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Basing on peculiarities of local potentials, the two principal trends in vacancy formation are revealed. The proximity to the threshold of local ionic stability due to a giant potential contribution of electronic delocalization accounts for…

Materials Science · Physics 2007-05-23 Eugene V. Kholopov

We probe theoretically the emergence of strong coupling in a system consisting of a topological insulator (TI) and a III-V heterostructure using a numerical approach based on the scattering matrix formalism. Specifically, we investigate the…

Ground state properties of SiC, AlN, GaN and InN in the zinc-blende and wurtzite structures are determined using an ab initio scheme. For the self-consistent field part of the calculations, the Hartree-Fock program Crystal has been used.…

Materials Science · Physics 2009-10-30 Beate Paulus , Fa-Jian Shi , Hermann Stoll

The band alignment (BA) between two materials is a fundamental property that governs the functionality and performance of electronic, as well as electrochemical, devices. However, despite decades of study, the inability to separate surface…

Materials Science · Physics 2024-09-26 Zeyu Jiang , Damien West , Shengbai Zhang

Transistors based on III-V semiconductor materials have been used for a variety of analog and high frequency applications driven by the high electron mobilities in III-V materials. On the other hand, the hole mobility in III-V materials has…

Materials Science · Physics 2015-05-30 Aneesh Nainani , Brian. R. Bennett , J. Brad Boos , Mario G. Ancona , Krishna C. Saraswat

We report on a semi-empirical tight binding model for 3C-SiC including the effect of sp3d5s* orbitals and spin-orbital coupling. In this work, we illustrate in detail the method to develop such a model for semiconductors with zincblende…

Applied Physics · Physics 2019-01-23 Murat Onen , Marco Turchetti

In this paper, density functional theory calculations are used to explore the electronic and atomic reconstruction at interfaces between III-III/I-V oxides. In particular, at these interfaces, two dimensional electron gases (2DEGs) with…

Materials Science · Physics 2012-06-06 Valentino R. Cooper

Several amorphous silicon structures were generated using a classical molecular dynamics (MD) protocol of melting and quenching with different quenching rates. An analysis of the calculated electronic properties of these structures revealed…

Materials Science · Physics 2020-12-23 Reza Vatan Meidanshahi , Payam Mehr , Stephan Marshal Goodnick

The complex crystal chemistry of elemental boron has led to numerous proposed structures with distinctive motifs as well as contradictory findings. Herein, evolutionary structure searches performed at 100 GPa have uncovered a series of…

Materials Science · Physics 2021-05-19 Katerina P. Hilleke , Eva Zurek , Tadashi Ogitsu , Shuai Zhang

In our recent experimental work (Appl. Phys. Lett. 125, 122109 (2024)), we observed that crystalline Si$_3$N$_4$ cap layers a few nanometers thick can form in situ on GaN surfaces. Compared with amorphous SiO$_2$ and Al$_2$O$_3$ caps, these…

Materials Science · Physics 2025-12-22 Xin Chen , Xin Luo , Duo Wang , Xu Cheng , Peng Cui

The integration of III-V on silicon is still a hot topic as it will open up a way to co-integrate Si CMOS logic with photonic vices. To reach this aim, several hurdles should be solved, and more particularly the generation of antiphase…

The properties of a semiconductor get drastically modified when the crystal point group symmetry is broken under an arbitrary strain. We investigate the family of semiconductors consisting of GaAs, GaSb, InAs and InSb, considering their…

Materials Science · Physics 2016-05-24 Aslı Çakan , Cem Sevik , Ceyhun Bulutay

We report valence and conduction band alignments and offsets for heterojunctions between CdCr2Se4, an n-type ferromagnetic semiconductor, and the non-magnetic materials Si and GaAs, evaluated using density functional theory. We explore…

Materials Science · Physics 2007-05-23 J. M. Sullivan , S. C. Erwin

In IV-VI semiconductor heterojunctions with band-inversion, such as those made of Pb$_{1-x}$Sn$_{x}$Te or Pb$_{1-x}$Sn$_{x}$Se, interface states are properly described by a two-band model, predicting the appearance of a Dirac cone in single…

Mesoscale and Nanoscale Physics · Physics 2017-11-16 A. Diaz-Fernandez , Leonor Chico , F. Dominguez-Adame

The band gap engineering of group IV semiconductors has not been well explored theoretically and experimentally, except for SiGe. Recently, GeSn has attracted much attention due to the possibility of obtaining a direct band gap in this…

Materials Science · Physics 2022-03-22 Maciej P Polak , Paweł Scharoch , Robert Kudrawiec

The modeling of finite-extent semiconductor nanostructures that are embedded in a host material requires the numerical treatment of the boundary in a finite simulation domain. For the study of a self-assembled InAs dot embedded in GaAs,…

Materials Science · Physics 2009-11-10 Seungwon Lee , Fabiano Oyafuso , Paul von Allmen , Gerhard Klimeck

This work describes the development of a third-generation charge optimized many-body (COMB3) potential for Al-C and its application to the investigation of aluminum/graphene nanostructures. In particular, the new COMB3 potential was used to…

Materials Science · Physics 2019-12-04 Difan Zhang , Alexandre F. Fonseca , Tao Liang , Simon R. Phillpot , Susan B. Sinnott

A large variety of transport properties have been observed at the interface between the insulating oxides SrTiO3 and LaAlO3 such as insulation, 2D interface metallicity, 3D bulk metallicity, Kondo scattering, magnetism and…

Strongly Correlated Electrons · Physics 2008-09-08 M. Huijben , A. Brinkman , G. Koster , G. Rijnders , H. Hilgenkamp , D. H. A. Blank

We perform a first principles investigation of Si/ZnS interface properties for the [111], [100], and [110] directions, including single-substitution polar-compensated interfaces. The asymmetry of general interface directions poses known…

Materials Science · Physics 2014-10-13 David H. Foster , Guenter Schneider

We report systematic first-principles calculations for ordered zinc-blende compounds of the transition metal elements V, Cr, Mn with the sp elements N, P, As, Sb, S, Se, Te, motivated by recent fabrication of zinc-blende CrAs, CrSb, and…

Materials Science · Physics 2009-11-07 Iosif Galanakis , Phivos Mavropoulos