English

Diffusiophoresis and medium structure control macroscopic particle transport in porous media

Soft Condensed Matter 2023-03-16 v1 Fluid Dynamics

Abstract

In this letter, we show that pore-scale diffusiophoresis of colloidal particles along local salt gradients manifests in the macroscopic dispersion of particles in a porous medium. Despite is transient character, this microscopic phenomenon controls large-scale particle transport by altering their partitioning between transmitting and dead-end pores. It determines the distribution of residence and arrival times in the medium. Depending on the diffusiophoretic mobility, particles can be mobilized from or trapped in dead-end pores, which provides a means for the controlled manipulation of particles in porous media.

Keywords

Cite

@article{arxiv.2303.08761,
  title  = {Diffusiophoresis and medium structure control macroscopic particle transport in porous media},
  author = {Mamta Jotkar and Pietro de Anna and Marco Dentz and Luis Cueto-Felgueroso},
  journal= {arXiv preprint arXiv:2303.08761},
  year   = {2023}
}

Comments

Article: 4 figures, 6 pages. Supplementary Information: 3 figures, 6 pages