We have investigated magnetoelastic effects in multiferroic YMnO3 below the antiferromagnetic phase transition, TN≈70 K, using neutron powder diffraction. The a lattice parameter of the hexagonal unit cell of YMnO3 decreases normally above TN, but decreases anomalously below TN, whereas the c lattice parameter increases with decreasing temperature and then increases anomalously below TN. The unit cell volume also undergoes an anomalous contraction below TN. By fitting the background thermal expansion for a non-magnetic lattice with the Einstein-Gr\"uneisen equation, we determined the lattice strains Δa, Δc and ΔV due to the magnetoelastic effects as a function of temperature. We have also determined the temperature variation of the ordered magnetic moment of the Mn ion by fitting the measured Bragg intensities of the nuclear and magnetic reflections with the known crystal and magnetic structure models and have established that the lattice strain due to the magnetoelastic effect in YMnO3 couples with the square of the ordered magnetic moment or the square of the order parameter of the antiferromagnetic phase transition.
@article{arxiv.1207.0301,
title = {Magnetoelastic effects in multiferroic YMnO$_3$},
author = {Tapan Chatterji and Bachir Ouladdiaf and Paul F. Henry and Dipten Bhattacharya},
journal= {arXiv preprint arXiv:1207.0301},
year = {2012}
}