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Raman scattering experiments have been carried out on single crystals of Nd$_{0.5}$Sr$_{0.5}$MnO$_3$ as a function of temperature in the range of 320-50 K, covering the paramagnetic insulator-ferromagnetc metal transition at 250 K and the…

Materials Science · Physics 2007-05-23 Md. Motin Seikh , A. K. Sood , Chandrabhas Narayana

High temperature powder neutron diffraction experiments have been conducted around the reported beta-gamma, insulator-metal phase transition (~ 930 C) in BiFeO3. The results demonstrate that while a small volume contraction is observed at…

We present the results of transmittance experiments on GdMnO3 multiferroic manganite in the far infrared frequency range. The spectra allow to obtain the positions and the intensity of the high frequency electromagnon (~ 75 cm-1) in this…

Strongly Correlated Electrons · Physics 2026-01-06 A. Shuvaev , F. Mayr , A. Loidl , A. A. Mukhin , A. Pimenov

We have investigated the dielectric properties of Gd$_{1-x}$Tb$_{x}$MnO$_{3}$ crystals in magnetic fields to clarify the crossover between two distinct ferroelectric phases, GdMnO$_{3}$-type (first-order displacive) and TbMnO$_{3}$-type…

Strongly Correlated Electrons · Physics 2009-11-11 K. Noda , S. Nakamura , H. Kuwahara

The floating-zone method with different growth ambiances has been used to selectively obtain hexagonal or orthorhombic DyMnO$_{3}$ single crystals. The crystals were characterized by X-ray powder diffraction of ground specimen and a…

Strongly Correlated Electrons · Physics 2009-11-13 S Harikrishnan , S Roessler , C M Naveen Kumar , H L Bhat , U K Roessler , S Wirth , F Steglich , Suja Elizabeth

We report the temperature dependent THz to mid-infrared response of hexagonal-ErMnO3 using absorption, reflectivity, and emissivity techniques from 2 K to 1700 K. At low temperatures, lowest frequency vibrational modes coexist with…

Experimental and theoretical studies of unusual polar, dielectric and magnetic properties of room temperature multiferroics, such as perovskites Pb(Fe$_{1/2}$Nb$_{1/2}$)O$_3$ (PFN) and Pb(Fe$_{1/2}$Ta$_{1/2}$)O$_3$ (PFT), are very…

The current controversies about the existence of an intermediate 'beta' phase of BiFeO_3 and the high temperature paraelectric 'gamma' phase are resolved by studying the sequence of ferroic transitions in 0.8BiFeO_3-0.2Pb(Fe_1/2Nb_1/2)O_3…

Materials Science · Physics 2009-06-08 Jay Prakash Patel , Anar Singh , Dhananjai Pandey

Hexagonal YMnO$_3$ is well known for the co-occurrence of ferroelectricity and antiferromagnetism at low temperatures. Using temperature-dependent spectroscopic ellipsometry at an $a$-plane oriented single crystal, we show how the…

Materials Science · Physics 2015-03-16 Steffen Richter , Stefan G. Ebbinghaus , Marius Grundmann , Rüdiger Schmidt-Grund

The novel ferroelectric-like structural transition observed in metallic LiOsO$_3$ [Y. Shi et al., Nat. Mater. 12, 1024 (2013)], has invoked many theoretical and experimental interests. In this work, we have performed polarized and…

Materials Science · Physics 2017-03-09 Feng Jin , Anmin Zhang , Jianting Ji , Kai Liu , Le Wang , Youguo Shi , Yong Tian , Xiaoli Ma , Qingming Zhang

Synchrotron x-ray powder diffraction measurements have been performed on unpoled ceramic samples of (1-x)PbMg(1/3)Nb(2/3)O3-xPbTiO3 (PMN-xPT) with 30%<= x<= 39% as a function of temperature around the morphotropic phase boundary (MPB),…

Materials Science · Physics 2009-11-07 B. Noheda , D. E. Cox , G. Shirane , Z. -G. Ye , J. Gao

The dielectric constant of multiferroic hexagonal HoMnO_3 exhibits an unprecedented diversity of anomalies at low temperatures (1.8 K< T <10 K) and under external magnetic fields related to magnetic phase transitions in the coupled system…

Strongly Correlated Electrons · Physics 2009-11-11 F. Yen , C. R. dela Cruz , B. Lorenz , Y. Y. Sun , Y. Q. Wang , M. M. Gospodinov , C. W. Chu

Specific heat studies of the Sr$_{1-x}$Ba$_x$Mn$_{1-y}$Ti$_y$O$_3$ polycrystalline samples performed by the relaxation and DSC methods over the temperature range 2 - 450 K are reported. Anomalies accompanying the…

Statistical Mechanics · Physics 2025-07-31 J. Wieckowski , A. Szewczyk , M. U. Gutowska , B. Dabrowski

We present a systematic first-principles study of the phonon spectrum of hexagonal YMnO3 in ferroelectric (multiferroic) phase. We investigated in detail the low-energy phonon modes, their dispersion, symmetry, as well as the infrared…

Materials Science · Physics 2012-07-30 Konstantin Z. Rushchanskii , Marjana Ležaić

We report on structural, magnetic, dielectric, and thermodynamic properties of (Eu:Y)MnO3 for Y doping levels 0 <= x < 1. This system resembles the multiferroic perovskite manganites RMnO3 (with R= Gd, Dy, Tb) but without the interference…

Strongly Correlated Electrons · Physics 2015-06-25 J. Hemberger , F. Schrettle , A. Pimenov , P. Lunkenheimer , V. Yu. Ivanov , A. A. Mukhin , A. M. Balbashov , A. Loidl

We report experimental evidence for pressure instabilities in the model multiferroic BiFeO3 and namely reveal two structural phase transitions around 3 GPa and 10 GPa by using diffraction and far-infrared spectroscopy at a synchrotron…

Materials Science · Physics 2011-07-26 R. Haumont , P. Bouvier , A. Pashkin , K. Rabia , S. Frank , B. Dkhil , W. A. Crichton , C. A. Kuntscher , J. Kreisel

The improper ferroelectricity in YMnO$_3$ and other related multiferroic hexagonal manganites are known to cause topologically protected ferroelectric domains that give rise to rich and diverse physical phenomena. The local structure and…

Measurements of the structure of hexagonal RMnO3 (R=rare earths (Ho) and Y) for temperatures significantly above the ferroelectric transition temperature (TFE) were conducted to determine the nature of the transition. The local and long…

Materials Science · Physics 2015-05-30 T. A. Tyson , T. Wu , H. Y. Chen , J. Bai , K. H. Ahn , K. I. Pandya , S. B. Kim , S. -W. Cheong

The authors of paper commented claim that trimethylammonium tetrachlorozincate crystal shows at 282 K the ferroelectric-paraelectric phase transition. But no ferroelectric hysteresis loop was observed below this temperature. Moreover, in…

Materials Science · Physics 2016-04-07 Zbigniew Tylczynski

Using the results of x-ray and neutron diffraction experiments, we show that the ferroelectric polarization, in ~22 nm particles of BiFeO3, exhibits a jump by ~30% around the magnetic transition point T_N (~635 K) and a suppression by ~7%…

Materials Science · Physics 2011-08-18 S. Goswami , Dipten Bhattacharya , P. Choudhury , B. Ouladdiaf , T. Chatterji