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Saddle point search schemes are widely used to identify the transition state of different processes, like chemical reactions, surface and bulk diffusion, surface adsorption, and many more. In solid-state materials with relatively large…

Materials Science · Physics 2024-02-22 Seyyedfaridoddin Fattahpour , Sara Kadkhodaei

Melting properties are critical for designing novel materials, especially for discovering high-performance, high-melting refractory materials. Experimental measurements of these properties are extremely challenging due to their high melting…

Materials Science · Physics 2024-08-19 Li-Fang Zhu , Fritz Koermann , Qing Chen , Malin Selleby , Joerg Neugebauer , and Blazej Grabowski

The Ultra Weak Variational Formulation (UWVF) is a special Trefftz discontinuous Galerkin method, here applied to the time-harmonic Maxwell's equations. The method uses superpositions of plane waves to represent solutions element-wise on a…

Numerical Analysis · Mathematics 2024-05-07 Timo Lähivaara , William F. Hall , Matti Malinen , Dale Ota , Vijaya Shankar , Peter Monk

The inverse problem of Kohn-Sham density functional theory (DFT) is often solved in an effort to benchmark and design approximate exchange-correlation potentials. The forward and inverse problems of DFT rely on the same equations but the…

Chemical Physics · Physics 2017-08-02 Daniel Jensen , Adam Wasserman

Large biomolecular systems, whose function may involve thousands of atoms, cannot easily be addressed with parameter-free density functional theory (DFT) calculations. Until recently a central problem was that such systems possess an…

Materials Science · Physics 2026-01-29 Kristian Berland , Elisa Londero , Elsebeth Schroder , Per Hyldgaard

Metasurfaces, consisting of large arrays of interacting subwavelength scatterers, pose significant challenges for general-purpose computational methods due to their large electric dimensions and multiscale nature. This paper introduces an…

Computational Physics · Physics 2024-10-07 Emanuele Corsaro , Giovanni Miano , Antonello Tamburrino , Salvatore Ventre , Carlo Forestiere

Time-domain discontinuous Galerkin (DG) methods for wave propagation require accounting for the inversion of dense elemental mass matrices, where each mass matrix is computed with respect to a parameter-weighted L2 inner product. In…

Numerical Analysis · Mathematics 2017-01-03 Jesse Chan , Russell J. Hewett , T. Warburton

We study the accuracy of Kohn-Sham density functional theory (DFT) for warm- and hot-dense matter (WDM and HDM). Specifically, considering a wide range of systems, we perform accurate ab initio molecular dynamics simulations with…

Computational Physics · Physics 2024-11-21 Phanish Suryanarayana , Arpit Bhardwaj , Xin Jing , Shashikant Kumar , John E. Pask

Weight-adjusted inner products are easily invertible approximations to weighted $L^2$ inner products. These approximations can be paired with a discontinuous Galerkin (DG) discretization to produce a time-domain method for wave propagation…

Numerical Analysis · Mathematics 2017-12-11 Jesse Chan

Full waveform inversion (FWI) is a high-resolution subsurface imaging technique, but its effectiveness is limited by challenges such as noise contamination, sparse acquisition, and artifacts from multiparameter coupling. To address these…

Geophysics · Physics 2025-06-24 Feng Liu , Yaxing Li , Rui Su , Jianping Huang , Lei Bai

Full waveform inversion (FWI) is a powerful yet computationally expensive technique that can yield subsurface models at high resolution. Randomly selected shots ("mini-batches") can be used to approximate the misfit and the gradient of FWI,…

Geophysics · Physics 2020-05-25 Bharath Shekar

The recently developed technique of DOC kernels has been a great success in the stability and convergence analysis for BDF2 scheme with variable time steps. However, such an analysis technique seems not directly applicable to problems with…

Numerical Analysis · Mathematics 2022-01-25 Chengchao Zhao , Ruoyu Yang , Yana Di , Jiwei Zhang

We present a comprehensive methodology to enable addition of van der Waals (vdW) corrections to machine learning (ML) atomistic force fields. Using a Gaussian approximation potential (GAP) [Bart\'ok et al., Phys. Rev. Lett. 104, 136403…

The self-consistent theory of the correlation effects in Highly Correlated Systems(HCS) is presented. The novel Irreducible Green's Functions(IGF) method is discused in detail for the Hubbard model and random Hubbard model. The…

Strongly Correlated Electrons · Physics 2008-02-03 A. L. Kuzemsky

Numerically obtaining the inverse of a function is a common task for many scientific problems, often solved using a Newton iteration method. Here we describe an alternative scheme, based on switching variables followed by spline…

Computational Physics · Physics 2020-03-09 Daniele Tommasini , David N. Olivieri

We present a numerical modeling workflow based on machine learning (ML) which reproduces the the total energies produced by Kohn-Sham density functional theory (DFT) at finite electronic temperature to within chemical accuracy at negligible…

Density functional theory (DFT) embedding provides a formally exact framework for interfacing correlated wave-function theory (WFT) methods with lower-level descriptions of electronic structure. Here, we report techniques to improve the…

Chemical Physics · Physics 2015-06-12 Jason D. Goodpaster , Taylor A. Barnes , Frederick R. Manby , Thomas F. Miller

Within the finite-field Kohn-Sham framework, static electric response properties of diatomic molecules are presented. The electronic energy, dipole moment ({\boldmath$\mu$}), static dipole polarizability ({\boldmath$\alpha$}) and…

Chemical Physics · Physics 2019-04-26 Abhisek Ghosal , Tanmay Mandal , Amlan K. ~Roy

In the workflow of Full-Waveform Inversion (FWI), we often tune the parameters of the inversion to help us avoid cycle skipping and obtain high resolution models. For example, typically start by using objective functions that avoid cycle…

Geophysics · Physics 2020-02-11 Bingbing Sun , Tariq Alkhalifah

We present a matrix-product state (MPS)-based quadratically convergent density-matrix renormalization group self-consistent-field (DMRG-SCF) approach. Following a proposal by Werner and Knowles (JCP 82, 5053, (1985)), our DMRG-SCF algorithm…

Chemical Physics · Physics 2017-08-14 Yingjin Ma , Stefan Knecht , Sebastian Keller , Markus Reiher
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