Related papers: Statistical Ensembles and Spectral Correlations in…
Ensemble inequivalence has been observed in several systems. In particular it has been recently shown that negative specific heat can arise in the microcanonical ensemble in the thermodynamic limit for systems with long-range interactions.…
We calculate the corrections due to noncommutativity of space on the Hamiltonian and then partition function of the canonical ensemble. We study some basic features of statistical mechanics and thermodynamics including equipartition and…
It is common knowledge that the microcanonical, canonical, and grand-canonical ensembles are equivalent in thermodynamically large systems. Here, we study finite-size effects in the latter two ensembles. We show that contrary to naive…
For quantum systems that are weakly coupled to a much 'bigger' environment, thermalization of possibly far from equilibrium initial ensembles is demonstrated: for sufficiently large times, the ensemble is for all practical purposes…
The canonical statistics describes the statistical properties of an open system by assuming its coupling with the heat bath infinitesimal in comparison with the total energy in thermodynamic limit. In this paper, we generally derive a…
We compute the internal energy of different Ising type models, both long-range and short-range, under Tsallis statistics using the microcanonical and the canonical ensembles and we discuss under which conditions both ensembles give…
This short paper presents a nontechnical introduction to the problem of nonequivalent microcanonical and canonical ensembles. Both the thermodynamic and the macrostate levels of definition of nonequivalent ensembles are introduced. The many…
Mesoscale forecasts are now routinely performed as elements of operational forecasts and their outputs do appear convincing. However, despite their realistic appearance at times the comparison to observations is less favorable. At the grid…
The two-body potential of systems with long-range interactions decays at large distances as $V(r)\sim 1/r^\alpha$, with $\alpha\leq d$, where $d$ is the space dimension. Examples are: gravitational systems, two-dimensional hydrodynamics,…
The equivalence of thermodynamic results in the canonical and the microcanonical ensembles has been questioned in some calculations for spin models with long-range interactions. We show that these claims of inequivalence are related to an…
We addressed the problem of generalizing the extensive postulates of the standard thermodynamics in order to extend it to the study of nonextensive systems. We did it in analogy with the traditional analysis, starting from the…
For models which exhibit a continuous phase transition in the thermodynamic limit a numerical study of small systems reveals a non-monotonic behaviour of the microcanonical specific heat as a function of the system size. This is in contrast…
It has recently been shown, by application of statistical mechanical methods to determine the canonical ensemble governing the equilibrium distribution of operator initial values, that complex quantum field theory can emerge as a…
We address the problem of the foundation of generalized ensembles in statistical physics. The approach is based on Boltzmann's concept of orthodes. These are the statistical ensembles that satisfy the heat theorem, according to which the…
The so-called $\chi^{2}$-superstatistics of Beck and Cohen (BC) is employed to investigate the infinite-range Blume-Capel model, a well-known representative system displaying inequivalence of canonical and microcanonical phase diagrams.…
Completely open systems can exchange heat, work, and matter with the environment. While energy, volume, and number of particles fluctuate under completely open conditions, the equilibrium states of the system, if they exist, can be…
Shortened abstract: Microcanonical equilibrium macrostates are characterized as the solutions of a constrained minimization problem, while canonical equilibrium macrostates are characterized as the solutions of a related, unconstrained…
How does an electrochemical interface respond to changes in the electrode potential? How does the response affect the key properties of the system - energetics, excess charge, capacitance? Essential questions key to ab-initio simulations of…
Focusing on isolated macroscopic systems, described either in terms of a quantum mechanical or a classical model, our two key questions are: In how far does an initial ensemble (usually far from equilibrium and largely unknown in detail)…
A theoretical scheme for the treatment of an open molecular system with electrons and nuclei is proposed. The idea is based on the Grand Canonical description of a quantum region embedded in a classical reservoir of molecules. Electronic…