Can one measure negative specific heat in the canonical statistical ensemble?
Abstract
According to thermodynamics, the specific heat of Boltzmannian short-range interacting systems is a positive quantity. Less intuitive properties are instead displayed by systems characterized by long-range interactions. In that case, the sign of specific heat depends on the considered statistical ensemble: negative specific heat can be found in isolated systems, which are studied in the framework of the microcanonical ensemble; on the other hand, it is generally recognized that a positive specific heat should always be measured in systems in contact with a thermal bath, for which the canonical ensemble is the appropriate one. We demonstrate that the latter assumption is not generally true: one can in principle measure negative specific heat also in the canonical ensemble if the system under scrutiny is non-Boltzmannian and/or out-of-equilibrium.
Keywords
Cite
@article{arxiv.1003.0631,
title = {Can one measure negative specific heat in the canonical statistical ensemble?},
author = {F. Staniscia and A. Turchi and D. Fanelli and P. H. Chavanis and G. De Ninno},
journal= {arXiv preprint arXiv:1003.0631},
year = {2015}
}
Comments
5 pages, 3 figures