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Thermodynamics constrains changes to the energy of a system, both deliberate and random, via its first and second laws. When the system is not in equilibrium, fluctuation theorems such as the Jarzynski equality further restrict the…

We show how Jarzynski relation can be exploited to analyze the nature of order-disorder and a bifurcation type dynamical transition in terms of a response function derived on the basis of work distribution over non-equilibrium paths between…

Chemical Physics · Physics 2015-06-05 Pulak Kumar Ghosh , Deb Shankar Ray

The asymptotic behaviour of the work probability distribution in driven non-equilibrium systems is determined using the method of optimal fluctuations. For systems described by Langevin dynamics the corresponding Euler-Lagrange equation…

Statistical Mechanics · Physics 2013-05-29 A. Engel

We present a new inequality which holds in the thermodynamical processes with measurement and feedback controls with using only the Helmholtz free energy and the entanglement of formation: $W_{\mathrm{ext}}\le-\Delta F-k_{B}T\Delta E_{F}$.…

Quantum Physics · Physics 2013-11-13 Hiroyasu Tajima

When a system deviates from equilibrium, it is possible to manipulate and control it to drive it towards equilibrium within a finite time $t_f$, even reducing its natural relaxation time scale $\tau_{relax}$. Although numerous theoretical…

Statistical Mechanics · Physics 2024-02-26 Diego Rengifo , Gabriel Téllez

We consider the task of extracting work from quantum systems in the resource theory perspective of thermodynamics, where free states are arbitrary thermal states, and allowed operations are energy conserving unitary transformations. Taking…

Quantum Physics · Physics 2013-02-13 Paul Skrzypczyk , Anthony J. Short , Sandu Popescu

We propose and analyze a process that extracts useful work from a single active particle maintained at constant temperature in a harmonic potential by measuring the relative sign of the self-propulsion and the confining force and then…

Statistical Mechanics · Physics 2026-03-09 Grzegorz Szamel

The Jarzynski relation is a recently discovered result relating the average exponential of the work done under nonequilibrium conditions to an equilibrium free energy difference. We illustrate this remarkable relation by considering the…

Statistical Mechanics · Physics 2007-05-23 Rhonald C. Lua

The driven double-well Duffing oscillator is a well-studied system that manifests a wide variety of dynamics, from periodic behavior to chaos, and describing a diverse array of physical systems. It has been shown to be relevant in…

Chaotic Dynamics · Physics 2017-12-22 Maximillian Trostel , Moses Misplon , Andrés Aragoneses , Arjendu Pattanayak

In the thermodynamics of nanoscopic systems the relation between classical and quantum mechanical description is of particular importance. To scrutinize this correspondence we study an anharmonic oscillator driven by a periodic external…

Statistical Mechanics · Physics 2020-08-26 Mattes Heerwagen , Andreas Engel

Based only on classical Hamiltonian dynamics, we prove the maximum work principle in a system where macroscopic dynamical degrees of freedom are intrinsically coupled to microscopic degrees of freedom. Unlike recent identities between…

Statistical Mechanics · Physics 2015-05-26 Christian Maes , Hal Tasaki

We extend Jarzynski's work relation and the second law of thermodynamics to a heat conducting system which is operated by an external agent. These extensions contain a new non equilibrium contribution expressed as the violation of the…

Statistical Mechanics · Physics 2012-09-25 Naoko Nakagawa

We derive the optimal estimates of the free energies of an arbitrary number of thermodynamic states from nonequilibrium work measurements; the work data are collected from forward and reverse switching processes and obey a fluctuation…

Statistical Mechanics · Physics 2009-11-11 Paul Maragakis , Martin Spichty , Martin Karplus

We derive the bias function that minimizes the statistical error of free energy differences calculated in work-biased fast-switching simulations. The optimum bias function is compared to other bias functions using a particle pulled through…

Statistical Mechanics · Physics 2009-11-13 Harald Oberhofer , Christoph Dellago

We consider a quasi-probability distribution of work for an isolated quantum system coupled to the energy-storage device given by the ideal weight. Specifically, we analyze a trade-off between changes in average energy and changes in…

Quantum Physics · Physics 2022-07-20 Marcin Łobejko

Anomalous transport of a particle subjected to non-Ohmic damping of the power $\delta$ in a tilted periodic potential is investigated via Monte Carlo simulation of generalized Langevin equation. It is found that the system exhibits two…

Statistical Mechanics · Physics 2009-11-13 Kun Lü , Jing-Dong Bao

While optimal control theory offers effective strategies for minimizing energetic costs in noisy microscopic systems over finite durations, a significant opportunity lies in exploiting the temporal structure of non-equilibrium forces. We…

Statistical Mechanics · Physics 2025-04-10 Kristian Stølevik Olsen , Rémi Goerlich , Yael Roichman , Hartmut Löwen

A remarkably simple result is found for the optimal protocol of drivings for a general two-level Hamiltonian which transports a given initial state to a given final state in minimal time. If one of the three possible drivings is…

Quantum Physics · Physics 2015-06-22 Gerhard C. Hegerfeldt

We study numerically the behavior of RNA secondary structures under influence of a varying external force. This allows to measure the work $W$ during the resulting fast unfolding and refolding processes. Here, we investigate a medium-size…

Statistical Mechanics · Physics 2021-09-15 Peter Werner , Alexander K. Hartmann

We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy (H-function) is not just a Lyapunov function…

Statistical Mechanics · Physics 2015-05-13 H. -H. Hasegawa , J. Ishikawa , K. Takara , D. J. Driebe