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We report an experimental study on the manipulation of colloidal particles in a drop sitting on a hydrogel. The manipulation is achieved by diffusiophoresis, which describes a directed motion of particles induced by solute gradients. By…

Soft Condensed Matter · Physics 2017-10-17 François Boulogne , Sangwoo Shin , Julien Dervaux , Laurent Limat , Howard A. Stone

Understanding how colloids move in crowded environments is key for gaining control over their transport in applications such as drug delivery, filtration, contaminant/microplastic remediation and agriculture. The classical models of colloid…

Soft Condensed Matter · Physics 2026-04-15 Mobin Alipour , Yiran Li , Haoyu Liu , Amir A. Pahlavan

Diffusiophoresis, a ubiquitous phenomenon that induces particle transport whenever solute concentration gradients are present, was recently observed in the context of microsystems and shown to strongly impact colloidal transport (patterning…

Predicting and controlling the transport of colloids in porous media is essential for applications ranging from contaminant remediation to drug delivery. In these complex environments, solute gradients are ubiquitous and could drive…

Soft Condensed Matter · Physics 2026-05-27 Aditya R. Pujari , Amir A. Pahlavan

Viscosity is a fundamental property of liquids and determines the diffusivity of suspended particles. A gradient in viscosity leads to a gradient in diffusivity, yet it is unknown whether such a gradient can lead to directed transport of…

Microparticles migrate in response to gradients in solute concentration through diffusiophoresis and diffusioosmosis. Merging streams of fluid with distinct solute concentrations is a common strategy for producing a steady concentration…

Fluid Dynamics · Physics 2023-06-01 Robben E. Migacz , Guillaume Durey , Jesse T. Ault

Electrolytic diffusiophoresis refers to directional migration of colloids due to interfacial forces that develop in response to local electrolytic concentration ($c$) gradients. This physicochemical transport provides an efficient…

Soft Condensed Matter · Physics 2025-06-27 Kushagra Tiwari , Jitendra Dhakar , Kapil Upadhyaya , Akash Choudhary

The more we learn about the cytoplasm of cells, the more we realise that the cytoplasm is not uniform but instead is highly inhomogeneous. In any inhomogeneous solution, there are concentration gradients, and particles move either up or…

Subcellular Processes · Quantitative Biology 2019-04-03 Richard P. Sear

In this letter, we show that pore-scale diffusiophoresis of colloidal particles along local salt gradients manifests in the macroscopic dispersion of particles in a porous medium. Despite is transient character, this microscopic phenomenon…

Soft Condensed Matter · Physics 2023-03-16 Mamta Jotkar , Pietro de Anna , Marco Dentz , Luis Cueto-Felgueroso

A colloidal particle placed in an inhomogeneous solution of smaller non-adsorbing polymers will move towards regions of lower polymer concentration, in order to reduce the free energy of the interface between the surface of the particle and…

Soft Condensed Matter · Physics 2017-12-13 Richard P. Sear , Patrick B. Warren

The separation of colloidal particles from fluids is essential to ensure a safe global supply of drinking water, yet in the case of microscopic particles, it remains a highly energy-intensive process when using traditional filtration…

Soft Condensed Matter · Physics 2026-05-12 Fernando Temprano-Coleto , Jeongmin Kim , Marcel M. Louis , Howard A. Stone

We study the diffusiophoretic self-propulsion of a colloidal catalytic particle due to a surface chemical reaction in a vicinity of a solid wall. Diffusiophoresis is a chemico-mechanical transduction mechanism in which a concentration…

Soft Condensed Matter · Physics 2016-06-22 Ali Mozaffari , Nima Sharifi-Mood , Joel Koplik , Charles Maldarelli

We study the trapping of charged particles and macromolecules (such as DNA) in salt gradients in aqueous solutions. The source for the salt gradient can be as simple as a dissolving ionic crystal, as shown by McDermott et al. [Langmuir 28,…

Soft Condensed Matter · Physics 2025-12-09 Richard P. Sear , Patrick B. Warren

In an externally imposed electrolyte (salt) concentration gradient, charged colloids drift at speeds of order one micrometre per second. This phenomenon is known as diffusiophoresis. In systems with multiple salts and 'crossed' salt…

Soft Condensed Matter · Physics 2023-11-27 Ian Williams , Patrick B. Warren , Richard P. Sear , Joseph L. Keddie

Diffusiophoresis is the spontaneous motion of particles under gradients of solutes. In electrolyte-driven diffusiophoresis, the zeta potential of the particles is an important surface property that characterizes diffusiophoretic mobility.…

Soft Condensed Matter · Physics 2022-09-30 Suin Shim , Janine K. Nunes , Guang Chen , Howard A. Stone

In this article, we study experimentally the dispersion of colloids in a two-dimensional, time independent, Rayleigh-B\'enard flow in the presence of salt gradients. Due to the additional scalar, the colloids do not follow exactly the…

Fluid Dynamics · Physics 2026-01-14 Florence Raynal , Menghua Zhao , Romain Volk

Dielectrophoresis (DEP), the motion of polarizable particles in non-uniform electric fields, has become an important tool for the transport, separation, and characterization of microparticles in biomedical and nanoelectronics research. In…

Soft Condensed Matter · Physics 2009-11-11 E. Salonen , E. Terama , I. Vattulainen , M. Karttunen

Behavior of the mixture of particles and dimers moving with different jump rates at reconstructed surfaces is described. Collective diffusion coefficient is calculated by the variational approach. Anisotropy of the collective particle…

Statistical Mechanics · Physics 2014-05-12 Marcin Mińkowski , Magdalena A. Załuska Kotur

Predicting and controlling the transport of colloids in porous media is essential for a broad range of applications, from drug delivery to contaminant remediation. Chemical gradients are ubiquitous in these environments, arising from…

Soft Condensed Matter · Physics 2026-04-13 Yiran Li , Mobin Alipour , Amir Pahlavan

In the presence of a chemically active particle, a nearby chemically inert particle can respond to a concentration gradient and move by diffusiophoresis. The nature of the motion is studied for two cases: first, a fixed reactive sphere and…

Soft Condensed Matter · Physics 2018-06-25 Shang Yik Reigh , Prabha Chuphal , Snigdha Thakur , Raymond Kapral
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