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We introduce a computational method developed for study of long-range molecular Rydberg states of such systems that can be approximated by two electrons in a model potential of the atomic cores. Only diatomic molecules are considered. The…

Chemical Physics · Physics 2016-01-26 Michal Tarana , Roman Čurík

We report the creation of ultralong-range Sr$_2$ molecules comprising one ground-state $5s^2$ $^1S_0$ atom and one atom in a $5sns$ $^3S_1$ Rydberg state for $n$ ranging from 29 to 36. Molecules are created in a trapped ultracold atomic gas…

We review ultralong-range Rydberg molecules (ULRM), which are bound states between a Rydberg atom and one or more ground-state atoms with bond lengths on the order of thousands of Bohr radii. The binding originates from multiple…

Atomic Physics · Physics 2020-03-18 Christian Fey , Frederic Hummel , Peter Schmelcher

Strongly Rydberg-blockaded two-level atoms form a Rydberg superatom, which is excited only to a collective symmetrical Dicke state. However, emerging often in the alkali-earth atoms, the spontaneous decay from the Rydberg state to an…

Quantum Physics · Physics 2021-12-21 Chang Qiao , Wenxian Zhang

The Rydberg blockade is a key ingredient for entangling atoms in arrays. However, it requires atoms to be spaced well within the blockade radius, which limits the range of local quantum gates. Here we break this constraint using Floquet…

Quantum Physics · Physics 2023-11-08 Luheng Zhao , Michael Dao Kang Lee , Mohammad Mujahid Aliyu , Huanqian Loh

A Rydberg molecule is composed of an outer electron that collides on the residual ionic core. Typical states of Rydberg molecules display entanglement between the outer electron and the core. In this work we quantify the average…

Quantum Physics · Physics 2007-05-23 M Lombardi , A Matzkin

Long-range Rydberg molecules are typically bound in wells formed in their oscillatory potential energy curves. In alkaline Rydberg molecules, bound vibrational states exist even when these potential wells are disrupted by level repulsion…

Atomic Physics · Physics 2024-08-28 Aileen A. T. Durst , Milena Simić , Neethu Abraham , Matthew T. Eiles

Rydberg molecules, Rydberg-atom or Rydberg-molecule, are an essential ingredient of cold molecular sciences. However, due to the richness of Rydberg-neutral interactions, new kinds of Rydberg molecules and binding mechanisms are still to be…

Atomic Physics · Physics 2025-02-18 Mateo Londoño , Vanessa C. Olaya-Agudelo , Felipe Herrera , Jesús Pérez-Ríos

Ultra-long-range Rydberg molecules (ULRMs) have attracted significant interest due to their unique electronic properties and potential applications in quantum technologies. We theoretically investigate the formation and characteristics of…

We suggest a novel way to use strong Rydberg dipole-dipole interactions in order to induce non-trivial conditional dynamics in individual-atom systems and mesoscopic ensembles. Contrary to previous works, we suggest to excite atoms into…

Quantum Physics · Physics 2009-11-13 E. Brion , A. S. Mouritzen , K. Molmer

Assemblies of highly excited Rydberg atoms in an ultracold gas can be set into motion by a combination of van-der-Waals and resonant dipole-dipole interactions. Thereby, the collective electronic Rydberg state might change due to…

Atomic Physics · Physics 2021-12-15 Ritesh Pant , Rajat Agrawal , Sebastian Wüster , Jan-Michael Rost

We observe the formation of long-range Cs$_2$ Rydberg molecules consisting of a Rydberg and a ground-state atom by photoassociation spectroscopy in an ultracold Cs gas near 6s$_{1/2}$($F$=3,4)$\rightarrow$np$_{3/2}$ resonances (n=26-34).…

Atomic Physics · Physics 2015-06-23 Heiner Saßmannshausen , Frédéric Merkt , Johannes Deiglmayr

We present a comprehensive study of the diverse properties of heteronuclear Rydberg molecules, placing a special emphasis on those composed of the light alkali atoms, Li, Na, and K. Electron-atom scattering phase shifts, which determine the…

Atomic Physics · Physics 2019-02-13 Matthew T. Eiles

The Rydberg blockade mechanism is an important ingredient in quantum simulators based on neutral atom arrays. It enables the emergence of a rich variety of quantum phases of matter, such as topological spin liquids. The typically isotropic…

Quantum Physics · Physics 2025-01-15 Zhongda Zeng , Giuliano Giudici , Hannes Pichler

We show the existence of ultra-long-range giant dipole molecules formed by a neutral alkali ground state atom that is bound to the decentered electronic wave function of a giant dipole atom. The adiabatic potential surfaces emerging from…

Atomic Physics · Physics 2012-03-14 Markus Kurz , Michael Mayle , Peter Schmelcher

Rydberg molecules, often exemplified by long-range "trilobite" molecules, are a subject of much recent interest at high principal quantum number $n$. States that use the same bonding mechanism can exist at much lower $n$ and less-extreme…

Atomic Physics · Physics 2017-05-01 R. A. Carollo , J. L. Carini , E. E. Eyler , P. L. Gould , W. C. Stwalley

We propose an approach to detect individual Rydberg molecules with each molecule consisting of two atoms in different Rydberg states. The scheme exploits the movement of atoms in the presence of an external force that exerts only on atoms…

Quantum Physics · Physics 2017-12-22 Mingxia Huo

The strong interaction between Rydberg atoms can be used to control the strength and character of the interatomic interaction in ultracold gases by weakly dressing the atoms with a Rydberg state. Elaborate theoretical proposals for the…

The internal electric field of a Rydberg atom electron can bind a polar molecule to form a giant ultralong-range stable polyatomic molecule. Such molecules not only share their properties with Rydberg atoms, they possess huge permanent…

Atomic Physics · Physics 2015-05-27 Seth T. Rittenhouse , M. Mayle , P. Schmelcher , H. R. Sadeghpour

Divalent atoms have emerged as powerful alternatives to alkalis in ultracold atom platforms, offering unique advantages arising from their two-electron structure. Among these species, ytterbium (Yb) is especially promising, yet its anionic…