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Single crystal synthesis, structure, electric polarization and heat capacity measurements on hexagonal InMnO3 show that this small R ion in the RMnO3 series is ferroelectric (space group P63cm). Structural analysis of this system reveals a…

Materials Science · Physics 2015-06-15 T. Yu , P. Gao , T. Wu , T. A. Tyson , R. Lalancette

The crystallographic and magnetic properties of the cleavable 4d3 transition metal compound a-MoCl3 are reported, with a focus on the behavior above room temperature. Crystals were grown by chemical vapor transport and characterized using…

We have investigated temperature and magnetic-field dependence of dielectric properties in the orthorhombic GdMnO$_3$ single crystal which is located near the phase boundary between the ferroelectric/spiral-antiferromagnetic phase and the…

Strongly Correlated Electrons · Physics 2009-11-13 H. Kuwahara , M. Akaki , J. Tozawa , M. Hitomi , K. Noda , D. Akahoshi

The novel field-induced re-entrant phase in multiferroic hexagonal HoMnO3 is investigated to lower temperatures by dc magnetization, ac susceptibility, and specific heat measurements at various magnetic fields. Two new phases have been…

Strongly Correlated Electrons · Physics 2009-11-10 B. Lorenz , F. Yen , M. M. Gospodinov , C. W. Chu

We report the magnetic susceptibility, specific heat and dielectric constant on high purity polycrystalline samples of three hexagonal manganites: YMnO_3, LuMnO_3 and ScMnO_3. These materials can exhibit a ferroelectric transition at very…

Materials Science · Physics 2007-05-23 D. G. Tomuta , S. Ramakrishnan , G. J. Nieuwenhuys , J. A. Mydosh

Hexagonal YMnO_3 with space group P63cm is one of the rare examples of multiferroic materials that exhibit co-dependence of a robust ferroelectric phase along with antiferromagnetic ordering. This is primarily ascribed to tilting of the…

Strongly Correlated Electrons · Physics 2010-05-25 A. K. Singh , S. D. Kaushik , V. Siruguri , S. Patnaik

Liquid crystal materials exhibiting up to three nematic phases are reported. Dielectric response measurements show that while the lower temperature nematic phase has ferroelectric order and the highest temperature nematic phase is apolar,…

Soft Condensed Matter · Physics 2021-09-07 S. Brown , E. Cruickshank , J. M. D. Storey , C. T. Imrie , D. Pociecha , M. Majewska , A. Makal , E. Gorecka

We have investigated magnetoelastic effects in multiferroic YMnO$_3$ below the antiferromagnetic phase transition, $T_N \approx 70$ K, using neutron powder diffraction. The $a$ lattice parameter of the hexagonal unit cell of YMnO$_3$…

Strongly Correlated Electrons · Physics 2012-12-24 Tapan Chatterji , Bachir Ouladdiaf , Paul F. Henry , Dipten Bhattacharya

We report on the growth and functional characterization of epitaxial thin films of the multiferroic YMnO3. We show that using Pt as a seed layer on SrTiO3(111) substrates, epitaxial YMnO3 films (0001) textured are obtained. An atomic force…

High resolution ultrasonic velocity measurements have been used to determine the temperature -- magnetic-field phase diagram of the monoclinic multiferroic CuO. A new transition at TN3 = 230 K, corresponding to an intermediate state between…

Materials Science · Physics 2015-03-20 R. Villarreal , G. Quirion , M. L. Plumer , M. Poirier , T. Usui , T. Kimura

We report on the high-temperature evolution of far- and mid- infrared reflectivity and emissivity spectra of ambient orthorhombic ErMnO3 from 12 K to sample decomposition above 1800 K. At low temperatures the number of phonons agrees with…

Strongly Correlated Electrons · Physics 2018-11-13 Néstor E. Massa , Leire del Campo , Karsten Holldack , Vinh Ta Phuoc , Patrick Echegut , Paula Kayser , José Antonio Alonso

Magneto-structural phase transition in FeRh epitaxial layers was studied optically. It is shown that the transition between the low-temperature antiferromagnetic phase and the high-temperature ferromagnetic phase is accompanied by a rather…

Materials Science · Physics 2016-08-31 V. Saidl , M. Brajer , L. Horak , H. Reichlova , K. Vyborny , M. Veis , T. Janda , F. Trojanek , I. Fina , X. Marti , T. Jungwirth , P. Nemec

Motivated by the recent neutron diffraction experiment on $YVO_3$, we consider a microscopic model where each $V^{3+}$ ion is occupied by two 3d electrons of parallel spins with two fold degenerate orbital configurations. The mean field…

Strongly Correlated Electrons · Physics 2007-05-23 Theja N. De Silva , Anuvrat Joshi , Michael Ma , Fu Chun Zhang

BiFeO3 (BFO) multiferroic oxide has a complex phase diagram that can be mapped by appropriately substrate-induced strain in epitaxial films. By using Raman spectroscopy, we conclusively show that films of the so-called supertetragonal T-BFO…

Materials Science · Physics 2011-08-16 J. Kreisel , P. Jadhav , O. Chaix-Pluchery , M. Varela , N. Dix , F. Sanchez , J. Fontcuberta

We show that in YVO3 new hard phonons gradually become zone center active below ~210 K verifying that a lattice phase transition takes place at about that temperature. The Debye-Waller factor found from EXAFS measurements show an additional…

The orthovanadate DyVO3 crystal, known to exhibit multiple structural, spin and orbital ordering transitions, is presently investigated on the basis of magnetization, heat capacity, resistivity, dielectric and polarization measurements. Our…

Strongly Correlated Electrons · Physics 2014-07-24 Q. Zhang , K. Singh , C. Simon , L. D. Tung , G. Balakrishnan , V. Hardy

The lattice dynamics of the $\rm YMnO_3$ magneto-electric compound has been investigated using density functional calculations, both in the ferroelectric and the paraelectric phases. The coherence between the computed and experimental data…

Materials Science · Physics 2012-03-09 Julien Varignon , Sébastien Petit , Marie-Bernadette Lepetit

Dielectric spectroscopy of $SrTiO_3$ single crystal over a broad range of microwave frequency using quasi $TE_{m,1,1}$ and quasi $TM_{m,1,1}$ modes reveals crystal asymmetry from typical measurement of $Q$-factor, transmission or frequency…

Materials Science · Physics 2025-05-22 M. A. Hosain , J-M. Le Floch , J. F. Bourhill , J. Krupka , M. E. Tobar

We report on the microwave, terahertz (THz), infrared and Raman spectroscopic studies of $BiMn_{7}O_{12}$ ceramics, shedding more light into the nature of two structural phase transitions and their possible relation with ferroelectricity in…

Materials Science · Physics 2024-01-08 A. Maia , M. Kempa , V. Bovtun , R. Vilarinho , C. Kadlec , J. Agostinho Moreira , A. A. Belik , P. Proschek , S. Kamba

We report a Raman scattering investigation of KTa1-xNbxO3 (x = 0.35, 0.5) thin films deposited on MgO and LaAlO3 as a function of temperature. The observed phase sequence in the range from 90 K to 720 K is similar to the structural phase…

Materials Science · Physics 2010-07-16 A. Bartasyte , J. Kreisel , W. Peng , M. Guilloux-Viry