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Related papers: Internal diffraction dynamics of trilobite molecul…

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A method for diffracting the weak probe beam into unidirectional and higher-order directions is proposed via a novel Rydberg electromagnetically induced grating, providing a new way for the implementations of quantum devices with cold…

Atomic Physics · Physics 2019-03-27 Dandan Ma , Dongmin Yu Xingdong Zhao , Jing Qian

Molecular bonds can be divided into four primary types: ionic, covalent, van der Waals and hydrogen bonds. At ultralow temperatures a novel binding type emerges paving the way for novel molecules and ultracold chemistry [1,2]. The…

Quantum Physics · Physics 2008-09-18 V. Bendkowsky , B. Butscher , J. Nipper , J. P. Shaffer , R. Loew , T. Pfau

A few-body approach relying on static line broadening theory is developed to treat the spectroscopy of a single Rydberg excitation to a trilobite-like state immersed in a high density ultracold medium. The present theoretical framework…

Atomic Physics · Physics 2016-09-14 Jesús Pérez-Ríos , Matthew T Eiles , Chris H Greene

We study the impact of Rydberg molecule formation on the storage and retrieval of Rydberg polaritons in an ultracold atomic medium. We observe coherent revivals appearing in the retrieval efficiency of stored photons that originate from…

We detail the rich electronic and vibrational structure of triatomic "butterfly" molecules, ultra-long-range Rydberg molecules bound by resonant $p$-wave scattering. We divide these molecules into two sub-classes depending on their parity…

Atomic Physics · Physics 2020-04-22 Matthew T. Eiles , Christian Fey , Frederic Hummel , Peter Schmelcher

We explore the external electric field control of a species of ultralong-range molecules that emerge from the interaction of a ground state polar molecule with a Rydberg atom. The external field mixes the Rydberg electronic states and…

Atomic Physics · Physics 2012-06-01 M. Mayle , S. T. Rittenhouse , P. Schmelcher , H. R. Sadeghpour

Recent developments in the study of ultracold Rydberg gases demand an advanced level of experimental sophistication, in which high atomic and optical densities must be combined with excellent control of external fields and sensitive Rydberg…

We observe that when an ultracold ground state cesium (Cs) atom becomes bound within the electronic cloud of an extended Cs electronic orbit, ultralong-range molecules with giant (kilo-Debye) permanent electric dipole moments form. Large…

Atomic Physics · Physics 2015-06-23 Donald Booth , Seth Rittenhouse , Jin Yang , Hossein Sadeghpour , James Shaffer

We present high-resolution spectroscopy of Rb$_\text{2}$ ultralong-range Rydberg molecules bound by mixed singlet-triplet electron-neutral atom scattering. The mixing of the scattering channels is a consequence of the hyperfine interaction…

Ultralong-range Rydberg molecules, composed of an excited Rydberg atom and a ground-state atom, are characterized by large bond lengths, dipole moments, sensitivity to external fields, and an unusual binding mechanism based on low-energy…

Atomic Physics · Physics 2025-05-13 Agata Wojciechowska , Michał Tomza , Matthew T. Eiles

We explore the electronic structure and rovibrational properties of an ultralong-range triatomic Rydberg molecule formed by a Rydberg atom and a ground state heteronuclear diatomic molecule. We focus here on interaction of Rb($27s$) Rydberg…

Atomic Physics · Physics 2015-06-22 Rosario González-Férez , H. R. Sadeghpour , Peter Schmelcher

Rydberg atoms held in optical tweezer arrays combine vibrational and electronic degrees of freedom which can be coupled and manipulated at a microscopic level. This opens opportunities for the quantum simulation of artificial molecular…

Quantum Physics · Physics 2025-10-21 Simon Euchner , Igor Lesanovsky

A fascinating aspect of Rydberg atoms is their ability to form huge but very weakly bound molecules with a ground state atom, only held together by a scattering process between the latter and the Rydberg electron. Beyond the usual way of…

Atomic Physics · Physics 2012-07-31 Andrej Junginger , Jörg Main , Günter Wunner

We investigate properties of ultralong-range polyatomic molecules formed with a Rb Rydberg atom and several ground-state atoms whose distance from the Rydberg atom is of the order of n^2a_0, where n is the principle quantum number of the…

Atomic Physics · Physics 2007-05-23 Ivan C. H. Liu , Jan M. Rost

We propose an experimentally realizable scheme to produce triatomic ultralong-range Rydberg molecules (TURM), formed in ultracold KRb traps. A near resonant coupling of the non-zero quantum defect Rydberg levels with the KRb molecule in N=0…

A Rydberg and a ground-state atom can form ultralong range diatomic molecules provided the interaction between the ground-state atom and the Rydberg electron is attractive [C. H. Greene, et al., Phys. Rev. Lett. 85, 2458 (2000)]. A…

Atomic Physics · Physics 2008-07-15 Ivan C. H. Liu , Jovica Stanojevic , Jan M. Rost

Recent experiments with Bose-Einstein condensates have entered a regime in which thousands of ground-state condensate atoms fill the Rydberg-electron orbit. After the excitation of a single atom into a highly excited Rydberg state,…

Quantum Physics · Physics 2022-07-06 S. Tiwari , F. Engel , M. Wagner , R. Schmidt , F. Meinert , S. Wüster

We present a novel binding mechanism where a neutral Rydberg atom and an atomic ion form a molecular bound state at large internuclear distance. The binding mechanism is based on Stark shifts and level crossings which are induced in the…

Atomic Physics · Physics 2021-12-28 Markus Deiß , Shinsuke Haze , Johannes Hecker Denschlag

Rydberg atom quantum simulator platforms are novel quantum simulators for physical systems ranging from condensed matter to particle physics. In this paper, we study out-of-equilibrium quantum dynamics in a model of Rydberg atoms arranged…

Quantum Physics · Physics 2026-03-17 Mainak Pal , Tista Banerjee

We present experimental evidence for spin-orbit interaction of an electron as it scatters from a neutral atom. The scattering process takes place within a Rb$_2$ ultralong-range Rydberg molecule, consisting of a Rydberg atomic core, a…