English

Static and Dynamic Bethe-Salpeter Equations in the $T$-Matrix Approximation

Chemical Physics 2022-04-28 v2 Materials Science Strongly Correlated Electrons Nuclear Theory Computational Physics

Abstract

While the well-established GWGW approximation corresponds to a resummation of the direct ring diagrams and is particularly well suited for weakly-correlated systems, the TT-matrix approximation does sum ladder diagrams up to infinity and is supposedly more appropriate in the presence of strong correlation. Here, we derive and implement, for the first time, the static and dynamic Bethe-Salpeter equations when one considers TT-matrix quasiparticle energies as well as a TT-matrix-based kernel. The performance of the static scheme and its perturbative dynamical correction are assessed by computing the neutral excited states of molecular systems. Comparison with more conventional schemes as well as other wave function methods are also reported. Our results suggest that the TT-matrix-based formalism performs best in few-electron systems where the electron density remains low.

Keywords

Cite

@article{arxiv.2202.07936,
  title  = {Static and Dynamic Bethe-Salpeter Equations in the $T$-Matrix Approximation},
  author = {Pierre-François Loos and Pina Romaniello},
  journal= {arXiv preprint arXiv:2202.07936},
  year   = {2022}
}

Comments

10 pages, 6 figures

R2 v1 2026-06-24T09:40:30.905Z