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The Jarzynski equality allows the calculation of free-energy differences using values of work measured from nonequilibrium trajectories. The number of trajectories required to accurately estimate free-energy differences in this way grows…

Statistical Mechanics · Physics 2025-05-13 Stephen Whitelam

In this short communication, I give a very simple derivation of the Jarzynski equality, which allows to compute the free energy difference of a body, which is driven between two equilibrium states $A$ and $B$ by an external (time-dependent)…

Statistical Mechanics · Physics 2016-08-16 Frédéric Douarche

We reconsider a well-known relationship between the fluctuation theorem and the second law of thermodynamics by evaluating a probability measure-valued process. In order to establish a bridge between microscopic and macroscopic behaviors,…

Statistical Mechanics · Physics 2015-03-19 Yuki Sughiyama , Masayuki Ohzeki

We consider a single Josephson junction in the presence of time varying gate charge, and examine the nonequilibrium work done by the charge control in the framework of fluctuation theorems. We obtain the probability distribution functions…

Statistical Mechanics · Physics 2013-02-07 Su Do Yi , Beom Jun Kim , Juyeon Yi

Recent studies have explored finite-time dissipation-minimizing protocols for stochastic thermodynamic systems driven arbitrarily far from equilibrium, when granted full external control to drive the system. However, in both simulation and…

Statistical Mechanics · Physics 2022-10-27 Adrianne Zhong , Michael R. DeWeese

We consider work extraction from $N$ copies of a quantum system. When the same work-extraction process is implemented on each copy, the relative size of fluctuations is expected to decay as $1/\sqrt{N}$. Here, we consider protocols where…

Quantum Physics · Physics 2019-08-15 Martí Perarnau-Llobet , Raam Uzdin

A promising method for calculating free energy differences Delta F is to generate non-equilibrium data via ``fast-growth'' simulations or experiments -- and then use Jarzynski's equality. However, a difficulty with using Jarzynski's…

Computational Physics · Physics 2007-05-23 F. Marty Ytreberg , Daniel M. Zuckerman

A fluctuation theorem relating the work to its optimal average work is presented. The function mediating the relation is increasing and convex, and depends on the switching time $\tau$, driving strength $\delta\lambda/\lambda_0$, and…

Statistical Mechanics · Physics 2024-07-02 Pierre Nazé

Quantum work fluctuation theorem (FT) commonly requires the system initially prepared in an equilibrium state. Whether there exists universal exact quantum work FT for initial state beyond equilibrium needs further discussions. Here, I…

Statistical Mechanics · Physics 2024-01-12 Bao-Ming Xu

A generalized version of the Maximum Work Theorem is valid when the system is initially not at thermal equilibrium. In this work, we initially study the fraction of trajectories that violate this generalized theorem for a two simple…

Statistical Mechanics · Physics 2017-09-15 Sourabh Lahiri , Arun M. Jayannavar , Anupam Kundu

Jarzynski's equality [1] allows us to investigate free energy landscapes (FELs) by constructing distributions of work performed on a system from an initial ensemble of states to final states. This work is experimentally measured by…

Biological Physics · Physics 2011-05-24 Van Ngo

We consider the paradigm of an overdamped Brownian particle in a potential well, which is modulated through an external protocol, in the presence of stochastic resetting. Thus, in addition to the short range diffusive motion, the particle…

Statistical Mechanics · Physics 2020-03-25 Deepak Gupta , Carlos A. Plata , Arnab Pal

Various aspects of the statistics of work performed by an external classical force on a quantum mechanical system are elucidated for a driven harmonic oscillator. In this special case two parameters are introduced that are sufficient to…

Statistical Mechanics · Physics 2009-06-05 Peter Talkner , P. Sekhar Burada , Peter Hänggi

The fluctuation theorems, and in particular, the Jarzynski equality, are the most important pillars of modern non-equilibrium statistical mechanics. We extend the quantum Jarzynski equality together with the Two-Time Measurement Formalism…

Statistical Mechanics · Physics 2018-03-01 Anthony Bartolotta , Sebastian Deffner

The field-dependent equilibrium thermodynamics is derived with two methods: either by using the potential formalism either by the statistical method. Therefore, Pontrjagin's extremum principle of control theory is applied to an extended…

General Physics · Physics 2007-05-23 W. D. Bauer

According to the Jarzynski theorem, equilibrium free energy differences can be calculated from the statistics of work carried out during non-equilibrium transformations. Although exact, this approach can be plagued by large statistical…

Statistical Mechanics · Physics 2007-05-23 Wolfgang Lechner , Christoph Dellago

We suggest and discuss a simple model of an ideal gas under the piston to gain an insight into the workings of the Jarzynski identity connecting the average exponential of the work over the non-equilibrium trajectories with the equilibrium…

Statistical Mechanics · Physics 2007-05-23 R. C. Lua , A. Y. Grosberg

Jarzynski's equality (JE) allows us to compute free energy differences from distributions of work. In molecular dynamics simulations, the traditional way of constructing work distributions is to perform as many pulling simulations as…

Computational Physics · Physics 2012-05-07 Van Ngo

The probability distribution function for an out of equilibrium system may sometimes be approximated by a physically motivated "trial" distribution. A particularly interesting case is when a driven system (e.g., active matter) is…

Statistical Mechanics · Physics 2012-03-27 Carlos Perez-Espigares , Alejandro B. Kolton , Jorge Kurchan

We study the possibility of deterministic protocols for extracting work from quantum systems. Focusing on the two-point measurement work extraction scenario, we prove that, with enough copies of the system, such zero-fluctuation protocols…

Quantum Physics · Physics 2024-07-15 Raffaele Salvia , Vittorio Giovannetti