English

Partial equivalence of statistical ensembles and kinetic energy

Statistical Mechanics 2007-09-25 v1

Abstract

The phenomenon of partial equivalence of statistical ensembles is illustrated by discussing two examples, the mean-field XY and the mean-field spherical model. The configurational parts of these systems exhibit partial equivalence of the microcanonical and the canonical ensemble. Furthermore, the configurational microcanonical entropy is a smooth function, whereas a nonanalytic point of the configurational free energy indicates the presence of a phase transition in the canonical ensemble. In the presence of a standard kinetic energy contribution, partial equivalence is removed and a nonanalyticity arises also microcanonically. Hence in contrast to the common belief, kinetic energy, even though a quadratic form in the momenta, has a non-trivial effect on the thermodynamic behaviour. As a by-product we present the microcanonical solution of the mean-field spherical model with kinetic energy for finite and infinite system sizes.

Keywords

Cite

@article{arxiv.cond-mat/0701339,
  title  = {Partial equivalence of statistical ensembles and kinetic energy},
  author = {Lapo Casetti and Michael Kastner},
  journal= {arXiv preprint arXiv:cond-mat/0701339},
  year   = {2007}
}

Comments

21 pages, 11 figures