…

Quantum Physics · Physics 2016-07-25 Nicole Yunger Halpern , Philippe Faist , Jonathan Oppenheim , Andreas Winter

We reconsider some general aspects about the mean field thermodynamical description of the astrophysical systems based on the microcanonical ensemble. Starting from these basis, we devote a special attention to the analysis of the scaling…

Statistical Mechanics · Physics 2007-05-23 L. Velazquez , F. Guzman

The sensitivity of the Statistical Multifragmentation Model to the underlying statistical assumptions is investigated. We concentrate on its micro-canonical, canonical, and isobaric formulations. As far as average values are concerned, our…

Nuclear Theory · Physics 2009-11-11 C. E. Aguiar , R. Donangelo , S. R. Souza

According to thermodynamics, the specific heat of Boltzmannian short-range interacting systems is a positive quantity. Less intuitive properties are instead displayed by systems characterized by long-range interactions. In that case, the…

Statistical Mechanics · Physics 2015-05-18 F. Staniscia , A. Turchi , D. Fanelli , P. H. Chavanis , G. De Ninno

This work explores fundamental statistical and thermodynamic properties of short-and long-range-interacting systems. The purpose of this study is twofold. Firstly, we rigorously prove that the probability distribution of arbitrary few-body…

Statistical Mechanics · Physics 2020-08-19 Tomotaka Kuwahara , Keiji Saito

The phenomenon of partial equivalence of statistical ensembles is illustrated by discussing two examples, the mean-field XY and the mean-field spherical model. The configurational parts of these systems exhibit partial equivalence of the…

Statistical Mechanics · Physics 2007-09-25 Lapo Casetti , Michael Kastner

In the field of classical discrete systems, specifically substitutional alloys, this study introduces a stochastic thermodynamic approach to address nonlinearity within a canonical ensemble. This approach establishes a nonlinear…

Statistical Mechanics · Physics 2025-12-15 Koretaka Yuge

We develop a regularization of the quantum microcanonical ensemble, called a Gaussian ensemble, which can be used for derivation of the canonical ensemble from microcanonical principles. The derivation differs from the usual methods by…

Statistical Mechanics · Physics 2008-11-26 Jani Lukkarinen

Particle number fluctuations are studied in the microcanonical ensemble. For the Boltzmann statistics we deduce exact analytical formulae for the microcanonical partition functions in the case of non-interacting massless neutral particles…

Nuclear Theory · Physics 2009-11-10 V. V. Begun , M. I. Gorenstein , A. P. Kostyuk , O. S. Zozulya

Equilibrium statistics of finite Hamiltonian systems is fundamentally described by the microcanonical ensemble (ME). Canonical, or grand-canonical partition functions are deduced from this by Laplace transform. Only in the thermodynamic…

Nuclear Theory · Physics 2008-11-26 D. H. E. Gross

We study the equivalence of microcanonical and canonical ensembles in continuous systems, in the sense of the convergence of the corresponding Gibbs measures. This is obtained by proving a local central limit theorem and a local large…

Statistical Mechanics · Physics 2017-08-02 Nicoletta Cancrini , Stefano Olla

Systems with long range interactions in general are not additive, which can lead to an inequivalence of the microcanonical and canonical ensembles. The microcanonical ensemble may show richer behavior than the canonical one, including…

Statistical Mechanics · Physics 2015-06-24 Freddy Bouchet , Julien Barre

In bulk systems the calculation of the main thermodynamic quantities leads to the same expectation values in the thermodynamic limit, regardless of the choice of the statistical ensemble. Single linear molecules can be still regarded as…

Soft Condensed Matter · Physics 2013-05-29 M. Süzen , M. Sega , C. Holm

The isoscaling parameter usually denoted by $\alpha$ depends upon both the symmetry energy coefficient and the isotopic contents of the dissociating systems. We compute $\alpha$ in theoretical models: first in a simple mean field model and…

Nuclear Theory · Physics 2008-11-26 G. Chaudhuri , S. Das Gupta , M. Mocko

Standard results for the fluctuations of thermodynamic quantities are derived under the assumption of sampling identical systems that are in different, not fully equilibrated states. These results apply to fluctuations with time in a…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 R. A. Serota