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We present a molecular extension of our recently proposed Green's function embedding method, interacting-bath dynamical embedding theory (ibDET), for computing charged excitation energies at the $GW$ and EOM-CCSD levels. Starting from…

Chemical Physics · Physics 2026-04-06 Christian Venturella , Jiachen Li , Tianyu Zhu

By recasting the non-linear frequency-dependent $GW$ quasiparticle equation into a linear eigenvalue problem, we explain the appearance of multiple solutions and unphysical discontinuities in various physical quantities computed within the…

Chemical Physics · Physics 2022-06-16 Enzo Monino , Pierre-François Loos

The rapid progress of electron spin resonance scanning tunneling microscopy experiments has enabled the manipulation of individual adsorbate spin states physisorbed on ultrathin oxide layers supported on metal substrates. Electron resonance…

Mesoscale and Nanoscale Physics · Physics 2026-05-12 Kevin Lizárraga , Saba Taherpour , Cesar E. P. Villegas , Christoph Wolf

We present a plane wave implementation of the G0W0 approximation within the projector augmented wave method code GPAW. The computed band gaps of ten bulk semiconductors and insulators deviate on average by 0.2 eV (~ 5 %) from the…

Materials Science · Physics 2014-01-10 Falco Hüser , Thomas Olsen , Kristian S. Thygesen

Linear detectors such as zero forcing (ZF) or minimum mean square error (MMSE) are imperative for large/massive MIMO systems for both the downlink and uplink scenarios. However these linear detectors require matrix inversion which is…

Information Theory · Computer Science 2016-11-15 Vipul Gupta , Abhay Kumar Sah , A. K. Chaturvedi

The energy minimization involved in density functional calculations of electronic systems can be carried out using an exponential transformation that preserves the orthonormality of the orbitals. The energy of the system is then represented…

Computational Physics · Physics 2022-11-09 Aleksei V. Ivanov , Elvar Ö. Jónsson , Tejs Vegge , Hannes Jónsson

Full Waveform Inversion (FWI) is a technique widely used in geophysics to obtain high-resolution subsurface velocity models from waveform seismic data. Due to its large computation cost, most flavors of FWI rely only on the computation of…

Geophysics · Physics 2024-03-27 Mustafa Alfarhan , Matteo Ravasi , Fuqiang Chen , Tariq Alkhalifah

Central idea: To obtain the interaction potential using the inverse scattering method, we have employed the Physics-Informed Machine Learning (PIML) approach. In this framework, the machine learning algorithm is guided by the underlying…

Molecular Density Functional Theory (MDFT) offers an efficient implicit- solvent method to estimate molecule solvation free-energies whereas conserving a fully molecular representation of the solvent. Even within a second order ap-…

Soft Condensed Matter · Physics 2014-06-12 Volodymyr P. Sergiievskyi , Guillaume Jeanmairet , Maximilien Levesque , Daniel Borgis

While the well-established $GW$ approximation corresponds to a resummation of the direct ring diagrams and is particularly well suited for weakly-correlated systems, the $T$-matrix approximation does sum ladder diagrams up to infinity and…

Chemical Physics · Physics 2022-04-28 Pierre-François Loos , Pina Romaniello

We consider the question of approximating the inverse $\mathbf W = \mathbf V^{-1}$ of the Galerkin stiffness matrix $\mathbf V$ obtained by discretizing the simple-layer operator $V$ with piecewise constant functions. The block partitioning…

Numerical Analysis · Mathematics 2016-05-30 Markus Faustmann , Jens Markus Melenk , Dirk Praetorius

Purpose: To introduce a novel method for the recovery of multi-shot diffusion weighted (MS-DW) images from echo-planar imaging (EPI) acquisitions. Methods: Current EPI-based MS-DW reconstruction methods rely on the explicit estimation of…

Medical Physics · Physics 2016-02-24 Merry Mani , Mathews Jacob , Douglas Kelley , Vincent Magnotta

Electronic structure calculations based on density-functional theory (DFT) represent a significant part of today's HPC workloads and pose high demands on high-performance computing resources. To perform these quantum-mechanical DFT…

Computational Physics · Physics 2021-04-28 Michael Lass , Robert Schade , Thomas D. Kühne , Christian Plessl

We calculate single-particle excitation energies for a series of 33 molecules using fully selfconsistent GW, one-shot G$_0$W$_0$, Hartree-Fock (HF), and hybrid density functional theory (DFT). All calculations are performed within the…

Materials Science · Physics 2015-05-14 C. Rostgaard , K. W. Jacobsen , K. S. Thygesen

We show how to construct an effective Hamiltonian whose dimension scales linearly with system size, and whose eigenvalues systematically approximate the excitation energies of GW theory. This is achieved by rigorously expanding the…

Chemical Physics · Physics 2023-07-18 Charles J. C. Scott , Oliver J. Backhouse , George H. Booth

Similar to other electron correlation methods, many-body perturbation theory methods based on Green functions, such as the so-called $GW$ approximation, suffer from the usual slow convergence of energetic properties with respect to the size…

We derive a low-scaling $G_0W_0$ algorithm for molecules, using pair atomic density fitting (PADF) and an imaginary time representation of the Green's function and describe its implementation in the Slater type orbital (STO) based Amsterdam…

Chemical Physics · Physics 2020-11-13 Arno Förster , Lucas Visscher

We present the isospin- and angular-momentum-projected nuclear density functional theory (DFT) and its applications to the isospin-breaking corrections to the superallowed beta-decay rates in the vicinity of the N=Z line. A preliminary…

Nuclear Theory · Physics 2011-04-05 W. Satula , J. Dobaczewski , W. Nazarewicz , M. Borucki , M. Rafalski

Electronic polarization and dispersion are decisive actors in determining interaction energies between molecules. These interactions have a particularly profound effect on excitation energies of molecules in complex environments, especially…

Chemical Physics · Physics 2024-12-13 Thomas P. Fay , Nicolas Ferré , Miquel Huix-Rotllant

A fast metasurface optimization strategy for finite-size metasurfaces modeled using integral equations is presented. The metasurfaces considered are constructed from finite patterned metallic claddings supported by grounded dielectric…

Numerical Analysis · Mathematics 2023-06-16 Jordan Budhu , Anthony Grbic
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