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The structural, electronic, and optical properties of twelve multicomponent oxides with layered structure, RAMO$_4$, where R$^{3+}$=In or Sc; A$^{3+}$=Al or Ga; and M$^{2+}$=Ca, Cd, Mg, or Zn, are investigated using first-principles density…

Materials Science · Physics 2015-06-03 A. Murat , J. E. Medvedeva

We present a symmetry-based calculation of the electronic structure of a compound semiconductor quantum dot (QD) in the sp^3s* tight-binding model including the spin-orbit interaction. The Hamiltonian matrix is diagonalized exactly for CdTe…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 J. Perez-Conde , A. K. Bhattacharjee

First principle calculations were performed to study the ground state electronic properties of Barium titanate within the density functional theory (DFT). In our DFT computations, we used Vosko-Wilk-Nusair correlation energy functional and…

Materials Science · Physics 2007-05-23 Hong-Jian Feng , Fa-Min Liu

This study has explored numerous physical properties of CaPd$_3$Ti$_4$O$_{1}$2 (CPTO) and CaPd$_3$V$_4$O$_{12}$ (CPVO) quadruple perovskites employing the density functional theory (DFT) method. The mechanical permanence of these two…

Post-deposition CdCl$_2$ treatment of polycrystalline CdTe is known to increase photovoltaic efficiency. However, the precise chemical, structural, and electronic changes that underpin this improvement are still debated. In this study,…

Materials Science · Physics 2018-04-06 Morgann Berg , Jason M. Kephart , Amit Munshi , Walajabad S. Sampath , Taisuke Ohta , Calvin Chan

The electronic properties of single- and multi-cation transparent conducting oxides (TCOs) are investigated using first-principles density functional approach. A detailed comparison of the electronic band structure of stoichiometric and…

Materials Science · Physics 2015-05-18 Julia E. Medvedeva , Chaminda L. Hettiarachchi

PbPdO$_2$, a ternary compound containing the lone-pair active ion Pb$^{2+}$ and the square-planar d$^8$ Pd$^{2+}$ ion, has attracted recent interest because of the suggestion that its electronic structure, calculated within density…

Materials Science · Physics 2011-11-03 Joshua A. Kurzman , Mao-Sheng Miao , Ram Seshadri

We investigate the electronic structure of ternary palladates $A$Pd$_3$O$_4$ ($A$ = Sr, Ca) using valence band photoemission spectroscopy and band structure calculations. Overall width of the valence band and energy positions of various…

Strongly Correlated Electrons · Physics 2024-04-25 B. H. Reddy , Asif Ali , Ravi Shankar Singh

A comprehensive angle resolved photoemission spectroscopy study of the band structure in single layer cuprates is presented with the aim of uncovering universal trends across different materials. Five different hole- and electron-doped…

First principles calculations were performed to study the ground state electronic properties of BaFeO3 (BFO) within the density functional theory (DFT). Adopting generalized gradient approximation (GGA) exchange and correlation functional…

Materials Science · Physics 2007-05-23 Hong-Jian Feng , Fa-Min Liu

We report the synthesis and characterization of a Si-based ternary semiconductor Mg$_3$Si$_2$Te$_6$, which exhibits a quasi-two-dimensional structure, where the trigonal Mg$_2$Si$_2$Te$_6$ layers are separated by Mg ions.…

We study a newly predicted layered-ternary compound Ti4SiN3 in its {\alpha}- and {\beta}-phases. We calculate their mechanical, electronic and optical properties and then compare these with those of other compounds M4AX3 (M = V, Ti, Ta; A =…

Materials Science · Physics 2011-08-03 M. M. Hossain , M. S. Ali , A. K. M. A. Islam

A VO2 single-crystal has been subject of a combined investigation by high resolution XPS, x-ray emission spectroscopy with electron and energy-selective x-ray excitation (V L-alpha, V K-beta-5- and O K-alpha emission) and x-ray absorption…

In$_2$Se$_3$ is a semiconductor material that can be stabilized in different crystal structures (at least one 3D and several 2D layered structures have been reported) with diverse electrical and optical properties. This feature has plagued…

1$T$-TaS$_2$ is the only insulating transition-metal dichalcogenide (TMD) with an odd number of electrons per unit cell. This insulating state is non-magnetic, making it a potential spin-liquid candidate. The unusual electronic behavior…

Strongly Correlated Electrons · Physics 2024-06-28 Amir Dalal , Jonathan Ruhman , Jörn W. F. Venderbos

Tuning the opto-electronic properties through alloying is essential for semiconductor technology. Currently, mostly isovalent and isostructural alloys are used (e.g., group-IV and III-V), but a vast and unexplored space of novel functional…

Materials Science · Physics 2014-07-02 Vladan Stevanovic , Andriy Zakutayev , Stephan Lany

By means of density functional theory the electronic structure of the MgB2 superconductor was characterised and compared with that of the related iso-structural systems: AlB2, ZrB2, NbB2, and TaB2. Using the full-potential linearized…

Superconductivity · Physics 2009-11-07 Pablo de la Mora , Miguel Castro , Gustavo Tavizon

TaTe$_4$, a metallic charge-density wave (CDW) material discovered decades ago, has attracted renewed attention due to its rich interesting properties such as pressure-induced superconductivity and candidate non-trivial topological phase.…

Strongly Correlated Electrons · Physics 2023-11-07 R. Z. Xu , X. Du , J. S. Zhou , X. Gu , Q. Q. Zhang , Y. D. Li , W. X. Zhao , F. W. Zheng , M. Arita , K. Shimada , T. K. Kim , C. Cacho , Y. F. Guo , Z. K. Liu , Y. L. Chen , L. X. Yang

The local structure of CeTe3 in the incommensurate charge density wave (IC-CDW) state has been obtained using atomic pair distribution function (PDF) analysis of x-ray diffraction data. Local atomic distortions in the Te-nets due to the CDW…

Materials Science · Physics 2009-11-11 H. J. Kim , C. D. Malliakas , A. Tomic , S. H. Tessmer , M. G. Kanatzidis , S. J. L. Billinge

We study the electronic structures and dielectric functions of the simple hydrides LiH, NaH, MgH2 and AlH3, and the complex hydrides Li3AlH6, Na3AlH6, LiAlH4, NaAlH4 and Mg(AlH4)2, using first principles density functional theory and GW…

Materials Science · Physics 2007-05-23 M. J. van Setten , V. A. Popa , G. A. de Wijs , G. Brocks