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Here we propose a mechanism by which spin polarization can be generated dynamically in chiral molecular systems undergoing photo-induced electron transfer. The proposed mechanism explains how spin polarization emerges in systems where…

Mesoscale and Nanoscale Physics · Physics 2021-08-19 Thomas P. Fay , David T. Limmer

Chirality-induced spin selectivity is a spin-splitting phenomenon from a helical structure with a considerably effective spin-orbit coupling. This unexpectedly large spin-splitting phenomenon has been experimentally observed in chiral…

Strongly Correlated Electrons · Physics 2024-05-08 Meng Xu , Yan Chen

The observation of spin-dependent transport through organic chiral structures has sparked numerous fundamental and applicative questions ranging from biology to spintronics. By now, there is a broad consensus that the effect results from…

Mesoscale and Nanoscale Physics · Physics 2022-01-12 Lior Oppenheim , Karen Michaeli

The chirality-induced spin selectivity (CISS), demonstrated in diverse chiral molecules by numerous experimental and theoretical groups, has been attracting extensive and ongoing interest in recent years. As the secondary structure of DNA,…

Mesoscale and Nanoscale Physics · Physics 2020-11-11 Pei-Jia Hu , Si-Xian Wang , Xiao-Hui Gao , Yan-Yang Zhang , Tie-Feng Fang , Ai-Min Guo , Qing-Feng Sun

The experiment that the high spin selectivity and the length-dependent spin polarization are observed in double-stranded DNA [Science ${\bf 331}$, 894 (2011)], is elucidated by considering the combination of the spin-orbit coupling, the…

Mesoscale and Nanoscale Physics · Physics 2015-06-03 Ai-Min Guo , Qing-feng Sun

Chiral-induced-spin-selectivity of electron transport and its interplay with DNA's mechanical motion is explored in a double stranded DNA helix with spin-orbit-coupling. The mechanical degree of freedom is treated as a stochastic classical…

Mesoscale and Nanoscale Physics · Physics 2024-09-24 Nicholas S. Davis , Julian A. Lawn , Riley J. Preston , Daniel S. Kosov

Chirality induced spin selectivity, discovered about two decades ago in helical molecules, is a non-equilibrium effect that emerges from the interplay between geometrical helicity and spin-orbit interactions. Several model Hamiltonians…

Mesoscale and Nanoscale Physics · Physics 2019-11-13 J. Fransson

The elucidation of the mechanisms behind chiral-induced spin selectivity remains an outstanding scientific challenge. Here we consider the role of delocalised phonon modes in electron transport in chiral structures and demonstrate that spin…

Mesoscale and Nanoscale Physics · Physics 2023-01-12 Clemens Vittmann , James Lim , Dario Tamascelli , Susana F. Huelga , Martin B. Plenio

The helical distribution of the electronic density in chiral molecules, such as DNA and bacteriorhodopsin, has been suggested to induce a spin-orbit coupling interaction that may lead to the so-called chirality-induced spin selectivity…

Mesoscale and Nanoscale Physics · Physics 2020-01-01 Miguel A. Sierra , David Sanchez , Rafael Gutierrez , Gianaurelio Cuniberti , Francisco Dominguez-Adame , Elena Diaz

We explicitly account for electron-electron interactions when modeling low-dimensional helical organic molecules. We show that competition between various hopping channels, together with interaction-induced double- and superexchange…

Strongly Correlated Electrons · Physics 2026-05-29 Jacek Herbrych , Maria Daghofer

Topological aspects of the geometry of DNA and similar chiral molecules have received a lot of attention, while the topology of their electronic structure is less explored. Previous experiments have revealed that DNA can efficiently filter…

Mesoscale and Nanoscale Physics · Physics 2022-10-07 Yizhou Liu , Jiewen Xiao , Jahyun Koo , Binghai Yan

Chiral induced spin selectivity is a phenomenon that has been attributed to chirality, spin-orbit interactions, and non-equilibrium conditions, while the role of electron exchange and correlations have been investigated only marginally…

Mesoscale and Nanoscale Physics · Physics 2021-04-28 J. Fransson

Despite generally lacking ferromagnetic properties or strong spin-orbit coupling, electrons in chiral molecules exhibit unique spin-dependent transport behavior, known as chiral-induced spin selectivity (CISS). This phenomenon implies a…

Chemical Physics · Physics 2025-09-05 Peng-Yi Liu , Tian-Yi Zhang , Qing-Feng Sun

Electron exchange and correlations emerging from the coupling between ionic vibrations and electrons are addressed. Spin-dependent electron-phonon coupling originates from the spin-orbit interaction, and it is shown that such…

Mesoscale and Nanoscale Physics · Physics 2021-01-04 J. Fransson

Chiral-induced spin selectivity (CISS) is a phenomenon in which electron spins are polarized as they are transported through chiral molecules, and the spin polarization depends on the handedness of the chiral molecule. In this study, we…

Mesoscale and Nanoscale Physics · Physics 2023-02-09 Nguyen Thanh Phuc

The spin-selective transport through helical molecules has been a hot topic in condensed matter physics, because it develops a new research direction in spintronics, \emph{i.e.}, chiro-spintronics. Double-stranded DNA (dsDNA) molecules have…

Mesoscale and Nanoscale Physics · Physics 2020-08-26 Gui-Fang Du , Hua-Hua Fu , Ruqian Wu

The chirality-induced spin selectivity (CISS) effect gives rise to strongly spin-dependent transport through many organic molecules and structures. Its discovery raises fascinating fundamental questions as well as the prospect of possible…

Mesoscale and Nanoscale Physics · Physics 2023-01-18 Dan Klein , Karen Michaeli

We present the first microscopic model for chirality-induced spin selectivity effect in electron-transfer, in which the internal degrees of freedom of the chiral bridge are explicitly included. By exactly solving this model on short chiral…

Mesoscale and Nanoscale Physics · Physics 2024-10-08 A. Chiesa , E. Garlatti , M. Mezzadri , L. Celada , R. Sessoli , M. R. Wasielewski , R. Bittl , P. Santini , S. Carretta

In disordered systems, the hopping conductivity regime is usually realized at low temperatures where spin-related phenomena differ strongly from the case of delocalized carriers. We develop the unified microscopic theory of current induced…

Mesoscale and Nanoscale Physics · Physics 2017-03-22 D. S. Smirnov , L. E. Golub

The spin activity in macromolecules such as DNA and oligopeptides, in the context of the Chiral Induced Spin Selectivity (CISS) has been proposed to be due to the atomic Spin-Orbit Coupling (SOC) and the associated chiral symmetry of the…

Mesoscale and Nanoscale Physics · Physics 2021-10-22 Alexander López , Solmar Varela , Ernesto Medina
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